CAS: 7173-54-8; N,N-Didodecyl-N-Methyldodecan-1-Aminium Chloride

该化合物是一种四氟铵化合物,其特点是长的氢离子烷基链和活性氮原子,通常视温度而定,是白色对白的固体或粘度液体,因其表面活性特性而闻名,可有效减少表面紧张,增强湿和乳化能力,在有机溶剂中溶解,水溶解度有限,这是长链四氟铵化合物的共同特征,这种物质经常用于各种用途,包括作为阶段转移催化剂,用于抗微生物剂的配制,以及用于生产丙酸表面活性剂.此外,TDMACel可以与生物膜相互作用,这可能会影响其毒性和环境影响.由于可能对皮肤和眼睛产生刺激效应,因此在处理时需要谨慎小心,而且应该储存在远离不相容材料的冷干地方.

结构式图片

相似化合物

5137-55-3 107-64-2 7173-51-5

欧盟法规

ECHA物质C&L通报REACH预注册

上下游产品

methylene chloride tridodecylamine

合成工艺路线路线简述

    氯甲烷,三月桂胺 以 乙腈 作为反应溶剂,化学反应 24.0H,反应生成 三十二烷基甲基氯化铵
    参考文献:イオン液体組成物及びそれを含む溶媒
    标题:イオン液体組成物及びそれを含む溶媒
    摘要:提供具有高流动性和高疏水性的离子液体组成物.将离子液体组成物包括至少一种固体有机盐(熔点>=70oc)和至少一种液体有机盐(熔点<=30oc),其中所述固体有机盐和液体有机盐具有相同的阳离子部分或相同的阴离子部分,含水量为1-50质量%,水/正辛烷醇计算分配系数(logp)>=0.5,粘度在25oc时不超过3Pa.s.

    海关参考信息

    专利信息


    专利号:US-11583842-B2
    优先权日:2019-07-24
    标题 :Zwitterionic catalysts for (trans)esterification: application in fluoroindole-derivatives and biodiesel synthesis
    发明人:YEUNG YING-YEUNG; LAM YING-PONG; KE ZHIHAI; WANG XINYAN; TAN FEI; NG WING-HIN; TSE YING-LUNG STEVE
    权利人:UNIV HONG KONG CHINESE
    摘要:An amide/iminium zwitterion catalyst has a catalyst pocket size that promotes transesterification and dehydrative esterification. The amide/iminium zwitterions are easily prepared by reacting aziridines with aminopyridines. The reaction can be applied a wide variety of esterification processes including the large-scale synthesis of biodiesel. The amide/iminium zwitterions allow the avoidance of strongly basic or acidic condition and avoidance of metal contamination in the products. Reactions are carried out at ambient or only modestly elevated temperatures. The amide/iminium zwitterion catalyst is easily recycled and reactions proceed in high to quantitative yields.

    专利号:WO-9630393-A1
    优先权日:1995-03-27
    标 题:A method for the synthesis of mixtures of compounds
    发明人:BECKER KATHERINE; DEWITT SHEILA HOBBS
    权利人:WARNER LAMBERT CO
    摘要:Described is a method of synthesizing a plurality of compounds in a plurality of wells comprising the steps of: (a) providing a plurality of test wells in a plurality of arrays of the wells; (b) reacting in at least a one step reaction a first reagent with a plurality of reagents called building blocks in the test well to obtain a unique product designed to be the same in each array; and (c) continuing to react reagents such that there are multiple reagents resulting in mixtures of multiple different products in each well.

    专利号:US-5663432-A
    优先权日:1995-05-18
    标 题:Process for the preparation of 5-amino-2,4,6-Triiodoisophthalic acid dichloride by chlorination with thionyl chloride in the presence of a catalyst
    发明人:VILLA MARCO; POZZOLI CLAUDIO; RUSSO LAURA; CASTALDI GRAZIANO
    权利人:ZAMBON SPA
    摘要:A process for the preparation of 5-amino-2,4,6-triiodoisophthalic acid dichloride by chlorination of 5-amino-2,4,6-triiodoisophthalic acid with thionyl chloride in the presence of a suitable solvent characterized in that the reaction is carried out in the presence of catalytic amounts of a tetraalkylammonium salt of formula R1R2R3R4NX (I) wherein X is halogen, mesylate or tosylate; R1, R2, R3 and R4, the same or different, are C1-C20 alkyl groups so that the total number of carbon atoms of the groups R1, R2, R3 and R4 is higher than 16. The 5-amino-2,4,6-triiodoisophthalic acid dichloride obtained according to the process of the present invention is useful as intermediate in the synthesis of iodinated contrast media.

    专利号:IT-MI951004-A1
    优先权日:1995-05-18
    标 题:PROCESS FOR THE PREPARATION OF A USEFUL INTERMEDIATE IN THE SYNTHESIS OF ORGANIC COMPOUNDS
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    主要参考文献

    参考标题:Zwitterionic Catalysts For (Trans)Esterification: Application In Fluoroindole-Derivatives And Biodiesel Synthesis
    摘要:An Amide/iminium Zwitterion Catalyst Has A Catalyst Pocket Size That Promotes Transesterification And Dehydrative Esterification. The Amide/iminium Zwitterions Are Easily Prepared By Reacting Aziridines With Aminopyridines. The Reaction Can Be Applied A Wide Variety Of Esterification Processes Including The Large-Scale Synthesis Of Biodiesel. The Amide/iminium Zwitterions Allow The Avoidance Of Strongly Basic Or Acidic Condition And Avoidance Of Metal Contamination In The Products. Reactions Are Carried Out At Ambient Or Only Modestly Elevated Temperatures. The Amide/iminium Zwitterion Catalyst Is Easily Recycled And Reactions Proceed In High To Quantitative Yields.

    合成参考文献


    参考文献:10.1007/s00216-006-0530-2
    摘要:Cortina M, Duran A, Alegret S, del Valle M. A sequential injection electronic tongue employing the transient response from potentiometric sensors for anion multidetermination. Analytical and Bioanalytical Chemistry. 2006 Jun 24;385(7):1186–94. doi: 10.1007/s00216-006-0530-2.
    参考文献:10.2116/analsci.33.159
    摘要:Yamamoto K, Mitsuda S, Ohtake N, Murashige N, Ohmuro S, Yuchi A. Perchlorate Selectivity of Anion Exchange Resins as Evaluated Using Ion-Selective Electrodes. Analytical Sciences. 2017 Feb 10;33(2):159–63. doi: 10.2116/analsci.33.159.
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