Diethyl Selenite,肼 反应生成 硒 参考文献:Badesha,S. S.;Monczka,P.;Smith,S. D.,Can. J. Chem.,1983,61,N 9,2199-2202 标题:Badesha,S. S.;Monczka,P.;Smith,S. D.,Can. J. Chem.,1983,61,N 9,2199-2202
专利信息
专利号:US-5936080-A 优先权日:1996-05-24 标题 :Compositions and methods for the synthesis of organophosphorus derivatives 发明人:STEC WOJCIECH J; WOZNIAK LUCYNA 权利人:GENTA INC; POLSKA AKADEMIA NAUK INSTYTUT 摘要:New organophosphorus mononucleoside derivatives, methods of their synthesis and methods for the synthesis of organophosphorus dinucleotide derivatives utilizing the organophosphorus mononucleosides are provided. Synthesized organophosphorus mononucleoside derivatives of the present invention are characterized by the formula; ##STR1## Organophosphorus dinucleoside derivatives prepared from the synthesis methods provided in the present invention are characterized by the formula; ##STR2##
专利号:US-2012103789-A1 优先权日:2010-10-28 标题:Greener Synthesis of Nanoparticles Using Fine Tuned Hydrothermal Routes 发明人:MAYE MATHEW 权利人:MAYE MATHEW; UNIV SYRACUSE 摘要:The synthesis of energy and sensor relevant nanomaterials that involves the colloidal synthesis of quantum dots (e.g. CdSe, CdS, ZnS, CdSe/ZnS) under well-controlled hydrothermal conditions (100-200 degrees C.) using simple inorganic precursors. The resulting nanomaterials are of high quality, and are easily processed depending upon application, and their synthesis is scalable. Scalability is provided by the use of a synthetic microwave reactor, which employs dielectric heating for the rapid and controllable heating.
专利号:WO-2018020240-A1 优先权日:2016-07-27 标 题:Process for the synthesis of semiconductor nanocrystals 发明人:HOU BO; CHA SEUNGNAM 权利人:UNIV OXFORD INNOVATION LTD 摘要:The invention relates to a process for the synthesis of semiconductor nanocrystals, comprising mixing a nonaqueous solution of a metal precursor with a solid-state chalcogen and reacting the resulting mixture at a temperature of about 90 °C or greater. In another aspect the invention relates to the use of a solid chalcogen in the heterogeneous synthesis of metal chalcogenide semiconductor nanocrystals. Semiconductor nanocrystals obtainable by the processes of the invention are further provided. In particular, nanocrystalline PbS or PbSe having a band gap of greater than 1.6 eV and/or a photoluminescence emission wavelength of about 440 to about 515 nm, and nanocrystalline ZnS or ZnSe having a photoluminescence emission wavelength of about 410 to about 430 nm, and solar cells comprising such nanocrystals, are provided.
专利号:US-5856465-A 优先权日:1996-05-24 标 题:Compositions and methods for the synthesis of chirally pure organophosphorus nucleoside derivatives 发明人:STEC WOJCIECH JACEK; WOZNIAK LUCYNA 权利人:POLSKA AKAD NAUK CENTRUM 摘要:Methods for the stereospecific synthesis of chirally pure organophosphorus dinucleotide derivatives and nucleoside monomer synthons used in their synthesis are provided. These methods allow for conversion of nucleoside intermediates of unchosen sense of P-chirality to nucleoside monomer synthons of chosen sense of P-chirality. Also provided are novel nucleoside intermediates useful in such methods.
专利号:US-2006287520-A1 优先权日:2005-05-16 标 题 :Synthesis of salinosporamide A and analogues thereof 发明人:DANISHEFSKY SAMUEL J; ENDO ATSUSHI 权利人:DANISHEFSKY SAMUEL J; ENDO ATSUSHI 摘要:A novel synthesis of salinosporamide A is provided. Salinospoamide A as well as structurally related natural products, omuralide and lactacystin, have been shown to be proteasome inhibitors. Therefore, these compounds as well as analogues of these natural products may be useful in the treatment of proliferative diseases such as cancer, autoimmune diseases, diabetic retinopathy, etc. The invention provides for the synthesis of salinosporamide A as well as analogs thereof using a convenient point for derivatization of the bicyclic core. Pharmaceutical compositions and method of using the inventive compounds are also provided.
专利号:US-4801744-A 优先权日:1985-03-01 标 题 :Catalytic synthesis of urea from carbon monoxide and amine compound 发明人:HERMAN JEAN-JACQUES; LECLOUX ANDRE 权利人:SOLVAY 摘要:Process for the catalytic synthesis of nitrogen-containing organic compounds, comprising the reaction of carbon monoxide with at least one amino compound in a reaction mixture containing a catalyst based on selenium and a substituted pyridine. The process is particularly suitable for the synthesis of ureas and of their polymers.
参考文献:10.1080/01635580903285189 摘要:Çavdar AO, Gözdaşoğlu S, Babacan E, Mengübaş K, Ünal E, Yavuz G, Taçyildiz N. Zinc and Selenium Status in Pediatric Malignant Lymphomas. Nutrition and Cancer. 2009 Nov 10;61(6):888–90. doi: 10.1080/01635580903285189. 参考文献:10.1021/ja908201x 摘要:Qin B, Chen H, Liang H, Fu L, Liu X, Qiu X, Liu S, Song R, Tang Z. Reversible photoswitchable fluorescence in thin films of inorganic nanoparticle and polyoxometalate assemblies. J Am Chem Soc. 2010 Mar 10;132(9):2886–8. doi: 10.1021/ja908201x. 参考文献:10.1177/1740774509357227 摘要:Cook ED, Arnold KB, Hermos JA, McCaskill-Stevens W, Moody-Thomas S, Probstfield JL, Hamilton SJ, Campbell RD, Anderson KB, Minasian LM. Impact of supplemental site grants to increase African American accrual for the Selenium and Vitamin E Cancer Prevention Trial. Clinical Trials. 2010 Feb;7(1):90–9. doi: 10.1177/1740774509357227. 参考文献:10.1074/jbc.m109.088781 摘要:Wu M, Kang MM, Schoene NW, Cheng W. Selenium Compounds Activate Early Barriers of Tumorigenesis. Journal of Biological Chemistry. 2010 Apr;285(16):12055–62. doi: 10.1074/jbc.m109.088781. 参考文献:10.1002/anie.200905053 摘要:Kikkeri R, Laurino P, Odedra A, Seeberger PH. Synthesis of carbohydrate-functionalized quantum dots in microreactors. Angew Chem Int Ed Engl. 2010 Mar 08;49(11):2054–7. doi: 10.1002/anie.200905053.