CAS: 80863-62-3; (S)-3-Amino-4-Oxo-4-(((R)-1-Oxo-1-((2,2,4,4-Tetramethylthietan-3-yl)Amino)Propan-2-yl)Amino)Butanoic Acid
该化合物是一种合成甜食器,属于氨基酸糖类,以其高甜度闻名,估计其甜度比苏格罗斯高数千倍,使它成为低热量和无糖食品的诱人选择.Alitame 由氨基酸,特别是片酸和亚麻宁混合组成,有助于其甜味描述.它在一系列pH条件下保持稳定,即使在接触热时也保持其甜度,使之适合各种烹饪和烘烤用途.此外, Alitame 的热度值很低,有利于体重管理和糖尿病饮食. 然而,像许多人工糖一样,其使用需要不同国家的监管批准,并不断研究潜在的健康影响.总的来说,Alitame 提供了一种适合传统糖的多种替代品,吸引消费者寻求更健康的饮食选择.
- 英文名称(S)-3-Amino-4-Oxo-4-(((R)-1-Oxo-1-((2,2,4,4-Tetramethylthietan-3-yl)Amino)Propan-2-yl)Amino)Butanoic Acid
- 中文名称阿力甜
- IUPAC名称(S)-3-amino-4-oxo-4-(((R)-1-oxo-1-((2,2,4,4-tetramethylthietan-3-yl)amino)propan-2-yl)amino)butanoic acid
- 其它别名L-alpha-Aspartyl-N-(2,2,4,4-tetramethyl-3-thietanyl)-D-alaninamide; (3S)-3-Amino-4-oxo-4-[[(2R)-1-oxo-1-[(2,2,4,4-tetramethylthietan-3-yl)amino]propan-2-yl]amino]butanoic acid
- CAS编号80863-62-3
- MFCD编号:MFCD00868124
- FDA UNII编号:PCE8DAE750
- 分子式:C14H25N3O4S
- 分子量:331.43
- 产品CID: 1803576
- 产品分类食品添加剂 → 甜味剂
物理性质
- 熔点136-147°
- 沸点608.5±55.0 °C at 760 mmHg
- 闪点321.8±31.5 °C
- 密度1.3±0.1 g/cm3
- PH:D25 +40 to +50° (c = 1 in water)
- pKa:3.71±0.10(预测)
- PSA:146.82
- LogP:1.17
- 折射率1.560
- 蒸汽压0.0±3.8 mmHg at 25°C
- 溶解性Methanol (Slightly)
- 外观形态白色至类白色固体
- 储存条件室温
- 产品应用阿力甜(80863-62-3)的用途:是新型,高甜度的甜味剂.我国规定可作为餐桌甜味剂,最大用量0.015g/包,片,用于胶姆糖,陈皮,话梅,话李和杨梅干,最大使用量0.3g/kg;在饮料,冰淇淋和雪糕,最大使用量0.1g/kg.
上下游产品
阿力甜-丙氨酸酰胺杂质 3-(D-Alaninamido)-2,2,4,4-Tetramethylthietane 80875-07-6合成工艺路线路线简述
- 80875-07-6 + 131021-87-9 = 80863-62-3
反应条件:1.1 Solvents: Tetrahydrofuran
标题:Preparation Of Aspartyl-D-Alanine N-(Thietan-3-Yl)Amides (Alitam).
参考文献:Germany
(2R)-2-[[(2S)-4-Methoxy-4-Oxo-2-(Phenylmethoxycarbonylamino)Butanoyl]Amino]Propanoic Acid,3-氨基-2,2,4,4-四甲基硫杂环丁烷 反应生成 L-天门冬酰-N-(2,2,4,4-四甲基-3-硫杂环丁基)-D-丙氨酰胺
参考文献:Brennan,Thomas M.;Hendrick,Michael F.
标题:Brennan,Thomas M.;Hendrick,Michael F.
海关参考信息
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2912110000-甲醛
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- 详情请参考：📖 海关编码查询和海关进出口税则
专利信息
专利号:US-2017204442-A1
优先权日:2014-05-29
标题 :Enzymatic synthesis of soluble glucan fiber
发明人：DICOSIMO ROBERT; CHENG QIONG; ELIOT ANDREW C; OUWEHAND ARTHUR; PAYNE MARK S; YOU ZHENG
权利人:DU PONT
摘要:An enzymatically produced soluble α-glucan fiber composition is provided suitable for use as a digestion resistant fiber in food and feed applications. The soluble α-glucan fiber composition can be blended with one or more additional food ingredients to produce fiber-containing compositions. Methods for the production and use of compositions comprising the soluble α-glucan fiber are also provided.
