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CAS号109-75-1 3-丁烯腈 | CAS号10025-78-2 三氯氢硅 | CAS号18301-86-5 3-氰基丙基三甲基硅烷 | CAS号1067-47-6 4-(三乙氧基)硅基丁腈 | CAS号17012-93-0 5-(Trimethylsil... | CAS号4390-84-5 4-silylbutanenitrile

烯丙基腈置于三氯硅烷体系中,化学反应生成(3-氰丙基)三氯硅烷
参考文献:γ 射线引发的反应.二,向烯烃中添加氢化硅1
标题:γ 射线引发的反应.二,向烯烃中添加氢化硅1
摘要:三氯硅烷和甲基二氯硅烷在作为引发剂的伽马射线存在下添加到某些烯烃的双键上.这些化合物包括辛烯-1,异丁烯,丁烯-2,2-甲基-2-丁烯,环戊烯,环己烯,1-甲基环己烯,烯丙基氯,乙酸烯丙酯,烯丙基氰,顺式1,2-二氯乙烯,3,3,4,4,4-五氟-1-丁烯,2-甲基-2,3,4,4,4-五氟-1-丁烯,3,3,4,4,5,5,5-七氟-1-戊烯和2-甲基-3,3,4,4,5,5,5-七氟-1-戊烯.肉桂酸乙酯,富马酸二乙酯,茚和反式二苯乙烯不反应.苯乙烯和α-甲基苯乙烯得到高沸点硅聚合物.除了饱和单体加合物的分离外,还获得了一些高沸点烷基甲硅烷基取代的衍生物.以这种方式获得的一些加合物转化为其四烷基甲硅烷基衍生物或水解形成聚硅氧烷.水解时,5,5,4,4,5,5,5-七氟1-戊基三氯硅烷出乎意料地得到液体硅氧烷.(授权)
Doi:10.1021/ja01540A058

专利信息

专利号:US-8771639-B2
优先权日:2007-01-05
标 题 :Methods for preparing composites of substrate-molecular sieve
发明人：YOON KYUNG BYUNG; LEE JIN SEOK; KIM JAE HYUN; LEE YOUNG JU; JEONG NAK CHEON
权利人:YOON KYUNG BYUNG; LEE JIN SEOK; KIM JAE HYUN; LEE YOUNG JU; JEONG NAK CHEON; UNIV SOGANG IND UNIV COOP FOUN
摘要:The present invention relates to a method for preparing composites of substrate-molecular sieve, in particular, to a method for preparing a composite of substrate-molecular sieve, which comprises applying a physical pressure to molecular sieve crystals against a substrate to form a chemical bond between the molecular sieve crystal and the substrate. The present invention requiring no solvents, reactors and other equipments enables molecular sieve crystals to be stably attached to the surface of substrates through various chemical bonds, particularly ionic present invention ensures the synthesis of substrate-molecular sieve composites with enhanced attachment rate, degree of lateral close packing (DCP) and attachment strength in more time-saving and energy-saving manners. The present method works well for molecular sieve crystals with lager sizes (e.g., more than 3 μm) with no generation of parasitic crystals. Furthermore, the present invention shows excellent applicability to large substrates, enabling the mass production of substrate-molecular sieve composites.