CAS: 93-08-3; 1-(Naphthalen-2-yl)Ethanone

• 英文名称1-(Naphthalen-2-yl)Ethanone
• 中文名称2-萘乙酮
• IUPAC名称1-(Naphthalen-2-yl)ethanone
• 其它别名.Beta.-Acetylnaphthalene; 1-(Naphthalen-2-yl)Ethanone; Beta -Naphthyl Methyl Ketone; Beta-Acetonaphthone; .Beta.-Naphthyl Methyl Ketone; Methyl Beta-Naphthyl Ketone, >=, Fcc, Fg; Cetone D; .Beta.-Acetonaphthalene; 2-Naphthyl Methyl
• CAS编号93-08-3
• MFCD编号:MFCD00004108
• EINECS号:202-216-2
• 分子式:C12H10O
• 分子量:170.21
• 产品CID: 2463198
• 产品分类有机原料→分子砌块→芳环类化合物→萘类化合物

• 相似结构搜索
• 产品信息参考;;;
• InChIKey: XSAYZAUNJMRRIR-UHFFFAOYSA-N
• InChI=1S/C12H10O/c1-9(13)11-7-6-10-4-2-3-5-12(10)8-11/h2-8H,1H3…
• 计算化学: 氢键受体数1.0氢键供体数0.0可旋转键数1.0

相似化合物

物理性质

• 熔点52-56°C
• 沸点300-301°C at 760 mmHg
• 闪点168°C
• 密度1.1±0.1 g/cm3
• pKa:0[at 20 °C]
• PSA:17.07
• LogP:3.0424
• 折射率1.615
• 蒸汽压0.0±0.6 mmHg at 25°C
• 溶解性0.272G/l
• 敏感性1.口服有害，使用时应避免吸入本品的粉尘，避免与眼睛及皮肤接触。2. 存在于烟气中。3.有两种位置异构体，此处内容信息对应于β-乙酰萘。
• 外观形态白色细结晶粉末和块状物
• 储存条件密封, 常温干燥保存
• 产品应用β-萘乙酮是有机合成的原料.
• 性质描述针状体结晶.熔点56°C,沸点301-303°C,171-173°C(2.27kPa).溶于苯,乙醇和乙醚.

MSDS等安全信息

• GHS象形图
• GHS符号GHS07 & GHS09;
  注释: Exclamation mark & Environment
• 危险类别皮肤腐蚀/刺激 类别2
  严重眼刺激 类别2
  水生慢性毒性 类别2
  急性毒性 类别4(经口)
  特定目标器官毒性 - 单次接触 类别3
  严重眼刺激 类别2A
• 警示词Warning(警告)
• 危险描述H315 |造成皮肤刺激.
  H319 |造成严重眼刺激.
  H411 |对水生生物有毒并具有长期持续影响.
  H302 |吞咽有害.
  H335 |可能引起呼吸道刺激.
• 防范说明P273-P391-P501
• 危险等级9
• UN编号3077.0
• 危险品标志Xn,Xi,N
• 风险等级Irritant
• 包装等级Ⅲ
• 安全声明26-36-61-24/25-22-36/37
• 危险类别码36/37/38-51/53-22-20/21/22
• WGK Germany3

欧盟法规

上下游产品

合成工艺路线路线简述

• 合成目标产物 2-Acetonaphthone 主要起始原料 Naphthalene, 2-[1,1-Bis(Phenylthio)Ethyl]-
• 7228-47-9 = 93-08-3
  反应条件:1.1 Reagents: Octakis(Acetato-Ko)[μ4-(Tricyclo[3.3.1.13,7]Decane-1,3,5,7-Tetrayltetra-4,1-Phen... Catalysts: Tempo Solvents: Dichloromethane; Rt
  标题:An Excellent Dual Recycling Strategy For The Hypervalent Iodine/nitroxyl Radical Mediated Selective Oxidation Of Alcohols To Aldehydes And Ketones
  作者:Dohi,Toshifumi; Fukushima,Kei-Ichiro; Kamitanaka,Tohru; Morimoto,Koji; Takenaga,Naoko; Et Al
  参考文献:Green Chemistry 日期:2012 卷标:14(5) 页码:1493-1501]
  
