CAS: 2168-93-6; 1-(Butylsulfinyl)Butane

该化合物是一种有机化合物,其特征是其二氧化二氮功能组,由硫磺原子与氧原子和两丁基组组成,它是一种无色的淡黄色液体,有温味的气味,以极度高和能够溶解多种有机和无机物质而著称.二丁基氧化二丁基氧化二丁基二氧具有良好的热稳定性,并且与水不相容,使其在各种化学反应和工艺中作为溶剂发挥作用.其化学结构有助于其作为有机合成的潜在试剂和作为电子化学应用媒介的特性.此外,二丁基二氧化二氧与其他溶剂相比毒性较低,因此得到承认,尽管在处理过程中仍应注意安全防范措施.重要的是,尽管DBSO具有有益特性,但其环境影响和监管地位应在工业应用中加以考虑.

结构式图片

相似化合物

3079-30-9 1986-89-6 2168-96-9

上下游产品

n-butyl magnesium bromide sulfurous acid dibutyl ester diethyl ether Dibutyl sulfidedibutyl sulfone perfluoro-1-butanesulfonyl fluoride 1-phenyl-2-hexanone (S)-2-((R)-Butane-1-sulfinyl)-1,1-diphenyl-pentan-1-ol

合成工艺路线路线简述

  • 合成目标产物 Di-N-Butyl Sulfoxide 主要起始原料 Dibutyl Sulfide
  • (文献来源)合成步骤主要原料 Dibutyl Sulfide
二丁基硫醚置于双氧水体系中,用 乙醇 用作溶剂,化学反应 1.0H,以99%的收率获得正丁基亚砜
参考文献:Fe3O4磁性纳米颗粒上负载的新型金属配合物,作为可回收的催化剂,用于将硫化物选择性氧化为亚砜
标题:Fe3O4磁性纳米颗粒上负载的新型金属配合物,作为可回收的催化剂,用于将硫化物选择性氧化为亚砜
摘要:Fe 3 O 4纳米颗粒涂有氨基丙基三乙氧基硅烷,然后与伊斯丁反应,得到亚胺键合的fe 3 O 4纳米颗粒.的zrocl的添加2 ⋅8H 2 O或氯化亚铜2导致形成的zr配合物(iv)/靛红@的fe 3 ö 4或cu(II)/靛红@的fe 3 ö 4作为新型的磁分离催化剂.使用各种技术对合成的催化剂进行了表征.这些催化剂显示出使用过氧化氢作为氧化剂将硫化物化学选择性氧化为亚砜的有效催化剂.该系统具有许多优点,例如磁性催化剂的可重复使用性极佳,产率高,使用外部磁体分离催化剂的简便性,环境友好性以及易于处理.版权所有©2016 John Wiley&sons,Ltd.
Doi:10.1002/aoc.3429

海关参考信息

专利信息


专利号:US-4918222-A
优先权日:1984-07-27
标 题 :Process for synthesis of N-acetylglycine
发明人:LIN JIANG-JEN; KNIFTON JOHN F; YEAKEY ERNEST L
权利人:TEXACO INC
摘要:An N-acetylglycine is manufactured by reacting paraformaldehyde with an acetamide and carbon monoxide in the present of a cobalt-containing catalyst promoted by a sulfoxide or dinitride compounds. The presence of sulfoxide or dinitrile ligands are essential for the high yield synthesis of N-acetylglycine and good cobalt recovery.

专利号:US-3720736-A
优先权日:1970-03-17
标 题 :Process for the synthesis of dihydrocarbonphosphinates
发明人:QUICK J; VENEZKY D
权利人:US NAVY
摘要:A PROCESS FOR THE SYNTHESIS OF A DIHYDROCARBONPHOSPHINATE WHEREIN A DIHYDROCARBONAHALOPHOSPHINE IS OXIDIZED IN THE PRESENCE OF A DIHYDROCARBON SULFOXIDE, SUCH AS DIMETHYLSULFOXIDE, AND THE REACTION MIXTURE THEREOF IS REACTED WITH AN APPROPRIATE ALCOHOL TO FORM THE DESIRED ESTER.

