CAS: 108464-88-6; 1,3-Phenylenebis((4-Fluorophenyl)Methanone)

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CAS号437-29-6 (p-fluorophenyl)3Bi | CAS号99-63-8 间苯二甲酰氯 | CAS号462-06-6 氟苯 | CAS号110471-15-3 1,3-双[4-(3-氨基苯氧...

氟苯,间苯二甲酰氯置于aluminum (III) Chloride体系中,化学反应 8.0H,以3.24 G的收率获得1,3-双(4-氟苯甲酰)苯
参考文献:基于咔唑衍生物修饰的双氰基乙烯基的多样化aie和机械变色发光:取代位点和分子堆积的影响
标题:基于咔唑衍生物修饰的双氰基乙烯基的多样化aie和机械变色发光:取代位点和分子堆积的影响
摘要:聚集诱导发射(aie)特性已得到广泛研究,这不仅是因为它们完全避免了常规荧光团中臭名昭著的聚集引起的猝灭效应,而且还因为它们在有机发光二极管,荧光传感器和生物成像中的应用前景广阔.在这项工作中,我们报道了对具有咔唑和双氰基乙烯基的aie活性位置异构体(m-Bpcdm和p-Bpcdm)的分子堆积和发光性质的研究.化合物米基于-Bpcdm元3'-取代显示出比化合物更明显aie流程p-Bpcdm基于第-取代,这可以归因于p-Bpcdm空间结构带来的强烈的π-π堆积效应.此外,两个位置异构体还表现出不同的机械致变色发光性质.
Doi:10.1039/c9Ce01958H

专利信息

专利号:US-7579427-B2
优先权日:2004-06-30
标 题 :Synthesis of poly(arylene)s copolymers containing pendant sulfonic acid groups bonded to naphthalene as proton exchange membrane materials
发明人：GAO YAN; GUIVER MICHAEL D; ROBERTSON GILLES P
权利人:CA NAT RESEARCH COUNCIL
摘要:A new series of wholly aromatic poly(arylene ether ether ketone ketone)s containing pendant sulfonic acid groups (SPAEEKK) were conveniently prepared by potassium carbonate mediated nucleophilic polycondensation reactions of inexpensive commercially available monomers: 1,3-bis(4-fluorobenzoyl)benzene (BFBB), sodium 6,7-dihydroxy-2-naphthalenesulfonate (DHNS), and 4,4′-biphenol or hydroquinone in N-methyl-2-pyrrolidone (NMP) at 170° C. FT-IR and NMR were used to characterize the structures and the sulfonate or sulfonic acid contents (SC) of the polymers. Flexible membrane films were obtained by casting N,N-dimethylacetamide (DMAc) solutions of copolymers. Membrane films in acid form were then obtained by treating the sodium form membrane films in 2 N sulfuric acid at room temperature. Glass transition temperatures (T g s) and decomposition temperatures (T d s) of SPAEEKKs in both sodium and acid forms were determined. Water uptake and swelling ratio values increased with SCs and temperatures. The proton conductivities of acid form membrane films increased with SC value and temperature and reached 5.6×10 −2 S/cm at 100° C. for SPAEEKK-100.

专利号:US-11732090-B2
优先权日:2016-12-21
标 题:Poly(ether ketone ketone) polymers, corresponding synthesis methods and polymer compositions and articles made therefrom
发明人：LOUIS CHANTAL
权利人:SOLVAY SPECIALTY POLYMERS USA
摘要:Described herein are PEKK polymers having improved processability and improved crystallinity. It was surprisingly found that PEKK polymers formed using a specifically adapted nucleophilic synthesis route, in which different monomers are added in to the polymerization reaction at different points during the synthesis, had lower glass transition temperatures (“Tgâ€?) and increased crystallinities, relative to PEKK polymers formed using traditional nucleophilic synthesis routes (“traditional PEKK polymersâ€?). Furthermore, compared with PEKK polymers synthesized using an electrophilic synthesis routes, the PEKK polymers described herein and significantly lower halogen content. The synthesis routes includes a first heating of a first monomer blend in a reaction mixture, a subsequent first addition of a second monomer blend to the reaction mixture, and a second heating of the reaction mixture subsequent to the first addition.

专利号:WO-2018115033-A1
优先权日:2016-12-21
标题:Poly(ether ketone ketone) polymers, corresponding synthesis methods and polymer compositions and articles made therefrom
发明人：LOUIS CHANTAL
权利人:SOLVAY SPECIALTY POLYMERS USA
摘要:Described herein are PEKK polymers having improved processability and improved crystallinity. It was surprisingly found that PEKK polymers formed using a specifically adapted nucleophilic synthesis route, in which different monomers are added to the polymerization reaction at different points during the synthesis, had lower glass transition temperatures ('Tg') and increased crystallinities, relative to PEKK polymers formed using traditional nucleophilic synthesis routes ('traditional PEKK polymers'). Furthermore, compared with PEKK polymers synthesized using an electrophilic synthesis routes, the PEKK polymers described herein and significantly lower halogen content. The synthesis routes includes a first heating of a first monomer blend in a reaction mixture, a subsequent first addition of a second monomer blend to the reaction mixture, and a second heating of the reaction mixture subsequent to the first addition.

专利号:US-12202940-B2
优先权日:2016-12-21
标题:Poly (ether ketone ketone) polymers, corresponding synthesis methods and polymer compositions and articles made therefrom
发明人：LOUIS CHANTAL
权利人:SOLVAY SPECIALTY POLYMERS USA
摘要:Described herein are poly(ether ketone ketone) (“PEKKâ€?) polymers having improved processability. It was surprisingly discovered that by selectively controlling the relative amounts of reactants during the synthesis, PEKK polymers having unexpectedly lower melt viscosities can be obtained. More particularly, by selectively controlling the relative amounts of monomers used to form recurring units of the PEKK polymer, in conjunction with selective control of other reaction components, the resulting PEKK polymers had reduced viscosities, relative to PEKK polymers synthesized by using tradition reaction schemes (“traditional PEKK polymersâ€?). By providing PEKK polymers with lower melt viscosities, the PEKK polymers described herein have improved processability.

专利号:WO-2018115035-A1
优先权日:2016-12-21
标 题 :Poly(ether ketone ketone) polymers, corresponding synthesis methods and polymer compositions and articles made therefrom
发明人：LOUIS CHANTAL
权利人:SOLVAY SPECIALTY POLYMERS USA; SOLVAY
摘要:Described herein are poly(ether ketone ketone) ('PEKK') polymers having improved processability. It was surprisingly discovered that by selectively controlling the relative amounts of reactants during the synthesis, PEKK polymers having unexpectedly lower melt viscosities can be obtained. More particularly, by selectively controlling the relative amounts of monomers used to form recurring units of the PEKK polymer, in conjunction with selective control of other reaction components, the resulting PEKK polymers had reduced viscosities, relative to PEKK polymers synthesized by using tradition reaction schemes ('traditional PEKK polymers'). By providing PEKK polymers with lower melt viscosities, the PEKK polymers described herein have improved processability.

专利号:US-2006004177-A1
优先权日:2004-06-30
标 题:Synthesis of poly(arylene)s copolymers containing pendant sulfonic acid groups bonded to naphthalene as proton exchange membrane materials