CAS: 4023-65-8; (E)-Prop-1-Ene-1,2,3-Tricarboxylic Acid

该化合物是一种不饱和的三色箱酸,作为柠檬酸循环的中间体,它具有僵硬的分子结构,因为它的跨结构使其与cis-异构体不同,该化合物因其发泡特性而具有价值,使其在金属离子固存和工业应用中有用,它还作为有机合成和生物化学研究的前体.由于极地溶剂具有高度的热稳定性和溶解性,因此跨芳酸适合分析和催化过程.该化合物在植物中的自然现象进一步支持对植物新陈代谢和应激反应的研究.

结构式图片

相似化合物

499-12-7 97-65-4 5746-90-7

欧盟法规

REACH注册ECHA物质C&L通报REACH预注册

上下游产品

CAS号857570-93-5 γ-bromo-aconiti... | CAS号68-04-2 柠檬酸钠 | CAS号77-92-9 柠檬酸 | CAS号585-84-2 顺乌头酸 | CAS号857824-55-6 chloro-ethenetr... | CAS号996-82-7 sodium 1,3-diet... | CAS号64-17-5 乙醇 | CAS号7732-18-5 水 | CAS号4271-99-2 反-乌头酸三甲酯 | CAS号208725-89-7 2-(2,5-dioxooxo... | CAS号127-17-3 丙酮酸 | CAS号110-17-8 富马酸,反丁烯二酸 | CAS号54509-73-8 ethene | CAS号97-65-4 衣康酸 | CAS号99-14-9 1,2,3-丙烷三甲酸 | CAS号585-84-2 顺乌头酸 | CAS号52193-50-7 1,2,3-tris(2-et...

合成工艺路线路线简述

  • 合成目标产物 Trans-Aconitic Acid 主要起始原料 1,1,2-Ethanetricarboxylic Acid
  • (文献来源)合成步骤主要原料 1,1,2-Ethanetricarboxylic Acid
Alkaline Earth Salt Of/the/ Methylsulfuric Acid置于氢氧化钾体系中,化学反应生成 反式-乌头酸
参考文献:Ingold; Oliver; Thorpe,Journal Of The Chemical Society,1924,Vol. 125,P. 2135
标题:Ingold; Oliver; Thorpe,Journal Of The Chemical Society,1924,Vol. 125,P. 2135

海关参考信息

专利信息


专利号:US-2012301720-A1
优先权日:2009-11-16
标题 :Metal island coatings and method for synthesis
发明人:KOBAN WIELAND; PEUKERT WOLFGANG; KLUPP TAYLOR ROBIN; DISTASO MONICA; BAO HUIXIN; VASYLYEV SERHIY
权利人:KOBAN WIELAND; PEUKERT WOLFGANG; KLUPP TAYLOR ROBIN; DISTASO MONICA; BAO HUIXIN; VASYLYEV SERHIY; BASF SE
摘要:The present invention relates to methods for synthesis of metallic island coatings with tunable island coverage and morphology on a variety of substrates. Particularly, the present invention relates to substrates coated with one or more metal islands and the use of said island-coated substrates.

专利号:US-11505519-B2
优先权日:2019-01-17
标题 :Synthesis of organic acids from α-keto acids
发明人:SPRINGSTEEN GREGORY GARDNER; STUBBS ROBERT TRENT
权利人:FURMAN UNIV
摘要:Methods for syntheses of organic acids from α-keto acids, including methods for syntheses of isotopically enriched organic acids from α-keto acids are disclosed. The isotopically enriched organic acids are useful, for example, in metabolic flux analyses.

专利号:US-2025011531-A1
优先权日:2020-06-25
标 题:Synthesis of environmentally degradable alkyl polyesters
发明人:PARK KINAM; GARNER JOHN SOLOMON
权利人:AKINA INC
摘要:A solid crosslinked polyester composition that is environmentally degradable in less than about 180 days. The crosslinked polyester can be the polyesterification reaction product between one or more multi-hydroxylic alcohols, one or more hydroxy acids, and one or more multi-carboxylic acid compounds. Alternately, the crosslinked polyester can be the polyesterification reaction product of one or more multi-hydroxylic alcohols, one or more hydroxy acids, one or more multi-carboxylic acid compounds, and a cyclic ester. Provided, however that if the one or more hydroxy acids has only one carboxyl group, it has two or more hydroxyl groups, and if the one or more hydroxy acids has only one hydroxyl group, it has two or more carboxyl groups.

