CAS: 6165-68-0; Thiophen-2-Ylboronic Acid

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CAS号1003-09-4 2-溴噻吩 | CAS号3437-95-4 2-碘噻吩 | CAS号1158984-92-9 2-噻吩硼酸甲基亚氨基二乙酸酯 | CAS号150-46-9 硼酸三乙酯 | CAS号188290-36-0 Thiophene(SIV) | CAS号121-43-7 硼酸三甲酯 | CAS号89180-57-4 2-thiophenemagn... | CAS号688-74-4 硼酸三丁酯 | CAS号22092-92-8 N,N-二异丙基氨基硼烷 | CAS号7732-18-5 水 | CAS号105125-00-6 3'-溴-2,2':5',2'... | CAS号1006384-44-6 2,3-dibromo-5,2... | CAS号3779-27-9 2,2'-联噻吩-5-甲醛 | CAS号6072-49-7 2-噻吩基苯甲酸 | CAS号32364-30-0 5-噻吩-2-基-2-糠醛 | CAS号3319-99-1 2-(2-噻吩)吡啶 | CAS号40133-22-0 2-(4-溴苯基)噻吩 | CAS号17595-86-7 4-噻吩-2-硼酸甲酯 | CAS号18013-97-3 2,5-二溴对苯二甲酸二乙酯 | CAS号492-97-7 2,2'-双噻吩

2-噻吩基锂置于硼酸三乙酯体系中,用 四氢呋喃 作为反应溶剂,化学反应 1.0H,以10 G的收率获得产物2-噻吩硼酸
参考文献:Synthetic Routes To Fluorescent Dyes Exhibiting Large Stokes Shifts
标题:Synthetic Routes To Fluorescent Dyes Exhibiting Large Stokes Shifts
摘要:Derivatives Of Isomeric 2-(Hydroxytolyl)-4,6-Dimethylamino-1,3,5-Triazines Have Been Synthesized In High Yields In A Controlled Manner Using A Multistep Reaction Sequence. Iodination Of Either 2-(1'-Hydroxy-6'-Methylphen-2'-yl)-Or 2-(1'-Hydroxy-4'-Methylphen-2'-yl)-4,6-Dimethylamino-1,3,5-Triazine With Icl Provides Species Differing In The Positioning Of The Iodo Group Relative To The Hydroxyl Which Readily Undergo Suzuki,Sonogashira,And Heck Reactions Under Pd(0) Catalysis. Thus,Thienyl,Bisthienyl,And 3,4-Ethylenedioxythienyl Groups Have Been Directly Grafted,While Unsubstituted Polycyclic Aromatics Such As Pyrene And Perylene Have Been Linked Via Alkyne Bridges,As Have Ethynyldifluoroborondipyrromethane (Bodipy) Dyes Prepared In Situ. The Presence Of A Hydrogen Bond In The Ground State Involving The Hydroxyl Substituent Has Been Established By Proton NMR And Several X-Ray Structure Determinations. All Of The New Dyes With A Simple Substituent (Phenyl,Thienyl) Exhibited A Pronounced Green Fluorescence Resulting From An Intramolecular Proton Transfer:In:The Excited State (Esipt) Which Produces A Large Stokes Shift (> 10 000 Cm(-1)). With Other Dyes,The Fluorescence Of The Keto Form Responsible For The Esipt Process Could Be Used As The.Input Energy In Efficient Intramolecular Energy Transfer Processes. Replacing Perylene With Pyrene Allowed Reversal Of The Direction Of Energy Transfer From The Polyaromatic Module To The Keto Form.
DOI:10.1021/jo301059U

专利信息

专利号:US-8822702-B2
优先权日:2002-12-20
标 题 :Synthesis of amines and intermediates for the synthesis thereof
发明人：BERENS ULRICH; DOSENBACH OLIVER; SPRENGER DANIEL
权利人:BERENS ULRICH; DOSENBACH OLIVER; SPRENGER DANIEL; BASF SE
摘要:The invention relates in a first embodiment to a method for the manufacture of esters of the formula I, n nor especially of amides of the formula II,n n nwherein the symbols have the meanings given in the specification, as well as other intermediates and compounds useful in the synthesis of tryptamines and other substances mentioned in the title. The synthesis methods and intermediates are useful in the synthesis of pharmaceuticals.

