CAS: 79060-88-1; Sodium Tetrakis(3,5-Bis(Trifluoromethyl)Phenyl)Borate

• 英文名称Sodium Tetrakis(3,5-Bis(Trifluoromethyl)Phenyl)Borate
• 中文名称四(3,5-二(三氟甲基)苯基)硼酸钠
• IUPAC名称sodium tetrakis(3,5-bis(trifluoromethyl)phenyl)borate
• 其它别名四[3,5-双(三氟甲基)苯基]硼酸钠 水合物; 四35二三氟甲基苯基硼酸钠; Sodium Tetrakis[3,5-Bis(Trifluoromethyl)Phenyl]Borate(1-)
• CAS编号79060-88-1
• MFCD编号:MFCD00043323
• EINECS号:676-842-3
• 分子式:C32H12BF24Na
• 分子量:886.2
• 产品CID: 1784366
• 产品分类有机原料→通用试剂→卤化试剂→氟化试剂

• 相似结构搜索
• 产品信息参考;;;;
• InChIKey: LTGMONZOZHXAHO-UHFFFAOYSA-N
• InChI=1S/C32H12BF24.Na/c34-25(35,36)13-1-14(26(37,38)39)6-21(5-13)33(22-7-15(27(40,41)42)2-16(8-22)28(43,44)45,23-9-17(29(46,47)48)3-18(10-2…
• 计算化学: 氢键受体数*氢键供体数0.0可旋转键数4.0

相似化合物

物理性质

• 熔点310 °C
• 沸点310°C
• LogP:8.2184
• 溶解性DMSO (Slightly)
• 敏感性远离氧化物，湿气。
• 外观形态棕褐色粉末
• 储存条件置于阴暗处,密封, 常温干燥保存
• 产品应用该化合物用作聚合反应的催化剂.

MSDS等安全信息

• GHS象形图
• GHS符号GHS07;
  注释: Exclamation mark
• 危险类别特定目标器官毒性 - 单次接触 类别3
  皮肤腐蚀/刺激 类别2
  严重眼刺激 类别2
  急性毒性 类别4(吸入)
  急性毒性 类别4(经皮)
  急性毒性 类别4(经口)
• 警示词Warning(警告)
• 危险描述H335 |可能引起呼吸道刺激.
  H315 |造成皮肤刺激.
  H319 |造成严重眼刺激.
  H332 |吸入有害.
  H312 |皮肤接触有害.
  H302 |吞咽有害.
• 防范说明P261-P264-P270-P271-P280-P302+P352-P304+P340-P305+P351+P338-P330-P362+P364-P403+P233-P405-P501
• 危险等级IRRITANT
• UN编号NONH for all modes of transport
• 危险品标志Xn,Xi
• 安全声明36/37/39-26-22
• 危险类别码36/37/38-20/21/22
• WGK Germany3

欧盟法规

上下游产品

合成工艺路线路线简述

• 合成目标产物 Sodium Tetrakis[3,5-Bis(Trifluoromethyl)Phenyl]Borate 主要起始原料 Sodium Tetrafluoroborate And 3,5-Bis(Trifluoromethyl)Bromobenzene
• 328-70-1 = 79060-88-1
  反应条件:1.1 Reagents: Magnesium,Sodium Tetrafluoroborate Catalysts: 1,2-Dibromoethane Solvents: Diethyl Ether; 30 Min,60 °C; Overnight,Rt1.2 Reagents: Sodium Carbonate Solvents: Water; 30 Min,Rt
  标题:Rip It Off: Nitro To Nitroso Reduction By Iron Half-Sandwich Complexes
  作者:Korb,Marcus; Hosseini Ghazvini,Seyed Mohammad Bagher; Moggach,Stephen A.; Meunier,Jean-Francois; Bousseksou,Azzedine; Et Al
  参考文献:Inorganic Chemistry 日期:2021 卷标:60(7) 页码:4986-4995]
  
  328-70-1 = 79060-88-1
  反应条件:1.1 Reagents: 1,2-Dibromoethane,Magnesium,Sodium Tetrafluoroborate Solvents: Diethyl Ether
  标题:Synthesis And Application Of Pinene-Pyridine Derivatives In Asymmetric Catalysis
  作者:Friscourt,Frederic
  参考文献:2008]
  
  328-70-1 = 79060-88-1
  反应条件:1.1 Reagents: 1,2-Dibromoethane,Magnesium,Sodium Tetrafluoroborate Solvents: Diethyl Ether; Rt -> Reflux; 3 H,Reflux1.2 Solvents: Diethyl Ether; 3 H,Reflux; 1 H,Reflux; Reflux -> Rt; Overnight,Rt1.3 Reagents: Sodium Carbonate Solvents: Water; 1 H,Rt
  标题:Electronic Effects Of Ligand Substitution On Spin Crossover In A Series Of Diiminoquinonoid-Bridged Feii2 Complexes
  作者:Park,Jesse G.; Jeon,Ie-Rang; Harris,T. David
  参考文献:Inorganic Chemistry 日期:2015 卷标:54(1) 页码:359-369]
  