  1355563-79-9 = 93-08-3
  反应条件:1.1 Reagents: Sodium Iodide,Hydrogen Peroxide Catalysts: Niobium Pentachloride Solvents: Ethyl Acetate,Water; 3 H,Rt1.2 Reagents: Sodium Bicarbonate,Sodium Thiosulfate Solvents: Water; Rt
  标题:Deprotection Of Dithioacetals With 30% Hydrogen Peroxide Catalyzed By Tantalum(V) Chloride-Sodium Iodide Or Niobium(V) Chloride-Sodium Iodide
  作者:Kirihara,Masayuki; Noguchi,Takuya; Okajima,Nobuhiro; Naito,Sayuri; Ishizuka,Yuki; Et Al
  参考文献:Tetrahedron 日期:2012 卷标:68(5) 页码:1515-1520]
  
  854841-26-2 = 93-08-3
  反应条件:1.1 Reagents: Water Solvents: Acetonitrile-D3; 20 Min,Rt
  标题:An Efficient Photoinduced Deprotection Of Aromatic Acetals And Ketals
  作者:Thevenet,Damien; Neier,Reinhard
  参考文献:Helvetica Chimica Acta 日期:2011 卷标:94(2) 页码:331-346]
  
  613-54-7 = 93-08-3
  反应条件:1.1 Reagents: Sodium Hydroxide,1H-Imidazolium,1-Butyl-3-Methyl-,(T-4)-Tetracarbonylcobaltate(1-) (1:1) Solvents: Benzene,1H-Imidazolium,1-Butyl-3-Methyl-,(T-4)-Tetracarbonylcobaltate(1-) (1:1)
  标题:1-Butyl-3-Methylimidazolium Cobalt Tetracarbonyl [bmim][co(Co)4]: A Catalytically Active Organometallic Ionic Liquid
  作者:Brown,Richard J. C.; Dyson,Paul J.; Ellis,David J.; Welton,Thomas
  参考文献:Chemical Communications (Cambridge 日期:2001 卷标:(18) 页码:1862-1863]
  
  613-54-7 = 93-08-3
  反应条件:1.1 Reagents: Hantzsch Ester,Diisopropylethylamine Catalysts: 2924304-96-9 Solvents: Tetrahydrofuran; 25 °C
  标题:Enhanced Reducibility Via Altering Exciton Binding Energy Of Conjugated Microporous Polymers For Photocatalytic Reduction
  作者:Zhang,Weijie; Wang,Degao; Xie,Qiujian; Xu,Chen; Kuang,Guichao; Et Al
  参考文献:Macromolecules (Washington 日期:2023 卷标:56(11) 页码:4022-4029]
  
  7228-47-9 = 93-08-3
  反应条件:1.1 Reagents: Trimethylamine Oxide Catalysts: Ruthenium Trichloride Hydrate Solvents: Dimethylformamide; 10 Min,60 °C
  标题:Two Simple And Highly Efficient Variants Of The Griffith-Ley Oxidation Of Alcohols
  作者:Weingart,Pascal; Huetchen,Patrick; Damone,Angelo; Kohns,Maximilian; Hasse,Hans; Et Al
  参考文献:Chemcatchem 日期:2020 卷标:12(15) 页码:3919-3928]
  
  7228-47-9 = 93-08-3
  反应条件:1.1 Reagents: Oxygen Catalysts: Platinum (Clusters With Gold),Gold (Clusters With Platinum,Palladium,Nickel,Or Iridium) Solvents: (Trifluoromethyl)Benzene,Water; 18 H,Rt
  标题:Preparation Of Carbonyl Compounds By Oxidation Of Alcohols Using Styrene Polymer-Supported Binary Gold-Transition Metal Cluster Catalysts
  参考文献:Japan]
  
  7228-47-9 = 93-08-3
  反应条件:1.1 Reagents: Iodobenzene Diacetate Catalysts: (Sp-5-13)-(Acetato-Ko)[[2,2′-[1,2-Cyclohexanediylbis[(Nitrilo-Kn)Methylidyne]]Bi... Solvents: Dichloromethane,1,3-Dimethylimidazolium Methyl Sulfate; 1 H,Rt
  标题:Oxidation Of Sec-Alcohols Catalyzed By Mn(Salen) In Ionic Liquids
  作者:Jing,Se; Zhen,Li; Xia,Chun-Gu
  参考文献:Fenzi Cuihua 日期:2008 卷标:22(6) 页码:561-564]
  
