CAS: 1313-13-9; Manganese(Iv) Oxide

上下游产品

manganese(ll) chloride sodium hydroxide potassium permanganate manganese(II) nitrate3-(pyridin-3-yl)propiolaldehyde manganese(ll) chloride permanganate(VII) ion oxygen

对溴甲苯置于potassium Permanganate体系中,用 水 用作溶剂,化学反应生成二氧化锰
参考文献:Reagents And Methods For Sirtuin Capture
标题:Reagents And Methods For Sirtuin Capture
摘要:这项发明提供了一种制备sirtuin复合物的方法,一种检测样品中sirtuin的方法,以及一种筛选抑制sirtuin去乙酰化酶活性的化合物的方法.该方法包括(A)提供具有以下公式的sirtuin底物: (B)提供具有以下公式的nad+或nad+类似物: 以及(C)提供sirtuin,其中r1-R4,A1,A2和n如本文所定义.

专利信息

专利号:WO-2025053792-A1
优先权日:2023-09-06
标题:Collective synthesis of phantomolin family through total synthesis of the sesquiterpene lactone molephantin
发明人：CHIBA SHUNSUKE; PATOURET REMI HENRI LOUIS; LI HOI YEUNG; LAI SOAK KUAN
权利人:UNIV NANYANG TECH
摘要:Disclosed herein are processes to generate an intermediate in the total synthesis of (+)- molephantin or a derivative thereof, and a total synthesis of (+)-molephantin or a derivative thereof. Also disclosed herein are methods of forming a compound of formula XIV and of forming a compound of formula XV, wherein compound of formula XIV and compound of formula XV are as defined in the description.

专利号:WO-2009104605-A1
优先权日:2008-02-18
标 题 :Novel intermediate for synthesis of ascofranone having various physiological activities, and novel shortened total synthesis method for ascofranone using the same
发明人：SAIMOTO HIROYUKI; HAGA YASUSHI
权利人:ARIGEN PHARMACEUTICALS INC; SAIMOTO HIROYUKI; HAGA YASUSHI
摘要:In the synthesis of ascofranone, a compound represented by formula (III), (IV), (V) or (VII) or an optical isomer thereof is used as an intermediate for the synthesis. [In the formulae, R 1 and R 2 independently represent a hydrogen atom, a C 1-7 alkyl group, a phenoxyalkyl group having a halogen atom on a carbon atom in a benzene ring therein, or a phenyl group having a C 1-7 alkoxy group or a C 1-7 alkoxycarbonyl group on a carbon atom in a benzene ring therein; and X represents a halogen atom or a group R 5 SO 3 (wherein R 5 represents a C 1-7 alkyl group or a phenyl group having a C 1-7 alkyl group on a carbon atom in a benzene ring therein).] By using the compound, it becomes possible to reduce the number of steps required for the total synthesis of ascofranone to 7 or 8 from 12 which is a number of the steps required for the conventional ascofranone total synthesis processes.

专利号:US-7326805-B2
优先权日:2003-05-07
标题 :Method for the synthesis of 4-hydroxyisoleucine and the derivatives thereof
发明人：MIOSKOWSKI CHARLES; CATALA CEDRIC; WAGNER ALAIN
权利人:MIOSKOWSKI CHARLES; CATALA CEDRIC; WAGNER ALAIN
摘要:The invention relates to a method for the synthesis of two isomers, at function OH, alone or in mixtures, of amino acids α or the derivatives thereof, having general formula (B), wherein: linkage C—O of the 4-position carbon (represented by symbol) denotes one or other of isomers III or IV, or mixtures thereof. Moreover, R 1 and R 2 represent: a hydrogen atom; or either R 1 or R 2 represents a hydrogen atom and the other substituent is a radical R a , an acyl group —COR a , such as acetyl, or a functional group —COOR a , —SO 2 R a , —N (R a , R b ), R a and R b , which are identical or different, representing a C1-C12 linear or branched alkyl radical, optionally substituted, an aryl group with one or more aromatic rings and heterocycles, comprising between 5 and 8C, optionally substituted, or aralkyl, the alkyl substituent and the aryl group being as defined above; or R 1 and R 2 both represent a substituent as defined above. R 3 represents a hydrogen atom or R a and R 4 has the significance of R a . The invention is characterised in that it comprises: the isomerisation of a compound having formula (I), wherein R 1 , R 2 , R a , R 3 and R 4 are as defined above, such as to produce a compound having formula (II); and the reduction of the carbonyl function thereof which, depending on the catalytic system employed and the formula (I) compound used, produces one of the isomers having general formula (III) or (IV) or a mixture thereof having formula (B). The invention can be used for the synthesis of (2S, 3R, 4S)-4-hydroxyisoleucine.

专利号:US-7601318-B2
优先权日:2000-09-26
标 题:Method for synthesis of carbon-coated redox materials with controlled size
发明人：ARMAND MICHEL; GAUTHIER MICHEL; MAGNAN JEAN-FRANCOIS; RAVET NATHALIE
权利人:HYDRO QUEBEC; CENTRE NAT RECH SCIENT; UNIV MONTREAL
摘要:A method for the synthesis of compounds of the formula C—Li x M 1−y M′ y (XO 4 ) n , where C represents carbon cross-linked with the compound Li x M 1−y M′ y (XO 4 ) n , in which x, y and n are numbers such as 0≦x≦2, 0≦y≦0.6, and 1≦n≦1.5, M is a transition metal or a mixture of transition metals from the first period of the periodic table, M′ is an element with fixed valency selected among Mg 2+ , Ca 2+ , Al 3+ , Zn 2+ or a combination of these same elements and X is chosen among S, P and Si, by bringing into equilibrium, in the required proportions, the mixture of precursors, with a gaseous atmosphere, the synthesis taking place by reaction and bringing into equilibrium, in the required proportions, the mixture of the precursors, the procedure comprising at least one pyrolysis step of the carbon source compound in such a way as to obtain a compound in which the electronic conductivity measured on a sample of powder compressed at a pressure of 3750 Kg·cm −2 is greater than 10 −8 S·cm −1 . The materials obtained have excellent electrical conductivity, as well a very improved chemical activity.

专利号:US-8022167-B2
优先权日:2006-12-21
标 题 :Process for the synthesis of diaminopyridines from glutaronitriles
发明人：MINTER AARON; STOKES BERLIN
权利人:MINTER AARON; STOKES BERLIN
摘要:A liquid-phase process is provided for the manufacture from glutaronitriles and related compounds of 2,6-diaminopyridine and related compounds, which are used industrially as compounds and as components in the synthesis of a variety of useful materials. The synthesis proceeds by means of a dehydrogenative aromatization process.

专利号:US-7452994-B2
优先权日:2001-09-12
标 题 :Synthesis of enantiomerically pure amino-substituted fused bicyclic rings
发明人：MCEACHERN ERNEST J; BRIDGER GARY J; SKUPINSKA KRYSTYNA A; SKERLJ RENATO T; YANG WEN
权利人:ANORMED INC
摘要:This invention describes various processes for synthesis and resolution of racemic amino-substituted fused bicyclic ring systems. One process utilizes selective hydrogenation of an amino-substituted fused bicyclic aromatic ring system. An alternative process prepares the racemic amino-substituted fused bicyclic ring system via nitrosation. In addition, the present invention describes the enzymatic resolution of a racemic mixture to produce the (R)- and (S)-forms of amino-substituted fused bicyclic rings as well as a racemization process to recycle the unpreferred enantioner. Further provided by this invention is an asymmetric synthesis of the (R)- or (S)-enantiomer of primary amino-substituted fused bicyclic ring systems.