专利号:US-12291596-B2 优先权日:2018-11-30 标 题 :Radical cascade-enabled synthesis of precision polymers with complex main-chain structures 发明人:NIU JIA; HUANG HANCHU; WANG WENQI 权利人:THE TRUSTEES OF BOSTON COLLEGE 摘要:Radical cascade reactions enabling sequence-controlled ring-closing polymerization and ring-opening polymerization for the controlled synthesis of polymers with complex main-chain structures are provided. Facile syntheses leading to low-strain macrocyclic monomers consisting of the ring-opening triggers and extended main-chain structures are also provided. The present disclosure further provides methods for excellent control over polymer molecular weights and molecular weight distributions and high chain-end fidelity allows for the preparation of polymeric systems with well-defined architectures. Further provided are the general nature of the radical cascade-triggered transformations in polymer chemistry, and its application to the synthesis of polymers with diverse main-chain structural motifs with tailored functions. This abstract is intended as a scanning tool for purposes of searching in the particular art and is not intended to be limiting of the present disclosure.
专利号:US-2022297078-A1 优先权日:2019-08-08 标题 :Sonochemical synthesis of particles 发明人:POZZO LILO D; KASTILANI RYAN; BISHOP BRITTANY P; LI DAVID SHICHENG 权利人:UNIV WASHINGTON 摘要:Sonochemical synthesis methods of particles (e.g., nanoparticles, microparticles, quantum dots) in emulsion reaction mixtures are described herein. The methods allow for control of the bulk temperature of the reaction mixtures to minimize the effects of solvent temperature increases. The sonochemical synthesis methods (e.g., in emulsion reaction mixtures) offer efficient, accelerated, and controllable pathways towards the on-demand synthesis of complex materials.
专利号:US-2024309024-A1 优先权日:2023-03-14 标题 :Direct synthesis of alkenylhalosilanes 发明人:LEWIS KENRICK MARTIN; ZHU YANJUN; BYRNE CHRISTOPHER M 权利人:MOMENTIVE PERFORMANCE MAT INC 摘要:A process for the direct synthesis of alkenylhalosilane monomers. Forming a slurry of liquid and copper-activated silicon from fresh silicon, cyclone fines and/or fine dust from silicon grinding, ultrafines and/or spent contact mass from the Direct Synthesis of alkylhalosilanes and arylhalosilanes, in a thermally stable solvent. Reacting the silanes by agitating the slurry with at least one unsaturated aliphatic or cycloaliphatic organohalide of the formula R1X, and optionally an organohalosilane and/or hydrogen halide, in the presence of a polymerization inhibiting Lewis base additive, at a reaction time, temperature and pressure effective to produce alkenylhalosilanes having the formulae, R1SiHX2, R12SiHX, R13SiX, R1SiX3, and R12SiX2 or mixtures thereof.
专利号:US-11186678-B2 优先权日:2018-11-30 标 题 :Radical cascade-enabled synthesis of precision polymers with complex main-chain structures 发明人:NIU JIA; HUANG HANCHU; WANG WENQI 权利人:TRUSTEES BOSTON COLLEGE 摘要:Radical cascade reactions enabling sequence-controlled ring-closing polymerization and ring-opening polymerization for the controlled synthesis of polymers with complex main-chain structures are provided. Facile syntheses leading to low-strain macrocyclic monomers consisting of the ring-opening triggers and extended main-chain structures are also provided. The present disclosure further provides methods for excellent control over polymer molecular weights and molecular weight distributions and high chain-end fidelity allows for the preparation of polymeric systems with well-defined architectures. Further provided are the general nature of the radical cascade-triggered transformations in polymer chemistry, and its application to the synthesis of polymers with diverse main-chain structural motifs with tailored functions. This abstract is intended as a scanning tool for purposes of searching in the particular art and is not intended to be limiting of the present disclosure.
专利号:US-9920349-B2 优先权日:2011-11-23 标题:Methods and materials for enzymatic synthesis of mogroside compounds 发明人:LIU YAOQUAN; LEE JUNG YEOP; KHARE MONIKA 权利人:EVOLVA SA 摘要:Methods and materials for enzymatic synthesis of mogroside compounds described.
专利号:WO-2024246574-A1 优先权日:2023-06-02 标题:METHOD OF SYNTHESIS OF COLLOIDAL InSb QUANTUM DOTS 发明人:REISS PETER; KWON YONGJU 权利人:COMMISSARIAT A LENERGIE ATOMATIQUE ET AUX ENERGIES ALTERNATIVES; CENTRE NAT RECH SCIENT; UNIV GRENOBLE ALPES 摘要:The present invention relates to a method of synthesis of colloidal InSb quantum dots (InSb QDs) comprising a premixing step of In and Sb precursors at a temperature of less than 100°C, under stirring.
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