CAS: 635-12-1; Anthracene-1,4-Dione

相似化合物

130-15-4 605-93-6 130-15-4

上下游产品

CAS号81-64-1 1,4-二羟基蒽醌 | CAS号610-50-4 1-羟基蒽 | CAS号87656-32-4 (2-(二甲氧基甲基)苯基)甲醇 | CAS号106-51-4 苯醌 | CAS号71155-60-7 1,4,4a,9a-tetra... | CAS号117934-77-7 (1R,4S,4aR,9aS)... | CAS号13209-15-9 α,α,α',α'-四溴邻二甲苯 | CAS号87656-31-3 2-(二甲氧基甲基)苯甲酸甲酯 | CAS号119-67-5 邻羧基苯甲醛 | CAS号144453-51-0 5,12-dioxotetra... | CAS号141988-08-1 2-aminoanthrace... | CAS号3029-32-1 6,13-五并苯醌 | CAS号31619-42-8 4-nitrosoanthra... | CAS号135-48-8 并五苯 | CAS号20494-73-9 6,7,11-trihydro... | CAS号1487-12-3 1,1':2',1''-Ter... | CAS号113431-26-8 | CAS号2141-42-6 1,2,3,4-tetrahy... | CAS号7218-35-1 1,4-Anthracenediol

1-蒽酚置于2-碘酰基苯甲酸体系中,用 N,N-二甲基甲酰胺 作为反应溶剂,以67%的收率获得产物1,4-蒽醌
参考文献:高价碘试剂将多环芳香酚区域特异性氧化成醌类
标题:高价碘试剂将多环芳香酚区域特异性氧化成醌类
摘要:高价碘试剂邻碘苯甲酸 (Ibx) 和双(三氟乙酰氧基)碘苯 (Bti) 被证明是将多环芳香酚 (Pap) 区域控制氧化成特定异构体(邻,对或远程)的通用试剂.) 的多环芳香醌 (Paq).ibx 对一系列pap的氧化在温和条件下发生,以提供相应的邻位paq.相比之下,同一系列pap与 Bti 的氧化表现出不同的区域特异性,在结构上可行的情况下提供对位paq 和邻位-Paqs 或其他情况下的远程 Paq 异构体.根据高价碘试剂的固有区域选择性以及苯酚前体的结构要求,可以预测形成的特定 Paq 异构体的结构.ibx 和 Bti 被推荐作为 Paps 到 Paqs 的区域控制氧化的首选试剂.
DOI:10.1016/j.Tet.2009.12.022

专利信息

专利号:US-2018244602-A9
优先权日:2016-08-26
标题 :Mechanochemical synthesis of iptycenes

专利号:WO-2018038742-A1
优先权日:2016-08-26
标 题 :Mechanochemical synthesis of iptycenes
发明人：SWAGER TIMOTHY M; ZHAO YANCHUAN; VELEIRINHO DE OLIVEIRA ROCHA SILVIA
权利人:MASSACHUSETTS INST TECHNOLOGY
摘要:Compositions comprising bridged bicyclic-based compounds such as iptycene-based compounds and methods for mechanochemically synthesizing them are generally provided. In some cases, two or more polycyclic aromatic hydrocarbons may be mechanochemically reacted such that the product comprises the bridged bicyclic-based compound. In some embodiments, the product may comprise two or more [2.2.2] bicyclic cores. In certain embodiments, the mechanochemical reactions described herein may produce higher order bridged bicyclic-based compounds such as oligoiptycenes or poly-iptycenes. In certain embodiments, the bridged bicyclic based compound comprises a molecular cage. Filter devices comprising such compounds are also disclosed.

专利号:US-10160715-B2
优先权日:2016-08-26
标 题 :Mechanochemical synthesis of iptycenes
发明人：SWAGER TIMOTHY M; ZHAO YANCHUAN; VELEIRINHO DE OLIVEIRA ROCHA SILVIA
权利人:MASSACHUSETTS INST TECHNOLOGY
摘要:Methods for mechanochemically synthesizing compositions comprising bridged bicyclic-based compounds such as iptycene-based compounds are generally provided. In some cases, two or more polycyclic aromatic hydrocarbons may be mechanochemically reacted such that the product comprises the bridged bicyclic-based compound. In some embodiments, the product (e.g., the bridged bicyclic compound) may comprise two or more [2.2.2] bicyclic cores. In certain embodiments, the mechanochemical reactions described herein may produce higher order bridged bicyclic-based compounds such as oligoiptcyenes or poly-iptycenes. In certain embodiments, the bridged bicyclic based compound comprises a molecular cage.

专利号:US-2018057443-A1
优先权日:2016-08-26
标题:Mechanochemical synthesis of iptycenes

专利号:CN-119080717-A
优先权日:2024-08-28
标 题 :Synthesis method of 2-amino-3-trifluoromethyl naphthoquinone compound

专利号:CN-118955877-A
优先权日:2024-07-31
标题 :Synthesis method and application of lithium extraction adsorption material based on tetraoxyalkene