专利号:US-10907185-B2
优先权日:2014-05-29
标 题 :Enzymatic synthesis of soluble glucan fiber
发明人：CHENG QIONG; DICOSIMO ROBERT; OUWEHAND ARTHUR; YOU ZHENG; LAI JIAN PING; YU ZHEYONG; ZHANG ZHENGHONG
权利人:DUPONT IND BIOSCIENCES USA LLC
摘要:An enzymatically produced soluble α-glucan fiber composition is provided suitable for use as a digestion resistant fiber in food and feed applications. The soluble α-glucan fiber composition can be blended with one or more additional food ingredients to produce fiber-containing compositions. Methods for the production and use of compositions comprising the soluble α-glucan fiber are also provided.
专利号:WO-2005020930-A3
优先权日:2003-09-02
标题 :Improved syntheses of alitame
发明人：KNOBLOCK KEN; SHAH PANKAJ
权利人:KNOBLOCK KEN; SHAH PANKAJ
摘要:The present invention relates to an improved synthesis of alitame (3-L-alpha-aspartyl-D-alanylamido-2,2,4,4-tetramethylthietanylamine) in which residual iodine species formed during the deodorization step are eliminated, resulting in an improved yield and a purer, more consistent product.
专利号:US-2017198323-A1
优先权日:2014-05-29
标题:Enzymatic synthesis of soluble glucan fiber
发明人：CHENG QIONG; DICOSIMO ROBERT; OUWEHAND ARTHUR; YOU ZHENG; PAYNE MARK S; PRASAD JAHNAVI CHANDRA
权利人:DU PONT
摘要:An enzymatically produced soluble α-glucan fiber composition is provided suitable for use as a digestion resistant fiber in food and feed applications. The soluble α-glucan fiber composition can be blended with one or more additional food ingredients to produce fiber-containing compositions. Methods for the production and use of compositions comprising the soluble α-glucan fiber are also provided.
专利号:US-2017198322-A1
优先权日:2014-05-29
标题:Enzymatic synthesis of soluble glucan fiber
发明人：CHENG QIONG; DICOSIMO ROBERT; ELIOT ANDREW C; OUWEHAND ARTHUR; ROESCH BRIAN MICHAEL; ROTHMAN STEVEN CARY; RUEBLING-JASS KRISTIN; YOU ZHENG
权利人:DU PONT
摘要:An enzymatically produced soluble α-glucan fiber composition is provided suitable for use as a digestion resistant fiber in food and feed applications. The soluble α-glucan fiber composition can be blended with one or more additional food ingredients to produce fiber-containing compositions. Methods for the production and use of compositions comprising the soluble α-glucan fiber are also provided.
专利号:US-12110347-B2
优先权日:2014-05-29
标 题:Enzymatic synthesis of soluble glucan fiber
发明人：CHENG QIONG; DICOSIMO ROBERT; OUWEHAND ARTHUR; YOU ZHENG; PAYNE MARK S; LAI JIAN PING; RUEBLING-JASS KRISTIN; ROTHMAN STEVEN CARY
权利人:NUTRITION & BIOSCIENCES USA 4 INC
摘要:An enzymatically produced soluble α-glucan fiber composition is provided suitable for use as a digestion resistant fiber in food and feed applications. The soluble α-glucan fiber composition can be blended with one or more additional food ingredients to produce fiber-containing compositions. Methods for the production and use of compositions comprising the soluble α-glucan fiber are also provided.
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主要参考文献
1: Lakade SS, Zhou Q, Li A, Borrull F, Fontanals N, Marcé RM. Hypercrosslinked particles for the extraction of sweeteners using dispersive solid-phase extraction from environmental samples. J Sep Sci. 2018 Apr;41(7):1618-1624. doi: 10.1002/jssc.201701113. Epub 2018 Jan 25. doi: 10.1016/j.clnesp.2017.01.004. Epub 2017 Feb 4. Review. doi: 10.1007/s00216-014-8355-x. Epub 2014 Dec 4.
4: Chattopadhyay S, Raychaudhuri U, Chakraborty R. Artificial sweeteners - a review. J Food Sci Technol. 2014 Apr;51(4):611-21. doi: 10.1007/s13197-011-0571-1. Epub 2011 Oct 21. Review.
5: Tsuruda S, Sakamoto T, Akaki K. [Simultaneous determination of twelve sweeteners and nine preservatives in foods by solid-phase extraction and LC-MS/MS]. Shokuhin Eiseigaku Zasshi. 2013;54(3):204-12. Japanese. Chinese. doi: 10.1080/19440049.2012.699475. Epub 2012 Jul 24. doi: 10.1007/s00216-011-4937-z. Epub 2011 Apr 5.
合成参考文献
参考文献:10.3358/shokueishi.49.31
摘要:Matsumoto H, Hirata K, Sakamaki N, Hagino K, Ushiyama H. [Simultaneous determination of neotame, alitame and aspartame in foods by HPLC]. Shokuhin Eiseigaku Zasshi. 2008 Feb;49(1):31–6. doi: 10.3358/shokueishi.49.31.
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