CAS: 13356-08-6; Fenbutatin Oxide

该化合物是一种有机锡化合物,主要用作农药和杀螨剂,用于农业用途,其特点是能够控制各种害虫,特别是灭蚁虫,使其在作物保护中具有价值;五丁二氧化物的化学结构包括一种锡原子结为有机组,有助于有机生物活动;通常以白色晶状固体的形式出现,以其易变性和在正常条件下的稳定性为名;六丁二氧化物对人类和动物具有中等毒性,需要谨慎处理和应用;其行动方式涉及破坏目标害虫的...

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欧盟法规

《欧盟PIC法规》统一分类与标签压力设备指令-第1组危险流体"欧盟管控危险化学品"ECHA物质ECHA物质欧盟农药活性物质OtherC&L通报工作场所安全标识要求REACH预注册废弃物危险特性清单

上下游产品

CAS号1178-79-6 chlorotris(2-me... | CAS号1178-79-6 chlorotris(2-me...

合成工艺路线路线简述

    氯-三(2-甲基-2-苯基丙基)锡烷 反应生成苯丁锡
    参考文献:Kano,Toshio;Knodo,Masamichi;Ikeda,Tatsufumi;Morikawa,Chiharu
    标题:Kano,Toshio;Knodo,Masamichi;Ikeda,Tatsufumi;Morikawa,Chiharu

    海关参考信息

    专利信息


    专利号:US-6610802-B2
    优先权日:2001-05-29
    标题 :Process for synthesis of polymer compositions, polymer compositionS obtainable by the process, and use of the same
    发明人:ROOS SEBASTIAN; EISENBERG BORIS; HARPE CAROLIN
    权利人:ROHMAX ADDITIVES GMBH
    摘要:The present invention relates to a process for synthesis of polymer compositions with reduced catalyst content, wherein ethylenically unsaturated monomers containing less than 0.5 wt % of ethylenically unsaturated monomers with at least one carboxylic group, sulfonic acid group and/or at least one phosphonic acid group relative to the total weight of the ethylenically unsaturated monomers are polymerized by means of initiators containing a transferable group of atoms and of one or more catalysts comprising at least one transition metal in the presence of ligands which can form a coordination compound with the metal catalyst or catalysts and, after the polymerization, the catalyst contained in the polymer is at least partly separated. For this purpose, the polymer composition is filtered, after the polymerization, in the presence of at least one filter aid which contains at least 0.5 wt %, relative to the total weight of the filter aid, of repeating units that contain at least one carboxylic acid group, sulfonic acid group and/or at least one phosphonic acid group.

    专利号:US-11306041-B2
    优先权日:2017-03-30
    标 题:Catalytic synthesis of super linear alkenyl arenes using rhodium catalysts
    发明人:SCHINSKI WILLIAM; GOLDMAN ALAN; GUNNOE THOMAS B; WEBSTER-GARDINER MICHAEL S; SCHWARTZ NICHOLE
    权利人:UNIV VIRGINIA PATENT FOUNDATION
    摘要:Catalytic methods for synthesis of super linear alkenyl arenes and alkyl arenes are provided. The methods are capable of synthesizing super linear alkyl and alkenyl arenes from simple arene and olefin starting materials and with high selectivity for linear coupling. Methods are also provided for making a 2,6-dimethylnapthalene (DMN) or 2,6-methylethylnapthalene (MEN).

    专利号:US-6610801-B1
    优先权日:2000-11-13
    标题:Processes for synthesis of polymer compositions
    发明人:SCHERER MARKUS
    权利人:ROHMAX ADDITIVES GMBH
    摘要:The present invention relates to processes for synthesis of poly(meth)acrylate compositions, wherein ethylenically unsaturated monomers are transformed to polymers by means of initiators containing a transferable group of atoms and of one or more catalysts comprising at least one transition metal in the presence of ligands which can form a coordination compound with the metal catalyst or catalysts, wherein ethylenically unsaturated monomers containing 50 to 100 wt %, relative to the total weight of ethylenically unsaturated monomers, of (meth)acrylates of formula (I) are polymerizedwherein R denotes hydrogen or methyl, R1 denotes a straight-chain or branched alkyl group with 8 to 40, carbon atoms, R2 and R3 independently denote hydrogen or a group of the formula -COOR1, wherein R' denotes hydrogen or a straight-chain or branched alkyl group with 8 to 40, carbon atoms, in the presence of copper, the total concentration of copper of oxidation numbers (I) and (II) in the polymerization composition being <=200 ppm relative to the total weight of the composition.

    专利号:US-6639029-B1
    优先权日:2000-11-13
    标 题 :Process for continuous synthesis of polymer compositions as well as use of same
    发明人:SCHERER MARKUS; BOLLINGER JOSEPH MARTIN; COOPER JR DAVID J; TILLERY LARRY STEPHEN; WOODRUFF ROBERT
    权利人:ROHMAX ADDITIVES GMBH
    摘要:The present invention relates to a process for synthesis of polymer compositions, wherein ethylenically unsaturated monomers are polymerized by means of initiators containing a transferable atom or group of atoms and of one or more catalysts comprising at least one transition metal in the presence of ligands which can form a coordination compound with the metal catalyst or catalysts, the process being characterized in that the polymerization takes place by means of continuous process operation.