  328-70-1 = 79060-88-1
  反应条件:1.1 Reagents: Dibromomethane,Magnesium,Sodium Tetrafluoroborate Solvents: Diethyl Ether; 10 Min,Reflux; 45 Min,Reflux1.2 Solvents: Diethyl Ether; 1.5 H,Reflux; 1 H,Reflux; 16 H,Rt1.3 Reagents: Sodium Carbonate Solvents: Water; 45 Min,Rt
  标题:N-Heterocyclic Iod(Az)Olium Salts - Potent Halogen-Bond Donors In Organocatalysis
  作者:Boelke,Andreas; Kuczmera,Thomas J.; Lork,Enno; Nachtsheim,Boris J.
  参考文献:Chemistry - A European Journal 日期:2021 卷标:27(52) 页码:13128-13134]
  
  328-73-4 = 79060-88-1
  反应条件:1.1 Reagents: Magnesium,Bromooctyl- Solvents: Diethyl Ether1.2 Reagents: Boron Trifluoride Etherate1.3 Reagents: Sodium Bicarbonate Solvents: Water
  标题:Syntheses And Lipophilicities Of Tetraarylborate Ions Substituted With Many Trifluoromethyl Groups
  作者:Fujiki,Kanji; Kashiwagi,Mitsuyoshi; Miyamoto,Hideyuki; Sonoda,Akinari
  参考文献:Journal Of Fluorine Chemistry 日期:1992 卷标:57(1-3) 页码:307-21]
  
  328-70-1 = 79060-88-1
  反应条件:1.1 Reagents: Magnesium,Iodine Solvents: Diethyl Ether; 25 Min,Rt1.2 Solvents: Diethyl Ether; 65 Min,Rt; 4 H,Rt1.3 Reagents: Boron Trifluoride Etherate Solvents: Diethyl Ether; 1 H,Rt; 16 H,Reflux; Reflux -> Rt1.4 Reagents: Sodium Carbonate Solvents: Water; 1 H,Rt
  标题:A Mechanistic Analysis Of Trimethylanilinium Salt Degradation: Implications For Methylation And Cross-Coupling Applications
  作者:Washington,Jack B.; Assante,Michele; Yan,Chunhui; Mckinney,David; Juba,Vanessa; Et Al
  参考文献:Chemrxiv 日期:2021 卷标:1 页码:1-14]
  
  328-70-1 = 79060-88-1
  反应条件:1.1 Reagents: Chloro(1-Methylethyl)Magnesium Solvents: Tetrahydrofuran; -20 °C; 1 H,-20 °C -> 0 °C1.2 Reagents: Sodium Tetrafluoroborate; 48 H,23 °C1.3 Reagents: Sodium Bicarbonate,Sodium Carbonate Solvents: Water; 1 H,Rt
  标题:Safe Preparation And Purification Of Sodium Tetrakis[(3,5-Trifluoromethyl)Phenyl]Borate (Nabarf24): Reliable And Sensitive Analysis Of Water In Solutions Of Fluorinated Tetraarylborates
  作者:Yakelis,Neal A.; Bergman,Robert G.
  参考文献:Organometallics 日期:2005 卷标:24(14) 页码:3579-3581]
  
  328-70-1 = 79060-88-1
  反应条件:1.1 Reagents: Chloro(1-Methylethyl)Magnesium Solvents: Tetrahydrofuran; 45 Min,-20 °C; 1 H,-20 °C -> 0 °C1.2 Reagents: Sodium Tetrafluoroborate; 48 H,Rt1.3 Reagents: Sodium Bicarbonate,Sodium Carbonate Solvents: Water; 1 H,Rt
  标题:Iron-Catalyzed Cycloisomerization And C-C Bond Activation To Access Non-Canonical Tricyclic Cyclobutanes
  作者:Kramm,Frederik; Ullwer,Franziska; Klinnert,Benedict; Zheng,Min; Plietker,Bernd
  参考文献:Angewandte Chemie 日期:2022 卷标:61(38)]
  
  328-70-1 = 79060-88-1
  反应条件:1.1 Reagents: Magnesium,Sodium Tetrafluoroborate Catalysts: 1,2-Dibromoethane Solvents: Diethyl Ether; 12 H,Rt
  标题:(R)-3-Methyl-3-Phenyl-1-Pentene Via Catalytic Asymmetric Hydrovinylation
  作者:Smith,Craig R.; Zhang,Aibin; Mans,Daniel J.; Rajanbabu,T. V.
  参考文献:Organic Syntheses 日期:2008 卷标:85 页码:248-266]
  
