CAS: 4499-86-9; Tetrapropylammonium Hydroxide

相似化合物

4499-86-9 5810-42-4 631-40-3

上下游产品

CAS号1941-30-6 四丙基溴化铵 | CAS号338-38-5 四丙基氟硼酸铵 | CAS号102-69-2 三正丙胺 | CAS号187737-37-7 propene

四丙基溴化铵置于potassium Hydroxide体系中,用 二氯甲烷 作为反应溶剂,化学反应 10.0H,以82%的收率获得产物四丙基氢氧化铵
参考文献:温度对铵离子液体与n,N-二甲基甲酰胺分子相互作用的影响
标题:温度对铵离子液体与n,N-二甲基甲酰胺分子相互作用的影响
摘要:鉴于n,N-二甲基甲酰胺(dmf)的高极性化合物与铵离子液体(ils)之间的广泛分子相互作用,我们已经测量了热物理性质,例如密度(ρ)和超声波速度(u).整个组合物的温度范围为大气压下25至50oc.为了对这些混合溶剂中存在的分子相互作用的几种聚集有一些了解,我们预测了过量的摩尔体积(v E)和等熵可压缩性的偏差(δk S)作为il浓度的函数.这些结果适合redlich-Kister多项式.在本研究中研究的材料包括氢氧化四甲基铵[(ch 3)4 N] [oh](tmah),氢氧化四乙铵[(c 2 H 5)4 N] [oh](teah)的氢氧化物系列氢氧化物.和氢氧化四丙基铵[(c 2 H 7)4N] [oh](tpah).分子间的相互作用和结构效应的基础上,测量和推导的性质进行了分析.关于离子-偶极子和离子对的相互作用,以及il和dmf分子之间的氢键及其结构因素,对结果进行了定性分析.
DOI:10.1021/jp108003X

专利信息

专利号:US-10618855-B2
优先权日:2016-06-07
标题:Catalyst and method for synthesis of aromatic hydrocarbons through direct conversion of synthesis gas
发明人：PAN XIULIAN; YANG JUNHAO; JIAO FENG; ZHU YIFENG; BAO XINHE
权利人:DALIAN INST CHEM & PHYSICS CAS
摘要:Synthesis of aromatic hydrocarbons from synthesis gas in a fixed bed or a moving bed reactor loaded with a composite catalyst comprising Catalyst Component A and Catalyst Component B mixed via a mechanical mixing mode, wherein the active ingredient of the Catalyst Component A is active metal oxides; and the Catalyst Component B is one or both of ZSM-5 zeolite and metal modified ZSM-5; the pressure of the synthesis gas is 0.1-6 MPa; the reaction temperature is 300-600° C.; and the space velocity is 500-8000 h −1 . The reaction process has a high product yield and selectivity, with the selectivity of aromatics reaching 50-85%, while the selectivity of the methane byproduct is less than 15%.

专利号:US-7901664-B2
优先权日:2008-03-31
标题 :Synthesis of aluminophosphate and metalloaluminophosphate molecular sieves
发明人：CAO GUANG; AFEWORKI MOBAE; SHAH MATU J; MERTENS MACHTELD MARIA
权利人:EXXONMOBIL CHEM PATENTS INC
摘要:In a method of synthesizing an aluminophosphate or metalloaluminophosphate molecular sieve, a synthesis mixture is provided comprising water, a source of aluminum, a source of phosphorus, optionally a source of a metal other than aluminum, a tertiary amine, and an alkylating agent capable of reacting with said tertiary amine to form a quaternary ammonium compound capable of directing the synthesis of said molecular sieve. The synthesis mixture is maintained under conditions sufficient to cause the alkylating agent to react with the tertiary amine to produce the quaternary ammonium compound and to induce crystallization of the molecular sieve.

专利号:US-6540970-B1
优先权日:1999-11-18
标题:Method for the synthesis of molecular sieves
发明人：STROHMAIER KARL G; VAUGHAN DAVID E W
权利人:EXXON MOBIL CHEM PATENTS INC
摘要:The present invention provides a method for the synthesis of MeAPO molecular sieves which includes the following steps: providing a source of alumina, a source of phosphorus, water, and a template suitable for forming a MeAPO molecular sieve; providing a source of metal (Me) including metal particles, the metal particles measuring, in their largest dimension, equal to or less than five nanometers; providing a water soluble organic solvent capable of solubilizing the source of metal; forming a synthesis mixture from the source of alumina, the source of phosphorus, the water, the template, the source of metal, and the solvent; and forming a MeAPO molecular sieve from the synthesis mixture.

专利号:EP-1220823-B1
优先权日:1999-09-30
标题:Process for the synthesis of 2-hydroxyphenyl alkyl ketones
发明人：BORZATTA VALERIO; POLUZZI ELISA; VACCARI ANGELO
权利人:ENDURA SPA
摘要:A process is described for the synthesis of 2-hydroxyphenylalkyl ketones, by means of catalytic rearrangement of phenolic esters. This process is characterized by the use, as catalysts, of crystalline aluminosilicates of the pentasyl type having predefined values of silica/alumina ratio, grain size, surface area and porosity, and containing between 10 wt% and 40 wt% of finely ground alumina as bonding agent. The rearrangement thus catalyzed involves a high conversion of the phenolic ester, a high orthoselectivity and a low formation of phenolic by-products, thus enabling the formation of the end product in high yields. In particular, the process applies to the synthesis of 2-hydroxyacetophenone.

专利号:US-2008103312-A1
优先权日:2006-08-29
标 题:Processes for the synthesis of 5-phenyl-1-trityl-1H-tetrazole
发明人：KANSAL VINOD K; MISTRY DHIRENKUMAR N; VASOYA SANJAY L; LUNAGARIYA VIJAYKUMAR D
权利人:KANSAL VINOD K; MISTRY DHIRENKUMAR N; VASOYA SANJAY L; LUNAGARIYA VIJAYKUMAR D
摘要:Provided are processes for the synthesis of 5-phenyl-1-trityl-1H-tetrazole, an intermediate useful in the synthesis of irbesartan.

专利号:US-11554348-B2
优先权日:2016-11-10
标 题 :Method of preparing hierarchical porous channel molecular sieve membrane and application thereof
发明人：GU XUEHONG; YAO XUN; PENG LI
权利人:NANJING UNIVERSITY OF TECHNOLOGY
摘要:The invention relates to a method for preparing a hierarchical porous zeolite membrane and an application thereof, comprising the following steps: a mesoporous structure-directing agent is added to limit the growth of zeolite crystals, and self-assembled in the crystallization process to generate a mesoporous structure. Based on a seed crystal induced secondary nucleation mechanism, this method can realize one-step hydrothermal synthesis of hierarchical porous zeolite membrane with the advantages of mild and controllable synthesis conditions, simple process, good repeatability, reduced energy consumption and cost savings. The hierarchical porous zeolite membrane prepared by the method has good cut-off performance, and the cut-off molecular weight is adjustable between 200 to 500,000 Da.