  141994-27-6 = 93-08-3
  反应条件:1.1 Reagents: Water,Oxygen Catalysts: Iodine Solvents: Chloroform; 24 H,1 Atm,Rt
  标题:Visible-Light-Induced Cleavage Of C-S Bonds In Thioacetals And Thioketals With Iodine As A Photocatalyst
  作者:Krumb,Matthias; Kammer,Lisa Marie; Forster,Robert; Grundke,Caroline; Opatz,Till
  参考文献:Chemphotochem 日期:2020 卷标:4(2) 页码:101-104]
  
  155536-85-9 = 93-08-3
  反应条件:1.1 Solvents: Water; 2 H,Rt -> 80 °C
  标题:Mild Water-Promoted Selective Deacetalization Of Acyclic Acetals
  作者:Williams,D. Bradley G.; Cullen,Adam; Fourie,Alex; Henning,Hendrik; Lawton,Michelle; Et Al
  参考文献:Green Chemistry 日期:2010 卷标:12(11) 页码:1919-1921]
  
  141994-27-6 = 93-08-3
  反应条件:1.1 Reagents: Sodium Iodide,Hydrogen Peroxide Catalysts: Tantalum Pentachloride Solvents: Ethyl Acetate,Water; 1 H,Rt
  标题:Deprotection Of Dithioacetals Using The Tantalum(V) Chloride-Catalyzed Oxidation Of Iodide Ion By Hydrogen Peroxide
  作者:Kirihara,Masayuki; Harano,Aiko; Tsukiji,Hiroyuki; Takizawa,Ryu; Uchiyama,Tomoyuki; Et Al
  参考文献:Tetrahedron Letters 日期:2005 卷标:46(37) 页码:6377-6380]
  
  66950-92-3 = 93-08-3 [标题:Reaction Conditions
  标题:Chemistry Of β-Iminosulfoxide. Ketone From β-Iminosulfoxide
  作者:Yokoyama,Masataka; Takeshima,Tatsuo
  参考文献:Tetrahedron Letters 日期:1978 卷标:(2) 页码:147-50]
  
  7228-47-9 = 93-08-3
  反应条件:1.1 Reagents: Sodium Bicarbonate,Sodium Hypochlorite Catalysts: Potassium Bromide,2768466-81-3 (Immobilized On Magnetic Polystyrene Nanosphere) Solvents: Dichloromethane,Water; 5 - 6 Min,0 - 10 °C
  标题:Heterogeneous Catalysis For Oxidation Of Alcohol Via 1-Methyl-2-Azaadamanane N-Oxyl Immobilized On Magnetic Polystyrene Nanosphere
  作者:Guo,Xiaqun; Li,Meichao; Wang,Jianli; Li,Chunmei; Hu,Xinquan; Et Al
  参考文献:Chemistryselect 日期:2022 卷标:7(14)]
  
  7228-47-9 = 93-08-3
  反应条件:1.1 Reagents: 1-Hydroxy-1,2-Benziodoxol-3(1H)-One 1-Oxide Catalysts: Trifluoromethanesulfonic Acid Solvents: 1,4-Dioxane; 8 Min,Rt
  标题:Ibx-Tfoh Mediated Oxidation Of Alcohols To Aldehydes And Ketones Under Mild Reaction Conditions
  作者:Kumar,Kamlesh; Kumar,Prashant; Joshi,Penny; Rawat,Diwan S.
  参考文献:Tetrahedron Letters 日期:2020 卷标:61(15)]
  
  7228-47-9 = 93-08-3
  反应条件:1.1 Reagents: Acetone,Potassium Tert-Butoxide Catalysts: (Oc-6-52)-Dichloro[2-[6-(3,5-Dimethyl-1H-Pyrazol-1-Yl-Kn2)-2-Pyridinyl-Kn]-1H-Be... Solvents: Methanol,Acetone; 5 Min,56 °C
  标题:Ruthenium(Ii)-Nnn Complex-Catalyzed Oppenauer-Type Oxidation Of Secondary Alcohols
  作者:Wang,Qingfu; Du,Wangming; Liu,Tingting; Chai,Huining; Yu,Zhengkun
  参考文献:Tetrahedron Letters 日期:2014 卷标:55(9) 页码:1585-1588]
  