专利号:US-9923142-B2
优先权日:2016-05-31
标 题:Methods of graphene growth and related structures
发明人:CHEN MIIN-JANG; PAN SAMUEL C; HSIEH CHUNG-YEN
权利人:TAIWAN SEMICONDUCTOR MFG CO LTD; UNIV NAT TAIWAN
摘要:A method and structure for providing uniform, large-area graphene by way of a transfer-free, direct-growth process. In some embodiments, a SAM is used as a carbon source for direct graphene synthesis on a substrate. For example, a SAM is formed on an insulating surface, and a metal layer is formed over the SAM. The metal layer may serve as a catalytic metal, whereby the SAM is converted to graphene following an annealing process. The SAM is deposited using a VPD process (e.g., an ALD process and/or an MLD process). In some embodiments, a CNT having a controlled diameter may be formed on the surface of a nanorod by appropriately tuning the geometry of the nanorod. Additionally, in some embodiments, a curved graphene transistor may be formed over a curved oxide surface, thereby providing a band gap in a channel region of the graphene transistor.

专利号:US-2024199795-A1
优先权日:2022-06-16
标 题 :Synthesis of environmentally degradable alkyl polyesters
发明人:PARK KINAM; GARNER JOHN SOLOMON
权利人:AKINA INC
摘要:A solid polyester wherein the polyester is environmentally degradable in less than about 5 to about 7 months. The polyester is the direct dehydration polyesterification reaction product between one or more multi-hydroxylic alcohols, one or more hydroxy acids, and one or more multi-carboxylic acid compounds without added catalysts or cyclic precursors; or the polyester is the direct dehydration polyesterification reaction product between one or more multi-hydroxylic alcohols, one or more hydroxy acids, one or more multi-carboxylic acid compounds, and a cyclic ester without requiring added catalysts or cyclic precursors.

专利号:US-2020231527-A1
优先权日:2019-01-17
标题 :Synthesis of organic acids from alpha-keto acids
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主要参考文献

参考标题:Trans -Aconitic Acid-Based Hetero -Diels-Alder Reaction In The Synthesis Of Thiopyrano[2,3- D ][1,3]Thiazole Derivatives
作者:Nataliya Zelisko,Olexandr Karpenko,Volodymyr Muzychenko,Andrzej Gzella,Philippe Grellier,Roman Lesyk |发布日期:2017.5
摘要:Hetero-Diels-Alder Reaction Of 5-Arylideneisorhodanines With Trans-Aconitic Acid Proceeds As A Regio- And Diastereoselective Process With Spontaneous Decarboxylation Of The [4+2]-Adduct To Furnish Thiopyrano[2,3-D][1,3]Thiazole (2) And Chromeno[4′,3′:4,5]Thiopyrano[2,3-D]Thiazole (3) Derivatives Analogously To The Use Of Itaconic Acid As A Dienophile. Conversely, The One-Pot, Three-Component Reaction Of 5-Ar

合成参考文献


参考文献:10.1007/bf02237961
摘要:Podell M, Shelton GD, Nyhan WL, Wagner SO, Genders A, Oglesbee M, Fenner WR. Methylmalonic and malonic aciduria in a dog with progressive encephalomyelopathy. Metab Brain Dis. 1996 Sep;11(3):239–47.
参考文献:10.1021/bi049784+
摘要:Katz JE, Dumlao DS, Wasserman JI, Lansdown MG, Jung ME, Faull KF, Clarke S. 3-Isopropylmalate is the major endogenous substrate of the Saccharomyces cerevisiae trans-aconitate methyltransferase. Biochemistry. 2004 May 25;43(20):5976–86. doi: 10.1021/bi049784+.
参考文献:10.1007/s10482-017-0831-9
摘要:Zhao JJ, Zhang J, Zhang RJ, Zhang CW, Yin HQ, Zhang XX. Rhizobium rhizosphaerae sp. nov., a novel species isolated from rice rhizosphere. Antonie Van Leeuwenhoek. 2017 May;110(5):651–6. doi: 10.1007/s10482-017-0831-9.
参考文献:10.1186/s40793-017-0220-z|10.1186/s40793-017-0283-x
摘要:Aserse AA, Woyke T, Kyrpides NC, Whitman WB, Lindström K. Draft genome sequences of Bradyrhizobium shewense sp. nov. ERR11T and Bradyrhizobium yuanmingense CCBAU 10071T. Environmental Microbiome. 2017 Dec 05;12(1):74. doi: 10.1186/s40793-017-0283-x.
参考文献:10.1007/s00284-019-01729-1
摘要:Rao Q, Liu Y, Chen C, Lin Q, Ren L, Huang M, Tu J, Luo T. Pseudomonas ovata sp. nov., Isolated from the Skin of the Tail of Farmed Murray cod (Maccullochella peelii peelii) with a Profound Ulceration. Curr Microbiol. 2019 Oct;76(10):1168–74. doi: 10.1007/s00284-019-01729-1.
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