在 Air体系中,用 Neat (No Solvent) 用作溶剂,化学反应生成氯化镧 参考文献:Rasskazova,N. A.; Murinov,Yu. I.; Yurkevich,R. V.,Russian Journal Of Inorganic Chemistry,1988,Vol. 33,P. 961-964 标题:Rasskazova,N. A.; Murinov,Yu. I.; Yurkevich,R. V.,Russian Journal Of Inorganic Chemistry,1988,Vol. 33,P. 961-964
专利信息
专利号:US-2024075466-A1 优先权日:2021-04-09 标 题:One-Pot Synthesis of Transition Metal-Promoted Chabazites 发明人:VAN TENDELOO LEEN; SCHUETZE FRANK-WALTER; VERHEYEN ELKE JANE JUNE 权利人:UMICORE AG & CO KG 摘要:The invention provides methods for a one-pot synthesis of molecular sieves of the CHA-type. The method uses molecular and non-molecular sieves as sources of silicon and aluminum. A first OSDA is selected from tetraethylenepentamine (TEPA) and triethy-lenepentamine (TETA). The synthesis mixture comprises a first metal selected from copper, iron and zinc. Optionally, the synthesis mixture may furthermore comprise a second OSDA and/or a second metal selected from manganese, cesium, magnesium, calcium, strontium, barium, yttrium, titanium, zirconium, niobium, iron, zinc, silver, lanthanum, cerium, praseodymium, neodymium, promethium, samarium, europium, gadolinium, terbium, dysprosium, holmium, erbium, thulium, ytterbium, lutetium and mixtures thereof. The molecular sieves of the CHA-type obtainable by the method can be used as SCR-catalytically active substances for the removal of nitrogen oxides from exhaust gases of combustion engines.
专利号:US-2016008797-A1 优先权日:2014-06-04 标 题:Method for the synthesis of porous inorganic material, catalytic cracking of petroleum hydrocarbons and preparation of catalyst thereof 发明人:CHEN LETIAN; CHEN JIANZHONG 权利人:ZHANJIANG GIANT SUCCESS INVEST CO LTD 摘要:A method for synthesis of porous inorganic materials, preparation of a catalyst and catalytic cracking of petroleum hydrocarbons thereof includes processes for synthesis of porous inorganic materials and preparation of the catalytic cracking catalyst and catalytic cracking of petroleum hydrocarbons. The synthesis process is advantaged in low cost in raw materials; the porous inorganic material has various pore structures; and transitional metal used overcomes the defects of the catalytic properties. The porous inorganic material serving as the main active ingredient and containing crystalline aluminum silicate zeolite structures provides surface acidity required by the catalytic reaction. The surface acidity is flexibly adjusted. The hierarchical pore profile improves the accessibility of the active center of the zeolite structure and favors the reaction efficiency and benefits of the petroleum hydrocarbon cracking, and reduces the negative effects caused by diffusion limit. The catalyst containing the porous inorganic material has low manufacturing cost and better properties.
专利号:US-7241399-B2 优先权日:2000-09-08 标题 :Synthesis of nanoparticles 发明人:HAUBOLD STEPHAN; HAASE MARKUS; RIWOTZKI KARSTEN; WELLER HORST; MEYSSAMY HEIKE; IBARRA FERNANDO 权利人:CT ANGEWANDTE NANOTECH CAN 摘要:Methods for the preparation of inorganic nanoparticles capable of fluorescence, wherein the nanoparticles consist of a host material that comprises at least one dopant. The synthesis of the invention in organic solvents allows to gain a considerably higher yield compared to the prior art synthesis in water. All kinds of objects can advantageously be marked and reliably authenticated by using an automated method on the basis of a characteristic emission. Further, the size distribution of the prepared nanoparticles is nartower which renders a subsequent size-selected separation process superfluous.
专利号:US-2007074541-A1 优先权日:2003-10-10 标 题:Synthesis of germanium sulphide and related compounds 发明人:BADDING JOHN V; HEWAK DANIEL W; HUANG CHUNG-CHE 权利人:UNIV SOUTHAMPTON 摘要:The invention relates to synthesis of germanium sulphide glasses and optical devices formed therefrom. In a chemical vapour deposition process, germanium tetrachloride is reacted with hydrogen sulphide at temperatures in the range 450-700° C. to form germanium sulphide. Lower temperatures within this range of 450-550° C. directly produce a glass, whereas higher temperatures within the range of 600-700° C. produce a crystalline powder which can then be reduced to a glass by subsequent melting and annealing. The reaction is preferably carried out at atmospheric pressure or slightly higher. Thin films and bulk glasses suitable for optical waveguides can be formed directly in one processing step as can powders and microspheres. The materials synthesised are of a high purity with low oxide impurities and only trace levels of transition metal ions.
专利号:EP-1730108-B1 优先权日:2004-03-18 标 题:Stereoselective synthesis of vitamin d analogues 发明人:SABROE THOMAS PETER; CALVERLEY MARTIN JOHN 权利人:LEO PHARMA AS 摘要:The present invention relates to intermediates useful for the synthesis of calcipotriol or calcipotriol monohydrate, to methods of producing said intermediates, and to methods of stereoselectively reducing said intermediates.
专利号:US-8759555-B2 优先权日:2004-03-18 标 题:Stereoselective synthesis of vitamin D analogues 发明人:SABROE THOMAS PETER; CALVERLEY MARTIN JOHN 权利人:SABROE THOMAS PETER; CALVERLEY MARTIN JOHN; LEO PHARMA AS 摘要:The present invention relates to intermediates useful for the synthesis of calcipotriol or calcipotriol monohydrate, to methods of producing said intermediates, and to methods of stereoselectively reducing said intermediates.
[参考文献]: Dandan Liu, Et Al. The Dual-Effects Of Lacl On The Proliferation, Osteogenic Differentiation, And Mineralization Of Mc3T3-E1 Cells. Biol Trace Elem Res. 2012 Dec;150(1-3):433-40. [参考文献]: Jie Wu, Et Al. Lanthanum Induced Primary Neuronal Apoptosis Through Mitochondrial Dysfunction Modulated By Ca2 And Bcl-2 Family. Biol Trace Elem Res. 2013 Apr;152(1):125-34. [参考文献]: Jie Zhou, Et Al. Jasmonic Acid (Ja) Acts As A Signal Molecule In Lacl(3)-Induced Baicalin Synthesis In Scutellaria Baicalensis Seedlings. Biol Trace Elem Res. 2012 Sep;148(3):392-5. [参考文献]: José R Rodríguez-Palomares, Et Al. Lanthanum Carbonate And Peritoneal Catheter Dysfunction. Nefrologia. 2012 May 14;32(3):415-6. [参考文献]: Junhui Xue, Et Al. Sugar-Metal Ion Interactions: The Coordination Behaviors Of Lanthanum With Erythritol. Carbohydr Res. 2012 Nov 1:361:12-8.
合成参考文献
参考文献:10.1007/s12011-011-9132-8 摘要:Suárez-Ortegón MF, Jiménez P, Mosquera M, Pradilla AG, Gracia AB, Aguilar de Plata C. Inverse Correlation Between Serum Calcium and Copper Levels in Male Urban Colombian Preschool Children: Relationships with Anthropometry and Age. Biological Trace Element Research. 2011 Jul 12;144(1-3):445–53. doi: 10.1007/s12011-011-9132-8.