(氯甲基)甲基二氯硅烷,原甲酸三甲酯 反应 4.0H,以87%的收率获得氯甲基甲基二甲氧基硅烷 参考文献:Synthesis And Properties Of Functionalized Alkylalkoxysilanes 标题:Synthesis And Properties Of Functionalized Alkylalkoxysilanes 摘要:A Method Of Chloroalkylalkoxysilanes Synthesis Scalable To Pilot Production Has Been Proposed. Morpholinotrialkoxysilanes Have Been Prepared And Studied As Vulcanizing Agents For Low-Molecular Silicone Rubbers. The Reaction Of N-Morpholinomethyltrialkoxysilanes With Triethanolamine Has Afforded N-[(Silatranyl)Methyl]Morpholine; It Has Been Studied By X-Ray Analysis. Doi:10.1134/s1070363216080144
专利号:US-9884879-B2 优先权日:2011-06-14 标 题:Method of synthesizing siloxane monomers and use thereof 发明人:PAULASAARI JYRI 权利人:SILECS OY 摘要:A method for preparation and polymerization of siloxane monomers of Formula I is presented. The synthesis includes the selective reaction between silanol containing unit and alkoxy containing units in the presence of basic catalyst. The siloxane monomers of the invention can be used for preparation of siloxane polymers with good flexibility and cracking threshold, and functional sites, useful for applications requiring low metal content in semiconductor industry.
专利号:SU-596591-A1 优先权日:1974-08-05 标题 :Silyl esters of adamantane-1-carboxylic acids for synthesis of polyorganosiloxanes
专利号:CN-101177446-B 优先权日:2007-12-18 标 题:A New Stereoselective Chemical Synthesis of Drospirenone
专利号:CN-109897185-A 优先权日:2019-03-18 标题 :A side chain containing vinyl and quaternary ammonium salt polysiloxane and its synthesis method and application in the preparation of antibacterial silicone rubber
参考标题:Chiral Acylsilanes In Organic Synthesis. Diastereoselective 1,2-Additions To Racemic Alkoxymethyl-Substituted Acylsilanes 作者:Stefan Bienz,Alexander Chapeaurouge |发布日期:1991.10.30 摘要:The Synthesis Of The Three Alkoxymethyl-Substituted Acyisilanes 1-3 Is Described (Schemes 1 And 2). Their Reactions With Nabh4 As Well As Phli Gave The Corresponding Alcohols With Moderate To Good Diastereoisomeric Induction (Up To 78% De; See Table), Depending Upon The Solvent Used (Scheme 3). The Results Indicate That In Et2O, The Reactions With Phli Proceed Via 6-Membered Chelates (See C In Scheme
合成参考文献
参考文献:10.1134/s1070363216080144 摘要:Lebedev AV, Minas’yan RM, Abramkin AM, Sheludyakov VD, Kuzmina NE, Lebedeva AB, Surikov GE, Rybakov VB. Synthesis and properties of functionalized alkylalkoxysilanes. Russian Journal of General Chemistry. 2016 Aug;86(8):1859–63. doi: 10.1134/s1070363216080144. 参考文献:10.1023/a:1017994916574 摘要:Voronkov MG, Trofimova OM, Bolgova YI, Chernov NF. New Organosilicon Derivatives of Nitrogen-containing Heterocycles. Chemistry of Heterocyclic Compounds. 2001 Nov;37(11):1358–68. doi: 10.1023/a:1017994916574. 参考文献:10.1007/bf00906815 摘要:Zhdanov AA, Pakhomov VI, Arkhipov IA. The reaction of chloromethylalkoxysilanes with aminoethoxyalkyl silanes. Russian Chemical Bulletin. 1967 Aug;16(8):1698–702. doi: 10.1007/bf00906815. 参考文献:10.1007/bf00853381 摘要:Zhdanov AA, Pakhomov VI, Arkhipov IA. Reaction of chloromethylalkoxysilanes with N-phenylaminoethoxy (alkyl) silanes. Russian Chemical Bulletin. 1970 Feb;19(2):338–41. doi: 10.1007/bf00853381.