  7228-47-9 = 93-08-3
  反应条件:1.1 Reagents: Acetone Catalysts: Potassium Tert-Butoxide,(Oc-6-42)-Chloro[2-[6-(3,5-Dimethyl-1H-Pyrazol-1-Yl-Kn2)-2-Pyridinyl-Kn]-5-Methy...; 1 Min,56 °C
  标题:A Versatile Ruthenium(Ii)-Nnc Complex Catalyst For Transfer Hydrogenation Of Ketones And Oppenauer-Type Oxidation Of Alcohols
  作者:Du,Wangming; Wang,Liandi; Wu,Ping; Yu,Zhengkun
  参考文献:Chemistry - A European Journal 日期:2012 卷标:18(37) 页码:11550-11554]
  
  120342-65-6 = 93-08-3
  反应条件:1.1 Reagents: Tert-Butyl Hydroperoxide Catalysts: Vanadium Oxide (V2O5) Solvents: Water; 7 H,Reflux
  标题:Efficient Synthesis Of Carbonyl Compounds: Oxidation Of Azides And Alcohols Catalyzed By Vanadium Pentoxide In Water Using Tert-Butylhydroperoxide
  作者:Alagiri,Kaliyamoorthy; Prabhu,Kandikere Ramaiah
  参考文献:Tetrahedron 日期:2011 卷标:67(44) 页码:8544-8551]
  
  7228-47-9 = 93-08-3
  反应条件:1.1 Reagents: Oxygen Catalysts: Pyridine,Palladium Diacetate Solvents: Toluene; 2.5 H,27 Psi,100 °C
  标题:Development Of Safe And Scalable Continuous-Flow Methods For Palladium-Catalyzed Aerobic Oxidation Reactions
  作者:Ye,Xuan; Johnson,Martin D.; Diao,Tianning; Yates,Matthew H.; Stahl,Shannon S.
  参考文献:Green Chemistry 日期:2010 卷标:12(7) 页码:1180-1186]
  
  7228-47-9 = 93-08-3
  反应条件:1.1 Reagents: Acetone,Sodium Tert-Butoxide Catalysts: Stereoisomer Of [1,8-Bis[bis(1-Methylethyl)Phosphino-Kp]-9,10[1′,2′]-Benzenoanth... Solvents: Acetone; 56 °C; 6 H,56 °C
  标题:Cyclometalated Phosphine-Based Ir(Iii) Pincer Complex As A Catalyst For Oppenauer-Type Oxidation Of Alcohols
  作者:Levy,Roy; Azerraf,Clarite; Gelman,Dmitri; Rueck-Braun,Karola; Kapoor,Pramesh N.
  参考文献:Catalysis Communications 日期:2009 卷标:11(4) 页码:298-301]
  
  7228-47-9 = 93-08-3
  反应条件:1.1 Reagents: Cesium Carbonate,Oxygen Catalysts: Gold Solvents: Toluene; 6 H,Rt
  标题:Recyclable Gold Nanoparticle Catalyst For The Aerobic Alcohol Oxidation And C-C Bond Forming Reaction Between Primary Alcohols And Ketones Under Ambient Conditions
  作者:Kim,Sungjin; Bae,Sang Won; Lee,Jae Sung; Park,Jaiwook
  参考文献:Tetrahedron 日期:2009 卷标:65(7) 页码:1461-1466

海关参考信息

• 2902600000-乙苯
  2902902000-精萘
  2912110000-甲醛
  2912120000-乙醛
• 💡 提示：海关信息按照顺序优先匹配，如需确认的海关信息，请参考相关资料。
• 详情请参考：📖 海关编码查询和海关进出口税则

其他信息查阅

• ➥ 象形图和危险代码
• ➥ 防范代码详解
• ➥ 危险代码说明
• ➥ Globally Harmonized System
• ➥ REACH监管