专利号:US-11794179-B2
优先权日:2016-08-24
标 题 :Synthesis and characterization of metathesis catalysts
发明人:JOHNS ADAM M
权利人:UMICORE AG & CO KG
摘要:This invention relates generally to olefin metathesis catalysts, to the preparation of such compounds, compositions comprising such compounds, methods of using such compounds, and the use of such compounds in the metathesis of olefins and in the synthesis of related olefin metathesis catalysts. The invention has utility in the fields of catalysis, organic synthesis, polymer chemistry, and in industrial applications such as oil and gas, fine chemicals and pharmaceuticals.

专利号:US-2006194214-A1
优先权日:2005-02-28
标题 :Methods for assembly of high fidelity synthetic polynucleotides
发明人:CHURCH GEORGE; JACOBSON JOSEPH; BAYNES BRIAN M
权利人:CHURCH GEORGE; JACOBSON JOSEPH; BAYNES BRIAN M
摘要:Disclosed are methods of manufacturing synthetic DNAs, that is, DNAs made at least in significant part by chemical synthesis of polynucleotide polymers. Also provided are methods for assembling plural DNAs in the same pool by multiplexed assembly of synthetic oligonucleotides. In exemplary embodiments, the methods involve pre-amplification of one or more oligonucleotides using “universalâ€? primers, reduction of the error rate in oligonucleotide and/or polynucleotide products, and sequence optimization and oligonucleotides design.

专利号:US-2009088576-A1
优先权日:2006-01-30
标题:Process for the Stereoselective Preparation of Alcohols From Alpha, Beta-Insaturated Compounds
发明人:HEROLD PETER; STUTZ STEFAN; MAH ROBERT; STOJANOVIC ALEKSANDAR; LYOTHIER ISABELLE; BEHNKE DIRK; SPINDLER FELIX; BAPPERT ERHARD
权利人:HEROLD PETER; STUTZ STEFAN; MAH ROBERT; STOJANOVIC ALEKSANDAR; LYOTHIER ISABELLE; BEHNKE DIRK; SPINDLER FELIX; BAPPERT ERHARD
摘要:A process for the synthesis of an alcohol of formula (I), using as intermediate a compound of formula (V).

专利号:US-2007122817-A1
优先权日:2005-02-28
标 题:Methods for assembly of high fidelity synthetic polynucleotides
发明人:CHURCH GEORGE; JACOBSON JOSEPH; BAYNES BRIAN M
权利人:CHURCH GEORGE; JACOBSON JOSEPH; BAYNES BRIAN M
摘要:Disclosed are methods of manufacturing synthetic DNAs, that is, DNAs made at least in significant part by chemical synthesis of polynucleotide polymers. Also provided are methods for assembling plural DNAs in the same pool by multiplexed assembly of synthetic oligonucleotides. In exemplary embodiments, the methods involve pre-amplification of one or more oligonucleotides using “universalâ€? primers, reduction of the error rate in oligonucleotide and/or polynucleotide products, and sequence optimization and oligonucleotides design.
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合成参考文献


摘要:Pilgrim, B. S.; Tucker, M. J., Science of Synthesis Knowledge Updates, (2019) 1, 298.
摘要:Kaneda, K.; Mitsudome, T., Science of Synthesis: Catalytic Reduction in Organic Synthesis, (2017) 1, 339.
摘要:Kaneda, K.; Mitsudome, T., Science of Synthesis: Catalytic Reduction in Organic Synthesis, (2017) 1, 344.
摘要:P.O. Virtanen and J. Korpela. Suomen Kemistilehti B 41, 326 (1968); CA 70, 41339f.
参考文献:10.2144/02324rr04
摘要:Chakrabarti R, Schutt CE. Novel sulfoxides facilitate GC-rich template amplification. Biotechniques. 2002 Apr;32(4):866, 868, 870–2, 874. doi: 10.2144/02324rr04.
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