CAS: 5471-63-6; 1,3-Diphenylisobenzofuran

该化合物是一种高度稳定的荧光有机化合物,广泛用作有机合成和材料科学的关键中间体,其僵硬的芳香结构以及扩大的 & conjugation系统使得其在单氧捕捉研究和光化学应用中作为发光探针方面特别宝贵.该化合物显示出强烈的蓝色荧光,增强了其在光电子材料中的效用,并成为先进聚合物的建筑块.其高热性和氧化性稳定性进一步确保了在高要求的实验条件下的可靠性能.研究人员支持1,3-二苯代苯并呋喃的可预见再活动及其与多种合成途径的兼容性.

结构式图片

相似化合物

5778-13-2 26870-25-7 1839-72-1

合成工艺路线路线简述

  • 合成目标产物 1,3-Diphenylisobenzofuran 主要起始原料 Methyl 2-Formylbenzoate And Phenylmagnesium Bromide
  • (文献来源)合成步骤主要原料 Methyl 2-Formylbenzoate 和 Phenylmagnesium Bromide
在 盐酸体系中,用 四氢呋喃,水 作为反应溶剂,以227 Mg的收率获得产物1,3-二苯基异苯并呋喃
参考文献:多功能和区域特异性合成功能化的1,3-二芳基异苯并呋喃.
标题:多功能和区域特异性合成功能化的1,3-二芳基异苯并呋喃.
摘要:已经开发了方便,通用和区域特异性的官能化的1,3-二芳基异苯并呋喃合成.它涉及芳基镁试剂的化学选择性加成至邻-芳酰基苯甲醛的醛官能团,其本身可通过水杨醛的n-芳酰基hydr的四乙酸铅氧化而容易地获得.因此已将各种官能团,包括硝基,碘或酯官能团,以完全的区域专一性定位在1,3-二苯基异苯并呋喃骨架上.
DOI:10.1021/ol801550A

海关参考信息

专利信息


专利号:US-11938546-B2
优先权日:2018-10-18
标题:Precision control of large-scale green synthesis of biodegradable gold nanodandelions as potential radiotheranostics
发明人:LO LEU-WEI; CHUANG YAO-CHEN
权利人:NATIONAL HEALTH RES INST; LO LEU WEI
摘要:The present invention relates to a new type of metabolizable flower-like gold nanodandelion (GND), which possesses features: (1) large scale green synthesis with high monodispersity and a circa 100% yield; (2) cellular/physiological degradability; (3) precision control of the shape, petal number and size; (4) highly efficient radiotheranostics encompassing better enhanced CT contrast and pronounced x-ray induced ROS generation than conventional spherical AuNP.

专利号:US-6448412-B1
优先权日:1995-07-31
标题:Methods for the preparation and characterization of multi-substituted fullerenes
发明人:MURPHY RANDALL B; WILSON STEPHEN R; LU QUING
权利人:SPHERE BIOSYSTEMS INC
摘要:The invention is directed to multiply-substituted fullerene derivatives of novel configurations, and methods for their preparation and use. The methods involve the combinatorial synthesis of a library of fullerene derivatives and comprises the steps of forming a mixture of fullerene derivatives by reacting the C n fullerene with two or more reactive precursor compounds, and removing the unreacted compounds to yield the fullerene derivatives having the desired activity. Methods for the identification and screening of a combinatorial library of fullerenes by 3 He-nuclear magnetic resonance and electrospray mass spectrometry to define members with the optimal desired activity are also provided.

专利号:US-9611281-B2
优先权日:2013-12-05
标题:BODIPY derivatives and methods of synthesis and use thereof
发明人:YOU YOUNGJAE; AWUAH SAMUEL; WATLEY RYAN
权利人:UNIV OKLAHOMA
摘要:Derivatives of BODIPY (boron dipyrromethene difluoride) and their synthesis and use are disclosed.

专利号:US-2009054649-A1
优先权日:2005-09-22
标题 :Bridged Organosilane and Production Method Thereof
发明人:SHIMADA TOYOSHI; GOTO YASUTOMO; INAGAKI SHINJI; MIZOSHITA NORIHIRO; IKAI MASAMICHI
权利人:TOYOTA CHUO KENKYUSHO KK; TOYOSHI SHIMADA
摘要:Provided is a bridged organosilane, which has a large complex organic group, and which is useful in the synthesis of a mesoporous silica and a light-emitting material, and a production method of the bridged organosilane. The bridged organosilane is expressed by the following general formula (1): n n n n n n n n n n [in the formula (1), q represents an integer in a range from 2 to 4, X 1 — represents a substituent selected from the group consisting of substituents expressed by the following general formulae (2) to (5): n n n n n n n n n n (in the formulae (2) to (5), R 1 represents alkyl group having 1 to 5 carbon atoms, R 2 represents an allyl group, and n represents an integer in a range from 0 to 3, and m represents an integer in a range from 0 to 6), and A 1 represents an organic group expressed by, for example, the following general formula (6): n n n n n n n n n n (in the formula (6), Y 1 < represents a substituent expressed by, for example, Oâ•?<)].

