CAS: 85877-79-8; Trimethoxy(3,3,4,4,5,5,6,6,6-Nonafluorohexyl)Silane

上下游产品

sodium methylate trichloro(1H,1H,2H,2H-nonafluorohexyl)silane 3,3,4,4,5,5,6,6,6-Nonafluoro-1-hexene (vinyl)trimethoxylsilane

1H,1H,2H-全氟-1-己烯置于dihydrogen Hexachloroplatinate,三氯硅烷体系中,用 甲醇,1,1,2-三氯三氟乙烷(cfc-113) 作为反应溶剂,化学反应 71.0H,反应生成 1H,1H,2H,2H-九氟己基三甲氧基硅烷
参考文献:金属有机物的合成和反应.十八.(1H,1H,2H,2H-多氟烷基)三甲氧基硅烷的合成及玻璃板的表面改性
标题:金属有机物的合成和反应.十八.(1H,1H,2H,2H-多氟烷基)三甲氧基硅烷的合成及玻璃板的表面改性
摘要:四种硅烷偶联剂,(1H,1H,2H,2H-多氟烷基)三甲氧基硅烷((1H,1H,2H,2H-二十碳氟十二烷基)三甲氧基硅烷,C10F21C2H4Si(och3)3,(1H,1H,2H,2H-十七氟癸基)三甲氧基硅烷,C8F17C2H4Si(och3)3,(1H,1H,2H,2H-十三氟辛基)三甲氧基硅烷,C6F13C2H4Si(och3)3和(1H,1H,2H,2H-九氟己基)三甲氧基硅烷,C4F9C2H4Si(och3)由三氯硅烷与相应的 1H,1H,2H-多氟-1-烯烃在六氯铂酸 (Iv) 存在下氢化硅烷化,然后与甲醇钠反应.尝试使用这些产品对玻璃板进行表面改性.通过测量水和油酸对改性玻璃板表面的接触角 θ (°),发现偶联剂具有高改性能力.
DOI:10.1246/bcsj.66.1754

专利信息

专利号:US-9981239-B2
优先权日:2015-04-21
标题:Devices and methods for oligonucleic acid library synthesis
发明人：BANYAI WILLIAM; PECK BILL JAMES; FERNANDEZ ANDRES; CHEN SIYUAN; INDERMUHLE PIERRE; MARSH EUGENE P
权利人:TWIST BIOSCIENCE CORP
摘要:Devices and methods for de novo synthesis of large and highly accurate libraries of oligonucleic acids are provided herein. Devices include structures having a main channel and microchannels, where the microchannels have a high surface area to volume ratio. Devices disclosed herein provide for de novo synthesis of oligonucleic acids having a low error rate.

专利号:US-2018104664-A1
优先权日:2016-08-03
标 题 :Textured surfaces for polynucleotide synthesis
发明人：FERNANDEZ ANDRES; INDERMUHLE PIERRE; MARSH EUGENE P; BANYAI WILLIAM; PECK BILL JAMES
权利人:TWIST BIOSCIENCE CORP
摘要:Methods, devices and systems are provided herein for surfaces for de novo polynucleotide synthesis that provide for increased polynucleotide yield. Surfaces described herein comprise a texture that increases surface area provide for increased polynucleotide yield compared to non-textured surfaces. In addition, the patterned placement of nucleoside coupling reagent spanning such surfaces provides for improved synthesis yield, representation, and a reduction in contamination on the surface between different polynucleotide species.

专利号:US-11970697-B2
优先权日:2020-10-19
标 题:Methods of synthesizing oligonucleotides using tethered nucleotides
发明人：LACKEY JEREMY; DODD DAVID
权利人:TWIST BIOSCIENCE CORP
摘要:Disclosed herein are methods and compositions comprising a polymerase and a phosphorylated nucleoside, wherein the polymerase and the nucleoside are covalently linked by a cleavable linker at the terminal phosphate group. Further disclosed herein are enzymatic polynucleotide synthesis using polymerase and nucleotide conjugation strategies.

专利号:US-10954139-B2
优先权日:2015-12-11
标 题:Oleophilic foams for oil spill mitigation
发明人：DARLING SETH B; ELAM JEFFREY W; MANE ANIL U
权利人:UCHICAGO ARGONNE LLC
摘要:A method of fabricating an oleophilic foam includes providing a foam comprising a base material. The base material is coated with an inorganic material using at least one of an atomic layer deposition (ALD), a molecular layer deposition (MLD) or sequential infiltration synthesis (SIS) process. The SIS process includes at least one cycle of exposing the foam to a first metal precursor for a first predetermined time and a first partial pressure. The first metal precursor infiltrates at least a portion of the base material and binds with the base material. The foam is exposed to a second co-reactant precursor for a second predetermined time and a second partial pressure. The second co-reactant precursor reacts with the first metal precursor, thereby forming the inorganic material on the base material. The inorganic material infiltrating at least the portion of the base material. The inorganic material is functionalized with an oleophilic material.

专利号:US-11351478-B2
优先权日:2018-09-06
标题 :Oil skimmer with oleophilic coating
发明人：DARLING SETH B; ELAM JEFFREY W
权利人:UCHICAGO ARGONNE LLC
摘要:A method of fabricating an coating includes providing a coating comprising a base material. The base material is coated with an inorganic material using at least one of an atomic layer deposition (ALD), a molecular layer deposition (MLD), or sequential infiltration synthesis (SIS) process. The SIS process includes at least one cycle of exposing the coating to a first metal precursor for a first predetermined time and a first partial pressure. The first metal precursor infiltrates at least a portion of the base material and binds with the base material. The coating is exposed to a second co-reactant precursor for a second predetermined time and a second partial pressure. The second co-reactant precursor reacts with the first metal precursor, thereby forming the inorganic material on the base material. The inorganic material infiltrating at least the portion of the base material. The inorganic material is functionalized with a material.

专利号:US-10870917-B2
优先权日:2016-07-08
标 题:Functionalized foams
发明人：DARLING SETH B; ELAM JEFFREY W; MANE ANIL U; SNYDER SETH W
权利人:UCHICAGO ARGONNE LLC
摘要:A method of fabricating an foam includes providing a foam comprising a base material. The base material is coated with an inorganic material using at least one of an atomic layer deposition (ALD), a molecular layer deposition (MLD), or sequential infiltration synthesis (SIS) process. The SIS process includes at least one cycle of exposing the foam to a first metal precursor for a first predetermined time and a first partial pressure. The first metal precursor infiltrates at least a portion of the base material and binds with the base material. The foam is exposed to a second co-reactant precursor for a second predetermined time and a second partial pressure. The second co-reactant precursor reacts with the first metal precursor, thereby forming the inorganic material on the base material. The inorganic material infiltrating at least the portion of the base material. The inorganic material is functionalized with a material.