合成目标产物 Buntane-2-Boronic Acid 主要起始原料 Trimethyl Borate And Sec-Bumgbr, Fandachem
922-66-7 = 88496-88-2 反应条件:1.1 Reagents: Trimethyl Borate Solvents: Diethyl Ether; 10 Min,-78 °C; -78 °C -> -60 °C; Overnight,-60 °C -> Rt; Rt -> 0 °C1.2 Reagents: Sulfuric Acid Solvents: Water; 0 °C; 0 °C -> Rt; 20 Min,Rt 标题:Highly E-Selective Olefin Synthesis Catalysed By Novel Quinoxalinone Photocatalyst Under Visible Light Conditions 作者:Xu,Xin; Et Al 参考文献:Chemistry - A European Journal 日期:2023 卷标:29(27)]
= 88496-88-2 反应条件:1.1 Reagents: Magnesium Catalysts: Iodine Solvents: Diethyl Ether; Reflux; Overnight,Reflux2.1 Reagents: Trimethyl Borate Solvents: Diethyl Ether; 10 Min,-78 °C; -78 °C -> -60 °C; Overnight,-60 °C -> Rt; Rt -> 0 °C2.2 Reagents: Sulfuric Acid Solvents: Water; 0 °C; 0 °C -> Rt; 20 Min,Rt 标题:Highly E-Selective Olefin Synthesis Catalysed By Novel Quinoxalinone Photocatalyst Under Visible Light Conditions 作者:Xu,Xin; Et Al 参考文献:Chemistry - A European Journal 日期:2023 卷标:29(27)
硼酸三甲酯,Sec-Bumgbr 反应生成 仲丁基硼酸 参考文献:Organoboron Compounds. Ii. Preparation And Properties Of Some Trialkylboroxines1-3 标题:Organoboron Compounds. Ii. Preparation And Properties Of Some Trialkylboroxines1-3 摘要: DOI:10.1021/ja01576A026
专利号:US-10844081-B2 优先权日:2015-08-07 标题 :Protected organoboronic acids with tunable reactivity, and methods of use thereof 发明人:BURKE MARTIN D; SCHMIDT MICHAEL; MOREHOUSE GREG; PIPAL ROBERT W 权利人:UNIV ILLINOIS 摘要:Disclosed are a range of protected organoboronic acid reagents useful in the modular assembly of complex organic compounds. The reactivities of the protected organoboronic acid reagents may be varied predictably by changes to the number and identities of their substituents. Also disclosed are methods of using the protected organoboronic acid reagents in the synthesis of organic compounds.
专利号:US-8207337-B2 优先权日:2007-01-29 标 题:Reagent for organic synthesis reaction containing organic triol borate salt 发明人:MIYAURA NORIO; YAMAMOTO YASUNORI 权利人:MIYAURA NORIO; YAMAMOTO YASUNORI; WAKO PURE CHEM IND LTD 摘要:[Problem] n To provide an organoboron compound-containing reagent for organic synthesis reactions which undergoes no trimerization with dehydration, does not necessitate activation with a base, and is stable and highly active. n [Means for Solving Problems] n The reagent for organic synthesis reactions contains an organic triol borate salt represented by any of the general formulae (I) to (III) and general formula (XVI): (wherein R 1 represents alkyl, alkenyl, etc.; R 2 represents optionally substituted alkyl, alkenyl, alkynyl, etc. or represents hydrogen; m + represents an alkaline metal ion, phosphonium ion, or given ammonium ion; M 2+ represents an alkaline earth metal; X represents halogen or alkoxide; Y represents an alkali metal ion, etc.; A represents optionally substituted methylene; and n represents an integer).
专利号:US-10072028-B2 优先权日:2013-11-03 标题:Cross-coupling of unactivated secondary boronic acids 发明人:BURKE MARTIN D; WANG PULIN; CROUCH IAN 权利人:UNIV ILLINOIS 摘要:Provided are methods for site- and stereo-retentive cross-couplings with unactivated secondary boronic acids, which methods are particularly useful in building block-based approach for small molecule synthesis. Also provided is a method of forming an air-stable chiral secondary boronic acid.