CAS: 4023-53-4; Tris(2-Cyanoethyl)Phosphine

该化合物是三级磷化合物,由三组环乙基化合物组成,与中磷原子结合,这种试剂在环境条件下具有稳定性,并且作为有机和有机金属合成的减少剂具有效用,因此具有价值;其富电子磷中心为离子和交换反应提供了便利,使其在准备磷基金属综合体方面有所助益; 丙基乙基化合物组提高了极有机溶剂的溶性,同时保持了中度空气稳定,与较敏感的磷相比,保持了中度空气稳定; 通常用于硫化聚氨化物化学,以减少脱硫联结,纳米粒合成作为一种稳定剂,其平衡的再活动性和处理特性使它成为受控减少和协调化学应用的实际选择.

结构式图片

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上下游产品

acrylonitrile bis(2-cyanoethyl)phosphine acetonitriletris(2-cyanoethyl)phosphine oxide tris(2-cyanoethyl)phosphine sulphide tris(2-carboxyethyl)phosphine Ethyl-tris-(2-cyan-ethyl)-phosphonium

合成工艺路线路线简述

  • 合成目标产物 Tris(2-Cyanoethyl)Phosphine 主要起始原料 Acrylonitrile
  • (文献来源)合成步骤主要原料 Acrylonitrile
丙烯腈置于phosphan体系中,化学反应生成 三(2-氰乙基)膦
参考文献:The Nucleophilicity Of Phosphines
标题:The Nucleophilicity Of Phosphines
摘要:
DOI:10.1021/ja01507A009

海关参考信息

专利信息


专利号:US-9273410-B2
优先权日:2009-01-16
标 题 :Low-temperature synthesis of colloidal nanocrystals
发明人:BARTL MICHAEL H; SIY JACQUELINE T
权利人:BARTL MICHAEL H; SIY JACQUELINE T; UNIV UTAH RES FOUND
摘要:Low-temperature organometallic nucleation and crystallization-based synthesis methods for the fabrication of semiconductor and metal colloidal nanocrystals with narrow size distributions and tunable, size- and shape-dependent electronic and optical properties. Methods include (1) forming a reaction mixture in a reaction vessel under an inert atmosphere that includes at least one solvent, a cationic precursor, an anionic precursor, and at least a first surface stabilizing ligand while stirring at a temperature in a range from about 50° C. to about 130° C. and (2) growing nanocrystals in the reaction mixture for a period of time while maintaining the temperature, the stirring, and the inert-gas atmosphere.

专利号:US-4341706-A
优先权日:1980-10-10
标题 :Process for the preparation of carbapenem antibiotics
发明人:CHRISTENSEN BURTON G; SHIH DAVID H
权利人:MERCK & CO INC
摘要:Disclosed is a process for the synthesis of carbapenem antibiotics I and their pharmaceutically acceptable salts and esters from 1: wherein: R7, R6, R1, R2 and R8 are selected from hydrogen, alkyl, alkenyl, alkynyl, cycloalkyl, spirocycloalkyl, cycloalkylalkyl, alkylcycloalkyl, aryl, aralkyl, aralkenyl, aralkynyl, heteroalkyl, heteroaralkyl, heterocyclyl and heterocyclyalkyl.

专利号:US-4460507-A
优先权日:1980-10-10
标题:Process for the preparation of thienamycin
发明人:SHIH DAVID H
权利人:MERCK & CO INC
摘要:Disclosed is a process for the total synthesis of thienamycin from descysteaminylthienamycin 1 ##STR1## via thienamycin sulfoxide 4: ##STR2## R 3 , R°, R' are blocking groups.

专利号:US-4451680-A
优先权日:1982-10-21
标题:Alcohols prepared from olefins and synthesis gas
发明人:KNIFTON JOHN F
权利人:TEXACO INC
摘要:This invention concerns a process of preparing predominantly linear alcohols which comprises the steps of contacting a mixture of terminal and/or internal olefins and synthesis gas with a catalyst system comprising a ruthenium-containing compound coupled with one or more bidentate or multidentate, phosphine-containing promoters, dispersed in a low melting quaternary phosphonium salt, and heating said resultant reaction mixture under a pressure of 100 psi or greater at a temperature of at least 50 DEG C. for a sufficient time to produce said alcohols.

专利号:US-2006030723-A1
优先权日:2001-09-28
标 题:Process for synthesis of organometallic compounds

专利号:US-2018320286-A1
优先权日:2009-01-16
标 题:Low-temperature synthesis of colloidal nanocrystals
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合成参考文献


摘要:Mathey, F., Science of Synthesis Knowledge Updates, (2012) 4, 351.
摘要:Andersson, C.-M.; Andersson, M., Science of Synthesis: Cross Coupling and Heck-Type Reactions, (2012) 3, 8.
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