    专利号:US-7834174-B2
    优先权日:2004-09-10
    标 题 :Per-6-guanidino-, alkylamino-cyclodextrins, methods of their synthesis and their use for the compaction of DNA and intercellular delivery
    发明人:MAVRIDIS IRENE M; YANNAKOPOULOU KONSTANTINA; ELIADOU KYRIAKI; MOURTZIS NIKOLAOS; AGGELIDOU CHRYSI
    权利人:MAVRIDIS IRENE M; YANNAKOPOULOU KONSTANTINA; ELIADOU KYRIAKI; MOURTZIS NIKOLAOS; AGGELIDOU CHRYSI
    摘要:The invention relates to new compounds of type hexakis(6-deoxy-6-NH(CH 2 ) n —R 1 )α-cyclodextrin and heptakis(6-deoxy-6-NH(CH 2 ) n —R 1 )-(β-cyclodextrin, and octakis(6-deoxy-6-NH(CH 2 ) n —R 1 )-γ-cyclodextrin, where n=2-6 when R 1 =NH 2 and n=0 when R 1 =C(â•?NH)NH 2 and n=2-6 when R 1 =NH—C(â•?NH)NH 2 and their use in the compaction of DNA and in cell permeation. The invention also relates to methods of synthesis of the above compounds.

    专利号:WO-2025056767-A1
    优先权日:2023-09-15
    标题 :Process for the preparation of enantiomerically enriched aliphatic amines
    发明人:BOU HAMDAN FARHAN; GODINEAU EDOUARD; SMEJKAL TOMAS; DUMEUNIER RAPHAEL; BOUSSEMGHOUNE MOHAMED ABDELOUAHAB; BLUM MATHIAS
    权利人:SYNGENTA CROP PROTECTION AG
    摘要:The present invention relates to a process for the preparation of enantiomerically enriched cyclobutylamines of formula (I) from α-tertiary cyclobutanones and reacting said enantiomerically enriched cyclobutylamines to enantiomerically enriched cyclobutylamides. Such compounds are useful intermediates in the synthesis of microbiocidal thiazole compounds.
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    主要参考文献


    1: Lin Z, Lin Y, Lin J, Zhang Y, Fang S. Trace Analysis of Fenbutatin Oxide in Soil and Plant- and Animal-Derived Foods Using Modified QuEChERS Coupled with HPLC-MS/MS. ACS Omega. 2021 Apr 6;6(15):10260-10265. doi: 10.1021/acsomega.1c00593.
    2: Kaufman JL, Gasparetto C, Schjesvold FH, Moreau P, Touzeau C, Facon T, Boise LH, Jiang Y, Yang X, Dunbar F, Vishwamitra D, Unger S, Macartney T, Pesko J, Yu Y, Salem AH, Ross JA, Hong WJ, Maciag PC, Pauff JM, Kumar S. Targeting BCL-2 with venetoclax and dexamethasone in patients with relapsed/refractory t(11;14) multiple myeloma. Am J Hematol. 2021 Apr 1;96(4):418-427. doi: 10.1002/ajh.26083. Epub 2021 Jan 19.
    3: De Beer B, Villacis-Perez E, Khalighi M, Saalwaechter C, Vandenhole M, Jonckheere W, Ismaeil I, Geibel S, Van Leeuwen T, Dermauw W. QTL mapping suggests that both cytochrome P450-mediated detoxification and target-site resistance are involved in fenbutatin oxide resistance in Tetranychus urticae. Insect Biochem Mol Biol. 2022 Jun;145:103757. doi: 10.1016/j.ibmb.2022.103757. Epub 2022 Mar 14. 47(4):293-9. doi: 10.1007/s10493-008-9219-x. Epub 2008 Nov 14. 38(5):813-9. doi: 10.1007/BF01616706. 11(2):159-64. doi: 10.1002/(SICI)1097-0231(19970131)11:2<159::AID-RCM730>3.0.CO;2-O. Brancato A, Brocca D, De Lentdecker C, Erdos Z, Ferreira L, Greco L, Jarrah S, Kardassi D, Leuschner R, Lythgo C, Medina P, Miron I, Molnar T, Nougadere A, Pedersen R, Reich H, Sacchi A, Santos M, Stanek A, Sturma J, Tarazona J, Theobald A, Vagenende B, Verani A, Villamar- Bouza L. Review of the existing maximum residue levels for fenbutatin oxide according to Article 12 of Regulation (EC) No 396/2005. EFSA J. 2017 Dec 12;15(12):e05091. doi: 10.2903/j.efsa.2017.5091.

    合成参考文献


    参考文献:10.1007/s10493-005-1423-3
    摘要:Pree DJ, Whitty KJ, Van Driel L. Baseline Susceptibility and Cross Resistances of Some New Acaricides in the European Red Mite, Panonychus ulmi*. Experimental and Applied Acarology. 2005 Dec;37(3-4):165. doi: 10.1007/s10493-005-1423-3.
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