CAS: 15243-33-1; Triruthenium Dodecacarbonyl

上下游产品

ruthenium trichloride hydrate carbon monoxide ruthenium tetracarbonyl ruthenium(III) chloride trihydrateRu3(CO)10(μ-bis(diphenylphosphino)methane) ruthenium carbon monoxide (0)tricarbonylbis(triphenylphosphine)ruthenium(0)

H(μ-H)Ru3(Co)11置于一氧化碳体系中,用 甲醇 用作溶剂,以95.7%的收率获得十二羰基三钌
参考文献:Nevinger,Leigh R.; Keister,Jerome B.; Maher,John,Organometallics,1990,Vol. 9,# 6,P. 1900-1905
标题:Nevinger,Leigh R.; Keister,Jerome B.; Maher,John,Organometallics,1990,Vol. 9,# 6,P. 1900-1905

专利信息

专利号:US-4794199-A
优先权日:1984-07-05
标题:Process for synthesis of primary amines from olefins, syngas and ammonia
发明人：LIN JIANG-JEN; KNIFTON JOHN F
权利人:TEXACO INC
摘要:This invention concerns the synthesis of primary amines from olefins, synthesis gas and ammonia via an amination process in the presence of a cobalt catalyst, an ether solvent and a tertiary group VB donor ligand.

专利号:US-4709034-A
优先权日:1986-02-14
标 题 :Process for the synthesis of hydroxyalkyl amines and hydroxyalkyl piperazines
发明人：MARSELLA JOHN A
权利人:AIR PROD & CHEM
摘要:The present invention comprises a process for the synthesis of hydroxyalkyl amines, hydroxyalkyl piperazines, or alkyl piperazines from alkylene glycols and ammonia or alkyl amines using a substantially soluble transition metal carbonyl complex catalyst precursor.

专利号:US-7273509-B1
优先权日:2001-12-10
标 题 :Synthesis of metal nanoparticle compositions from metallic and ethynyl compounds
发明人：KELLER TEDDY M; QADRI SYED B
权利人:US OF AMERICA AS OF OF AMERICA
摘要:A process of making metal nanoparticles comprising the steps of: providing a precursor composition comprising at least one metallic compound and at least one organic compound; wherein the organic compound is selected from the group consisting of an ethynyl compound, a metal-ethynyl complex, and combinations thereof; wherein the precursor composition is a liquid or a solid at room temperature; and heating the precursor composition under conditions effective to produce metal nanoparticles. A metal nanoparticle composition comprising metal nanoparticles dispersed homogenously in a matrix selected from the group consisting of ethynyl polymer, crosslinked ethynyl polymer, amorphous carbon, carbon nanotubes, carbon nanoparticles, graphite, and combinations thereof.

专利号:US-12017206-B2
优先权日:2021-09-30
标 题 :Preparation method of Cu—Pd—CeO2/γ—Al2O3@NP catalyst and synthesis method of benzopyrazine compounds
发明人：FENG FENG; LI XIAONIAN; GUO LINGLING; SUN YANXIA; LU CHUNSHAN; ZHANG QUNFENG; Jin Jiatong; XU XIAOLIANG
权利人:UNIV ZHEJIANG TECHNOLOGY
摘要:A preparation method of Cu—Pd—CeO 2 /γ-Al 2 O 3 @NP catalyst and a synthesis method of benzopyrazine compounds. The preparation method of the Cu—Pd—CeO 2 /γ-Al 2 O 3 @NP catalyst comprises the following steps: (1) preparing a CeO 2 /γ-Al 2 O 3 carrier; (2) preparing a CeO 2 /γ-Al 2 O 3 @NP carrier; (3) preparing the Cu—Pd—CeO 2 /γ-Al 2 O 3 @NP catalyst by impregnation method. A one-pot method for synthesizing benzopyrazine compounds of formula (III) includes using an o-nitroaniline compound of formula (I) and an aliphatic diol compound of formula (II) as raw materials, carrying out the one-pot synthesis of the benzopyrazine compound of formula (III) under solvent-free condition and under the combined action of the Cu—Pd—CeO 2 /γ-Al 2 O 3 @NP catalyst prepared by the method and an alkali. The Cu—Pd—CeO 2 /γ-Al 2 O 3 @NP catalyst increases the number of basic sites by doping N and P, and meanwhile loads CeO 2 to assist in the extraction of protons, thereby improving the dehydrogenation activity and product selectivity.

专利号:US-6903044-B2
优先权日:2001-05-18
标题:One-step production of 1,3-propanediol from ethylene oxide and syngas with a catalyst with a N-heterocyclic ligand
发明人：KNIFTON JOHN FREDERICK; JAMES TALMADGE GAIL; ALLEN KEVIN DALE; WEIDER PAUL RICHARD; POWELL JOSEPH BROUN; SLAUGH LYNN HENRY; WILLIAMS TIMOTHY
权利人:SHELL OIL CO
摘要:Disclosed is a new catalyst composition comprising a bimetallic Co—Ru catalyst complexed with a N-heterocylcic ligand that is effective, economical, and provides improvements in oxidative stability in the one step synthesis of 1,3-propanediol (1,3-PDO) from ethylene oxide and synthesis gas. For example, cobalt-ruthenium-2,2′-bipyrimidine, 2,2′-dipyridyl, or 2,4,6-tripridyl-s-triazine catalyst precursors in cyclic ether solvents, such as 1,3-dioxolane, 1,4-dioxolane, 1,4-dioxane, and 2-ethyl-2-methyl-1,3-dioxolane, provide good yields of 1,3-PDO in a one step synthesis.

专利号:US-2011172437-A1
优先权日:2008-04-01
标题:Perfluorophthalocyanine Molecules and Methods of Synthesis
发明人：GORUN SERGIU M; GERDES ROBERT; GERDES OLGA; LAPOK LUKASZ
权利人:NEW JERSEY TECH INST
摘要:Advantageous methods for synthesis of fluorinated phthalocyanines are provided. Typical implementation involves a reaction mixture that includes perfluoro compound that is reacted for a reaction period sufficient to yield a fluorinated phthalocyanine of formula F 64 PcM, wherein “Pcâ€? is any phthalocyanine macrocycle and “Mâ€? is hydrogen. Novel fluorinated phthalocyanine molecules/compounds are also provided herein, including specifically compounds that include fluorinated phthalocyanines wherein “Mâ€? is Cu or Vâ•?O. The fluorinated phthalocyanines have wide ranging applications, e.g., corrosion-related applications, coating-related applications, catalysis, and the production of optical and electronic materials.