  328-70-1 = 79060-88-1
  反应条件:1.1 Reagents: 1,2-Dibromoethane,Magnesium,Sodium Tetrafluoroborate Solvents: Diethyl Ether1.2 Reagents: Sodium Carbonate Solvents: Water
  标题:Control Of The Stereochemical Impact Of The Lone Pair In Lead(Ii) Tris(Pyrazolyl)Methane Complexes. Improved Preparation Of Na{b[3,5-(Cf3)2C6H3]4}
  作者:Reger,Daniel L.; Wright,Terri D.; Little,Christine A.; Lamba,Jaydeep J. S.; Smith,Mark D.
  参考文献:Inorganic Chemistry 日期:2001 卷标:40(15) 页码:3810-3814]
  
  328-70-1 = 79060-88-1
  反应条件:1.1 Reagents: 1,2-Dibromoethane,Magnesium,Sodium Tetrafluoroborate Solvents: Diethyl Ether; Heated1.2 Solvents: Diethyl Ether; 30 Min,Reflux; 30 Min,Reflux; Overnight,Rt
  标题:Main Group Compounds. Sodium Tetrakis(3,5-Bis(Trifluoromethyl)Phenyl)Borate,Na[b(3,5-(Cf3)2C6H3)4]
  作者:Reger,Daniel L.; Little,Christine A.; Lamba,Jaydeep J. S.; Brown,Kenneth J.; Krumper,Jennifer R.; Et Al
  参考文献:Inorganic Syntheses 日期:2004 卷标:34 页码:5-8]
  
  112981-69-8 = 79060-88-1
  反应条件:1.1 Reagents: Sodium Tetrafluoroborate Solvents: Diethyl Ether
  标题:Exocyclic Stereocontrol Via Asymmetric Hydrovinylation In The General Synthesis Of Pseudopterogorgia Natural Products. Stereoselective X-Y-Mediated Cyclization Studies Of An Allene-Ynamide And An Allene-Aldehyde
  作者:Mans,Daniel J.
  参考文献:2008 卷标:69(1)]
  
  328-70-1 = 79060-88-1
  反应条件:1.1 Reagents: 1,2-Dibromoethane,Magnesium,Sodium Tetrafluoroborate Solvents: Diethyl Ether; > 1 Min,Rt1.2 Solvents: Diethyl Ether; 30 Min,Rt; 30 Min,Heated; Overnight,Rt1.3 Reagents: Sodium Carbonate Solvents: Water; 30 Min,Rt
  标题:Tunable Aryl Alkyl Ionic Liquids With Weakly Coordinating Bulky Borate Anion
  作者:Kaliner,Maria; Strassner,Thomas
  参考文献:Tetrahedron Letters 日期:2016 卷标:57(31) 页码:3453-3456]
  
  328-73-4 = 79060-88-1
  反应条件:1.1 Reagents: Magnesium Solvents: Diethyl Ether
  标题:Synthesis Of Sodium Tetrakis[3,5-Bis(Trifluoromethyl)Phenyl]Borate
  作者:Gol'Dberg,Yu. Sh.; Abele,E.; Liepins,E.; Shimanskaya,M. V.
  参考文献:Zhurnal Organicheskoi Khimii 日期:1989 卷标:25(5) 页码:1099-102]
  
  112981-69-8 = 79060-88-1
  反应条件:1.1 Reagents: Boron Trifluoride Etherate,Magnesium Solvents: Diethyl Ether; Rt; 2 H,Rt -> 50 °C; Overnight,50 °C -> Rt
  标题:Iridium(I) N-Heterocyclic Carbene (Nhc)/phosphine Catalysts For Mild And Chemoselective Hydrogenation Processes
  作者:Kerr,William J.; Mudd,Richard J.; Brown,Jack A.
  参考文献:Chemistry - A European Journal 日期:2016 卷标:22(14) 页码:4738-4742]
  
  328-70-1 = 79060-88-1
  反应条件:1.1 Reagents: Magnesium,Iodine Solvents: Diethyl Ether; 25 Min,Rt1.2 Solvents: Diethyl Ether; 65 Min,Rt; 4 H,Rt1.3 Reagents: Boron Trifluoride Etherate Solvents: Diethyl Ether; 1 H,Rt; 16 H,Reflux; Reflux -> Rt1.4 Reagents: Sodium Carbonate,Oxygen Solvents: Water; 1 H,Rt
  标题:Trialkylammonium Salt Degradation: Implications For Methylation And Cross-Coupling
  作者:Washington,Jack B.; Assante,Michele; Yan,Chunhui; Mckinney,David; Juba,Vanessa; Et Al
  参考文献:Chemical Science 日期:2021 卷标:12(20) 页码:6949-6963

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