CAS: 1693-86-3; 3-Hexylthiophene

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CAS号872-31-1 3-溴噻吩 | CAS号3761-92-0 己基溴化镁 | CAS号111-25-1 1-溴代正己烷 | CAS号69249-61-2 2-溴-3-己基噻吩 | CAS号691006-31-2 triethyl-[3-(n-... | CAS号691006-33-4 tert-butyl-[3-(... | CAS号438587-18-9 (2-[4-(2-ethoxy... | CAS号691006-35-6 {2-[4-(2-ethoxy... | CAS号164991-12-2 (3-hexylthiophe... | CAS号124397-96-2 己基溴化锌 | CAS号222554-30-5 4-己基噻吩-2-甲醛 | CAS号222554-28-1 3-己基噻吩-2-甲醛 | CAS号850881-09-3 3-己基噻吩-2-硼酸频哪醇酯 | CAS号69249-61-2 2-溴-3-己基噻吩 | CAS号116971-11-0 2,5-二溴-3-己基噻吩 | CAS号154717-21-2 2-bromo-3-hexyl... | CAS号154717-19-8 3-hexyl-5-(3-he... | CAS号135926-93-1 3,4'-二己基-2,2'-联噻吩 | CAS号125607-30-9 3,3'-二己基-2,2'-联噻吩 | CAS号160096-76-4 2-溴-3-己基-5-碘噻吩

{2-[4-(2-Ethoxyethoxy)Phenyl]Ethyl}Diethyl-[4-(N-Hexyl)Thiophen-2-Yl]Germane置于溶剂黄146体系中,用 二氯甲烷 用作溶剂,化学反应生成3-己基噻吩
参考文献:迈向使用基于锗的连接基迭代合成共轭低聚物的一般固相方法-寡聚(三芳基胺)的第一个固相合成.
标题:迈向使用基于锗的连接基迭代合成共轭低聚物的一般固相方法-寡聚(三芳基胺)的第一个固相合成.
摘要:描述了一种基于锗的接头系统的开发,该系统用于通过迭代扩链进行3-(n-己基)噻吩低聚物和三芳基胺低聚物的第一个sps的固相合成(sps).低聚合成中关键步骤的效率及其与锗连接基的相容性通过联[3-(正己基)噻吩] 19和叔-(三芳基胺)50的sps进行了证明.适当地选择的基于硅的封闭/保护基的结合基团允许双重偶联以驱动关键的交叉偶联步骤完成,因此使缺失序列最小化,并且还允许从树脂无痕和潜在的功能性裂解.
Doi:10.1039/b703022C

专利信息

专利号:US-2013045416-A1
优先权日:2011-08-15
标题 :Gold micro- and nanotubes, their synthesis and use
发明人：SEFEROS DWIGHT S; BRIDGES COLIN; DICARMINE PAUL
权利人:UNIV TORONTO; SEFEROS DWIGHT S; BRIDGES COLIN; DICARMINE PAUL
摘要:Synthesis of gold microtubes and nanotubes suspendable in solution is presented. The synthesis is accomplished using an AAO template route, wherein a polymer tube is used as a sacrificial core. The synthesis produces hollow structures that consist of only gold. These nanostructures exhibit two SPR modes, which correspond to both the transverse and longitudinal modes. The mode assignment was confirmed by measuring SPR behavior as both aligned arrays and in solution. The performance of gold nanotubes as refractive index detectors was quantified and determined to be more sensitive than analogous solid nanorods prepared under identical conditions, and are among the most sensitive nanostructured plasmon sensors to date. Due to their intense and sensitive resonances in the NIR spectrum, these solution-suspendable nanoparticles have potential to be used as in vitro or in vivo sensors.

