CAS: 112-72-1; 1-Tetradecanol

相似化合物

638-59-5 70682-72-3 124-10-7

上下游产品

CAS号544-63-8 肉豆蔻酸 | CAS号124-06-1 十四酸乙酯 | CAS号629-63-0 十四腈 | CAS号124-10-7 肉豆蔻酸甲酯 | CAS号14980-92-8 2-溴十四碳酸乙酯 | CAS号21129-09-9 1,2-十四碳二醇 | CAS号21964-49-8 1,13-十四烷二烯 | CAS号110-27-0 肉豆蔻酸异丙酯 | CAS号112-41-4 1-十二烯 | CAS号109591-76-6 4-oxo-4-tetrade... | CAS号540-09-0 12-二十三酮 | CAS号542-50-7 14-二十七烷酮 | CAS号56677-60-2 氯甲酸十四烷基酯 | CAS号3234-85-3 十四酸十四酯 | CAS号544-63-8 肉豆蔻酸 | CAS号4536-26-9 十六(烷)酸十四(烷)酯 | CAS号4536-30-5 乙二醇月桂酸酯 | CAS号3055-93-4 十二烷基二乙二醇醚

十四腈置于samarium Diiodide,水,三乙胺体系中,用 四氢呋喃 用作溶剂,化学反应 2.0H,以55%的收率获得十四醇
参考文献:Electron Transfer Reduction Of Nitriles Using Smi2-et3N-h2O: Synthetic Utility And Mechanism
标题:Electron Transfer Reduction Of Nitriles Using Smi2-et3N-h2O: Synthetic Utility And Mechanism
摘要:The First General Reduction Of Nitriles To Primary Amines Under Single Electron Transfer Conditions Is Demonstrated Using Smi2 (Kagan'S Reagent) Activated With Lewis Bases. The Reaction Features Excellent Functional Group Tolerance And Represents An Attractive Alternative To The Use Of Pyrophoric Alkali Metal Hydrides. Notably,The Electron Transfer From Sm(II) To Cn Functional Groups Generates Imidoyl-Type Radicals From Bench Stable Nitrile Precursors.
Doi:10.1021/ol403668E

专利信息

专利号:US-7247752-B2
优先权日:2004-10-01
标 题 :Methods for the synthesis of astaxanthin
发明人：LOCKWOOD SAMUEL F; TANG PENG CHO; NADOLSKI GEOFF; JACKSON HENRY L; FANG ZHIQIANG; DU YISHU; YANG MIN; GEISS WILLIAM; WILLIAMS RICHARD; BURDICK DAVID
权利人:CARDAX PHARMACEUTICALS INC
摘要:A method used for synthesizing intermediates for use in the synthesis of carotenoids and carotenoid analogs, and/or carotenoid derivatives. In some embodiments, the invention includes methods for synthesizing optically active intermediates useful for the synthesis of optically active carotenoids. Synthesis of optically active carotenoids, in one embodiment, may be accomplished by forming an optically active dihydroxy intermediate from ketoisopherone. The optically active dihydroxy intermediate may be converted into optically active astaxanthin derivatives.

专利号:US-9643915-B2
优先权日:2013-03-15
标题:Methods for the synthesis of sphingomyelins and dihydrosphingomyelins
发明人：ONICIU DANIELA CARMEN; HECKHOFF STEFAN; OSWALD BENOIT; REBMANN PETER; PEER ANDREAS; GONZALEZ MIGUEL; SAUTER PATRIK
权利人:CERENIS THERAPEUTICS HOLDING SA
摘要:The present invention includes methods for the synthesis of sphingomyelins and dihydrosphingomyelins. The present invention also includes methods for the synthesis of sphingosines and dihydrosphingosines. The present invention further includes methods for the synthesis of ceramides and dihydroceramides.

专利号:US-9708354-B2
优先权日:2013-03-15
标 题:Methods for the synthesis of sphingomyelins and dihydrosphingomyelins
发明人：ONICIU DANIELA CARMEN; HECKHOFF STEFAN; OSWALD BENOIT; REBMANN PETER; PEER ANDREAS; GONZALEZ MIGUEL; SAUTER PATRIK
权利人:CERENIS THERAPEUTICS HOLDING SA
摘要:The present invention includes methods for the synthesis of sphingomyelins and dihydrosphingomyelins. The present invention also includes methods for the synthesis of sphingosines and dihydrosphingosines. The present invention further includes methods for the synthesis of ceramides and dihydroceramides.

专利号:US-6156885-A
优先权日:1997-10-30
标 题 :Process for the synthesis of alkylpolyglucosides
发明人：MERONI MARIA LUISA; PELLIZZON TULLIO
权利人:CONDEA AUGUSTA SPA
摘要:The process for the synthesis of an alkylpolyglucoside having the formula (I): n n H--(G).sub.n --O--R-- (I) n n wherein n R is linear or branched, saturated or unsaturated C 8 -C 20 alkyl; n G is a radical resulting from removal of a molecule of water from a monosaccharide; and n n is an integer from 1 to 5; n the process entailing reacting an alcohol with a monosaccharide or a compound capable of generating a monosaccharide in in situ, wherein the reaction is carried out in the presence of a catalyst consisting of one or more sterically hindered polyalkylarylsulfonic acids.

专利号:US-10730904-B2
优先权日:2012-11-14
标 题:Method for liquid-phase synthesis of nucleic acid
发明人：NONOGAWA MITSURU; NAGATA TOSHIAKI; SAITO HIDEKI; YASUMA TSUNEO
权利人:TAKEDA PHARMACEUTICALS CO
摘要:In this method, an oligonucleotide represented by formula (II) [wherein Y 1 , Q, Base, r and r′ are each as defined in claim 1 ] is prepared by using, as a synthesis unit, a novel nucleoside monomer compound represented by formula (I) [wherein X, R 1 , Y, Base, Z, Ar, R 2 , R 3 and n are each as defined in claim 1 ]. The novel nucleoside monomer compound is a nucleoside, the base moiety of which is substituted with an aromatic-hydrocarbon-ring-carbonyl or -thiocarbonyl group having at least one hydrophobic group. The method can dispense with column-chromatographic purification in every reaction, and enables base elongation not only in the 3′-direction but also in the 5′-direction, thus attaining efficient liquid-phase mass synthesis of an oligonucleotide.

专利号:US-5919969-A
优先权日:1996-06-05
标 题 :Synthesis of yellow couplers
发明人：CRAWLEY MICHAEL W
权利人:EASTMAN KODAK CO
摘要:The invention provides a method of synthesis of a image-dye forming coupler of formula (I) wherein X is a substituent linked to the coupler by an atom of oxygen, sulfur or nitrogen R1 is an alkyl or aryl group, R2 is a hydrogen atom or an alkyl group; R3 to R7 are the same or different and selected from a hydrogen atom and substituent groups; which method comprises the reaction of a compound of formula (II) wherein R and R1 are the same or different and are as defined above for R1 and X is as defined above with a compound of formula (III) wherein R2 to R7 are as defined above, in the presence of an inert organic solvent.