专利号:WO-2021019558-A1
优先权日:2019-07-30
标题 :An efficient method for synthesis of 5-(3-pyridyl)-2,2'-bithiophene(sensitizer)
发明人：DATLA ANUPAMA; NAGRE PRASHANT; TAMORE JAGDISH; PRABHU MANOJKUMAR SADANAND; KADAM SACHIN VASANT
权利人:FERMENTA BIOTECH LTD
摘要:The present invention discloses an efficient process for synthesis of photosensitizer, 5-(3-pyridyl)-2,2'-bithiophene in high yield and purity.

专利号:US-9328109-B2
优先权日:2013-01-14
标 题:Process for the preparation of benzohetero [1, 3] diazole compounds disubstituted with heteroaryl groups
发明人：BIANCHI GABRIELE; PO' RICCARDO
权利人:ENI SPA
摘要:Process for the preparation of a benzohetero-[1,3]diazole compound disubstituted with brominated heteroaryl groups which comprises reacting at least one dihalogenated benzohetero[1,3]diazole compound with at least one brominated heteroaryl compound. Said benzohetero[1,3]diazole compound disubstituted with brominated heteroaryl groups can be advantageously used in the synthesis of compounds useful in the construction of solar concentrators (LSCs—“Luminescent Solar Concentratorsâ€?). Furthermore, said benzohetero[1,3]diazole compound disubstituted with brominated heteroaryl groups can be advantageously used in the synthesis of photoactive polymers useful in the construction of photovoltaic devices (or solar devices) such as, for example, photovoltaic cells (or solar cells), photovoltaic modules (or solar modules), on both rigid or flexible supports. Furthermore, said benzohetero[1,3]diazole compound disubstituted with brominated heteroaryl groups can be advantageously used as precursor of monomeric units in the synthesis of semiconductr polymers.

专利号:US-7176230-B2
优先权日:2004-11-16
标题 :Synthesis of indole analogs of 1-benzyl-3-(5′-hydroxymethyl-2′-furyl) indazole (YC-1) as anti-platelet agents
发明人：KUO SHENG-CHU; LEE FANG-YU; HUANG TSANG-MIAO; TENG CHE-MING; LEE ON; WU CHIN-YI; HWANG CHRONG-SHIONG; HUNG CHI-YING
权利人:YUNG SHIN PHARM IND CO LTD
摘要:The present invention synthesizes a series of novel indole analogs of 1-benzyl-3-(5′-hydroxymethyl-2′-furyl)indazole (YC-1), and their anti-platelet activity.

专利号:US-2023212216-A1
优先权日:2019-12-20
标 题:Synthesis of lactone derivatives and their use in the modification of proteins
发明人：MORRIS ALEXANDER REDFERN; SUTOV GRIGORIJ; BRUNE KARL DIETRICH
权利人:GENIE BIOTECH UK LTD
摘要:Site-specific modifications of proteins are desirable in biotechnological applications such as biopharmaceuticals, immunotherapy, vaccines, and are useful in chemical biology. Gluconoylation is a non-enzymatic, covalent, post-translational modification commonly observed on N-terminal His-Tags bearing proteins. We synthesized glucono-1,5-lactone derivatives, including azido variants for selective acylation. High yield acylation is achieved by simply mixing derivatives with target protein amidst diverse conditions of temperatures, aqueous buffers, excipients, or complex cell lysate.

专利号:US-2022267323-A1
优先权日:2019-07-23
标题 :Synthesis of bicyclic inhibitors of histone deacetylase
发明人：FULLER NATHAN OLIVER; HEWITT MICHAEL CHARLES; ASSELIN SYLVIE M; LUKE WAYNE DOUGLAS
权利人:ALKERMES INC
摘要:Provided herein are synthetic methods for the preparation of compounds having the Formula: (I) and (I′) and salts thereof.