专利号:US-12441673-B2 优先权日:2019-12-09 标题:Catalysed synthesis of fluorinated alkenes and fluorinated alkene compositions 发明人:PETROV VIACHESLAV A; JUHASZ JASON R; SIMONI LUKE DAVID; BRANDT DREW RICHARD; STEHMAN JONATHAN P 权利人:THE CHEMOURS COMPANY FC LLC 摘要:A method of producing a fluoroolefin includes contacting a compound of formula (1), RfCX1â•?CHCF3, with a fluorinated ethylene compound of formula (2), CX2X3â•?CX4X5 in the presence of a catalyst. In the compound of formula (1), Rf is a linear or branched C1-C10 perfluorinated alkyl group and X1 is H, Br, Cl, or F. In the compound of formula (2), X2, X3, X4, and X5 are each independently H, Br, Cl, or F and at least three of X2, X3, X4, and X5 are F. The resulting composition comprises a compound of formula (3), Rf(CF2)nCX6â•?CH(CF2)mCX7X8CFX9X10. In the compound of formula (3), X6, X7, X8, X9, and X10 are each independently H, Br, Cl, or F, and the total number of each of H, Br, Cl, and F corresponds to the total number of each of H, Br, Cl, and F provided by the compounds of formulae (1) and (2).
专利号:US-2025145551-A1 优先权日:2022-02-25 标题 :Synthesis of hfo-153-10mczz including catalytic coupling of hcfc-225ca or cfc-215cb 发明人:SUN XUEHUI; BRANDT DREW RICHARD; LOUSENBERG ROBERT DANIEL; MINOR BARBARA HAVILAND 权利人:CHEMOURS CO FC LLC 摘要:In an embodiment, a method of producing a fluoroolefin comprises coupling 3,3-dichloro-1,1,1,2,2-pentafluoropropane (CF3—CF2—CHCl2) in a liquid phase in the presence of a catalyst to form a composition comprising 1,1,1,2,2,5,5,6,6,6-decafluoro-3-hexene (CF3CF2CHâ•?CHCF2CF3). In another embodiment, a method of producing a fluoroolefin comprises coupling 1,1,1-trichloropentafluoropropane (CF3—CF2—CCl3) in a vapor phase in the presence of a first catalyst to form a composition comprising 3,4-dichloro-1,1,1,2,2,5,5,6,6,6-decafluoro-3-hexene (CF3—CF2—CClâ•?CCl—CF2—CF3). The method may further include forming the CF3—CF2—CCl3 in a vapor phase from CF3CF2CHmCl3-m and chlorine (Cl2). The method may further include hydrodechlorinating the 3,4-dichloro-1,1,1,2,2,5,5,6,6,6-decafluoro-3-hexene with hydrogen (H2) in a vapor phase in the presence of a second catalyst to form a composition comprising CF3CF2CHâ•?CHCF2CF3 and 3-chloro-1,1,1,2,2,5,56,6,6-decafluoro-3-hexene (CF3CF2CClâ•?CHCF2CF3).
专利号:US-11952302-B2 优先权日:2020-08-06 标 题:Process for the preparation of fluorinated quartz glass 发明人:OCHS STEFAN; KAYSER THOMAS; TROMMER MARTIN; LANGNER ANDREAS; PIHAN SASCHA; SCHUSTER KAY; HÜNERMANN MICHAEL 权利人:HERAEUS QUARZGLAS 摘要:A process for the production of a fluorinated quartz glass including the steps of generating SiO2 particles in a synthesis burner; depositing the resulting SiO2 particles into a body; and vitrifying the resulting body, wherein a fluorinating agent having a boiling point greater than or equal to −10° C. is supplied to the synthesis burner.
专利号:WO-2023239377-A1 优先权日:2022-06-10 标题:Digital microfluidic devices for cell-free protein synthesis 发明人:SENGUPTA RAGHUVIR N; SHKOLNIKOV VIKTOR; BARCELO STEVEN 权利人:HEWLETT PACKARD DEVELOPMENT CO 摘要:Examples are directed to an apparatus include a digital microfluidic device (DMF) and circuitry. The DMF includes a housing including an interconnected chamber and with a two-dimensional array of electrodes couplable to the interconnected chamber, a plurality of fluidic inlets fluidically coupled to the interconnected chamber to input a plurality of reaction fluids, and a magnetic unit coupled to the interconnected chamber. The circuitry is to selectively actuate electrodes of the two-dimensional array of electrodes and the magnetic unit to cause movement of fluid droplets of the plurality of reaction fluids and to provide a thermal zone within a first portion of the interconnected chamber.
专利号:JP-2025507468-A 优先权日:2022-02-25 标题 :Synthesis of HFO-153-10MCZZ involving catalytic coupling of HCFC-225CA or CFC-215CB
专利号:US-2022388929-A1 优先权日:2019-12-09 标题 :Catalysed synthesis of fluorinated alkenes and fluorinated alkene compositions
参考标题:Photo-On-Demand Base-Catalyzed Phosgenation Reactions With Chloroform: Synthesis Of Arylcarbonate And Halocarbonate Esters 作者:Yuka Hashimoto,Sasuga Hosokawa,Fengying Liang,Yuto Suzuki,Namin Dai,Gegen Tana,Kazuo Eda,Toshifumi Kakiuchi,Takashi Okazoe,Hidefumi Harada,Akihiko Tsuda |发布日期:2021.7.16 摘要:Utilized As Solvents And Reagents For C1 Building Blocks In Organic Synthesis. This Study Reports A Novel Photo-On-Demand In Situ Synthesis Of Carbonate Esters With Chcl3 Solutions Containing A Mixture Of An Aromatic Or Haloalkyl Alcohol Having Relatively High Acidity, And An Organic Base. We Found That The Acid-Base Interaction Of The Alcohol And Base In The Chcl3 Solution Plays A Key Role In Enabling The
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摘要:S25 | OECDPFAS | List of PFAS from the OECD | DOI:10.5281/zenodo.2648775 摘要:S95 | PFASANEXCH | PFAS List from the NORMAN PFAS Analytical Exchange Activity | DOI:10.5281/zenodo.6384309