专利号:TW-202015706-A
优先权日:2018-10-18
标题 :Synthesis of degradable flower-like gold nanoparticles and its use for radiological diagnosis and treatment

专利号:WO-2020081088-A1
优先权日:2018-10-18
标题:Precision control of large-scale green synthesis of biodegradable gold nanodandelions as potential radiotheranostics
武汉市罗氏科技发展有限公司
⚠️ 未注册 · 未认证企业
⚠️ 该商家尚未完成注册及企业认证,请用户仔细辨别,谨慎交易。
数据来源于公开网络搜索,平台未作核实,请自行辨别。
🏢敬请 企业认领
🏬开设公司展台
📢获取免费会员权益
🎖️点亮专属注册企业标签
📇展现公司完整信息 样本查看立即注册认领 →
网址: http://www.luoshikg.com
企业联系电话:18986168071;19307247857👤
📞武汉市罗氏科技发展有限公司 ⚠️参考联系方式
联系人:罗经理;祝经理
电话:18986168071;19307247857
手机:18986168071;19307247857
传真:027-88121016;QQ1712680783
邮箱:18986168071@163.com
通信地址: 湖北省武汉市洪山区洪山工业园
邮编: 430064
🆔 联系时候可告知是从"百琢研"平台获取的信息.
⚠️ 声明: 该企业未认证、未认领,请自行辨别信息的真实性和可靠性。咨询或交易时请注意风险评估与信息核实,百琢研不参与任何交易。企业认领注册入口→

地址:湖北省武汉市洪山区洪山工业园
⚠️ 未注册 · 未认证企业
注册入口 备注: 📌 数据来源说明:本展台内容基于各搜索引擎等公开数据整理,仅作展示用途。请用户自行辨别
✉️ 若企业需抹除展台内容或有异议, 请通过页面底部联系方式告知我们,我们会尽快处理。
武汉欣扬瑞和化学科技有限公司
⚠️ 未注册 · 未认证企业
⚠️ 该商家尚未完成注册及企业认证,请用户仔细辨别,谨慎交易。
数据来源于公开网络搜索,平台未作核实,请自行辨别。
🏢敬请 企业认领
🏬开设公司展台
📢获取免费会员权益
🎖️点亮专属注册企业标签
📇展现公司完整信息 样本查看立即注册认领 →
网址: http://www.ruihechem.com
企业联系电话:15926260361👤
📞武汉欣扬瑞和化学科技有限公司 ⚠️参考联系方式
联系人:罗先生
电话:15926260361
手机:15926260361
传真:QQ:1930063008
邮箱:1930063008@qq.com
通信地址: 襄阳余家湖化工园
邮编: 441000
🆔 联系时候可告知是从"百琢研"平台获取的信息.
⚠️ 声明: 该企业未认证、未认领,请自行辨别信息的真实性和可靠性。咨询或交易时请注意风险评估与信息核实,百琢研不参与任何交易。企业认领注册入口→

地址:襄阳余家湖化工园
⚠️ 未注册 · 未认证企业
注册入口 备注: 📌 数据来源说明:本展台内容基于各搜索引擎等公开数据整理,仅作展示用途。请用户自行辨别
✉️ 若企业需抹除展台内容或有异议, 请通过页面底部联系方式告知我们,我们会尽快处理。
第 1 / 1 页
现货

供应商参考报价(招募中)

品牌试剂参考报价(招募中)

📌 第三方产品分析报告

✅ COA系统入驻 | 共享模式

主要参考文献


1: Boeré RT, Dibble PW, Fischer KE. 1,3-diphenylisobenzofuran. Acta Crystallogr Sect E Struct Rep Online. 2008 Mar 12;64(Pt 4):o686. doi: 10.1107/S1600536808006016.
2: Johnson JC, Michl J. 1,3-Diphenylisobenzofuran: a Model Chromophore for Singlet Fission. Top Curr Chem (Cham). 2017 Sep 11;375(5):80. doi: 10.1007/s41061-017-0162-3. 9(2):025003. doi: 10.1088/2050-6120/abe219. 51(1):38-46. doi: 10.1080/10715762.2016.1262541. Epub 2016 Dec 13. 18(9):2112-2124. doi: 10.1039/c9pp00283a. Epub 2019 Aug 29. 14(32):7193-7197. doi: 10.1021/acs.jpclett.3c01736. Epub 2023 Aug 7. 117(16):4680-95. doi: 10.1021/jp310979q. Epub 2013 Mar 7. 80(1):80-9. doi: 10.1021/jo502004r. Epub 2014 Dec 1. 76(3):920-38. doi: 10.1021/jo102240u. Epub 2011 Jan 10. 27(2):143-9. doi: 10.1016/0165-022x(93)90058-v.

合成参考文献


摘要:Kawase, T., Science of Synthesis, (2008) 44, 400.
摘要:Toyota, S.; Iwanaga, T., Science of Synthesis, (2010) 45, 840.
摘要:Waldvogel, S. R.; Welschoff, N., Science of Synthesis, (2010) 45, 1172.
摘要:Qian, D.; Zhang, J., Science of Synthesis Knowledge Updates, (2017) 1, 12.
摘要:Kwiecień, H., Science of Synthesis Knowledge Updates, (2018) 3, 82.
📝 需求与反馈
尽可能描述清楚需求与问题信息
×

通知