专利号:US-9328109-B2
优先权日:2013-01-14
标 题:Process for the preparation of benzohetero [1, 3] diazole compounds disubstituted with heteroaryl groups
发明人：BIANCHI GABRIELE; PO' RICCARDO
权利人:ENI SPA
摘要:Process for the preparation of a benzohetero-[1,3]diazole compound disubstituted with brominated heteroaryl groups which comprises reacting at least one dihalogenated benzohetero[1,3]diazole compound with at least one brominated heteroaryl compound. Said benzohetero[1,3]diazole compound disubstituted with brominated heteroaryl groups can be advantageously used in the synthesis of compounds useful in the construction of solar concentrators (LSCs—“Luminescent Solar Concentratorsâ€?). Furthermore, said benzohetero[1,3]diazole compound disubstituted with brominated heteroaryl groups can be advantageously used in the synthesis of photoactive polymers useful in the construction of photovoltaic devices (or solar devices) such as, for example, photovoltaic cells (or solar cells), photovoltaic modules (or solar modules), on both rigid or flexible supports. Furthermore, said benzohetero[1,3]diazole compound disubstituted with brominated heteroaryl groups can be advantageously used as precursor of monomeric units in the synthesis of semiconductr polymers.

专利号:US-7834106-B2
优先权日:2005-04-01
标题:Living synthesis of conducting polymers including regioregular polymers, polythiophenes, and block copolymers
发明人：MCCULLOUGH RICHARD D; SHEINA ELENA E; IOVU MIHAELA C
权利人:UNIV CARNEGIE MELLON
摘要:Regioregular poly(3-alkylthiophenes) and other polythiophenes can be prepared by living polymerization which have good solubility, processability and environmental stability. The polymerization method can afford regioregular poly(3-alkylthiophenes) in high yields. Kinetic study of polymerization revealed the living character of this process. The molecular weight of poly(3-alkylthiophenes) is a function of the molar ratio of the monomer to nickel initiator, and conducting polymers with relatively narrow molecular weight distribution (PDI<1.5) are now readily available. Sequential monomer addition resulted in new block copolymers containing different poly(3-alkylthiophene) segments, which further confirms the “livingnessâ€? of this system. Other synthetic methods can be used as well to conduct living polymerization. Blends and electronic devices can be prepared.

专利号:US-9453102-B2
优先权日:2013-10-18
标题:Synthesis of chalcogen-capped pi-conjugated polymers
发明人：LUSCOMBE CHRISTINE KEIKO; OKAMOTO KEN
权利人:UNIV WASHINGTON THROUGH ITS CENTER FOR COMMERCIALIZATION
摘要:Methods for the preparation of mono- and bis-end-functionalized Ï€-conjugated polymers. In the methods, chalcogens are selectively installed at the polymer terminus or termini.

专利号:WO-2007007735-A1
优先权日:2005-07-12
标 题 :Synthesis of organic conductive polymerizable material onto metal oxide surface through light irradiation
发明人：TACHIBANA YASUHIRO
权利人:UNIV OSAKA; KANSAI TECH LICENSING ORG CO; TACHIBANA YASUHIRO
摘要:Disclosed is a composite material having a nanostructure containing metal oxide fine particles and an organic conductive polymerizable material. In this composite material, the metal oxide fine particles are joined with one another and the organic conductive polymerizable material is contained in the spaces between the fine particles. In this connection, the organic conductive polymerizable material is a copolymer which is composed of a polythiophene derivative, a thiophene or a derivative thereof and pyrrole, aniline, fluorene, furan or a derivative thereof. Also disclosed is a method for producing such a composite material. This composite material is useful for display elements such as electronic paper.

专利号:US-8168745-B2
优先权日:2007-08-02
标 题:Process for the preparation of poly- and oligothiophenes on an industrial scale
发明人：HENNINGER BJOERN; RAUSCHER FRANK; MLECZKO LESLAW
权利人:HENNINGER BJOERN; RAUSCHER FRANK; MLECZKO LESLAW; BAYER TECHNOLOGY SERVICES GMBH
摘要:Process for industrial scale synthesis of poly- and oligothiophenes, which works in concentrated solution. In this process, a solution which comprises an organometallic thiophene reagent is added to a second solution which comprises a catalyst.