CAS: 14609-54-2; 4,4,4,4-(Porphine-5,10,15,20-Tetrayl)Tetrakis(Benzoic Acid)

该化合物是合成激素化合物,其特征是附于Porphyrin环中间位置的四种碳酸基苯替代物,这种结构在极地溶剂中具有重大的溶解性,使其在各种应用中有用,包括光动疗法和生物系统中的染色; 碳酸组增强了其形成金属离子复合体的能力,可用于催化和感测应用; 化合物在电磁频谱可见区域,特别是在索雷特和Q波段,表现出强烈吸收,这是Porphyrins的典型特征,允许其参与轻度收获过程; 此外,中-Tetra(4-carboxyboxy)poprephine可以进行各种化学修改,从而能够开发材料科学和生物化学学中具体应用的功能化衍生物; 其独特特性使它成为与摄影化学和分子电子有关的研究的主体.

结构式图片

相似化合物

22112-83-0 150805-46-2 14609-51-9

上下游产品

pyrrole 4-Carboxybenzaldehyde 5,10,15,20-tetrakis(4-methoxycarbonylphenyl)porphyrin 5,10,15,20-tetrakis(4-cyanophenyl)porphirin5,10,15,20-tetrakis(4-methoxycarbonylphenyl)porphyrin -21H,23H-phorphine trihydrate10-(4-hexadecyloxycarbonylphenyl)-5,15,20-tris4-carboxyphenyl-21H,23H-phorphine trihydrate phenyl>porphyrin5,10,15,20-tetrakis4-4-(chloromethyl)benzyloxycarbonylphenylporphyrin

合成工艺路线路线简述

    对醛基苯甲酸,吡咯 以 丙酸 用作溶剂,以to Obtain 6.9 G Of 5,10,15,20-Tetra(4-Carboxyphenyl)Porphine的收率获得中-四(4-羧基苯基)卟吩
    参考文献:Optical Recording Material
    标题:Optical Recording Material
    摘要:公开了一种光记录材料,包括至少具有一个离子基团的卟啉衍生物和与该卟啉衍生物相容的聚合物.作为卟啉衍生物,使用具有n-烷基吡啶基团的卟啉衍生物,例如5,10,5,20-四(4-N-甲基吡啶)卟啉,具有季铵基的卟啉衍生物,例如5,10,15,20-四(4-N,N,N-三甲基氨基苯基)卟啉,具有磺酸苯基基团的卟啉衍生物,例如5,10,15,20-四(4-磺酸苯基)卟啉,以及具有碳酸苯基基团的卟啉衍生物,例如5,10,15,20-四(4-碳酸苯基)卟啉.作为聚合物,可以使用有机聚合物或无机聚合物.从记录稳定性的角度来看,有机聚合物如聚乙烯醇或聚苯乙烯磺酸钠是首选的水溶性聚合物.使用以四甲氧基硅烷或四乙氧基硅烷为起始材料合成的二氧化硅玻璃作为无机聚合物.在光记录材料中,可以在比液氦温度更高的温度下形成热稳定孔,因此,升温后形成的孔的衰减很小,记录稳定性很高.此外,可以在液氮温度下进行孔的形成.

    专利信息


    专利号:US-4783529-A
    优先权日:1985-12-03
    标题 :Rapid synthesis of radiolabeled porphyrin complexes for medical application
    发明人:LAVALLEE DAVID K; MANSUY DANIEL; BATTIONI JEAN-PAUL
    权利人:RES CORP TECHNOLOGIES INC
    摘要:This invention relates to a novel method for the rapid synthesis of radiolabeled porphyrin complexes which are highly useful for biomedical application, i.e. conjugation to protein antibodies for use in tumor imaging and internal radiation therapy.

    专利号:US-12209103-B2
    优先权日:2018-06-22
    标题:Nanoreactors for the synthesis of porous crystalline materials
    发明人:PUIGMARTI-LUIS JOSEP; ZAMORA ABANADES FELIX JUAN; FRANCO PUJANTE CARLOS; RODRIGUEZ SAN MIGUEL DAVID; SORRENTI ALESSANDRO
    权利人:UNIV MADRID AUTONOMA
    摘要:The present invention relates to the field porous crystalline materials, more particularly to metal organic frameworks (MOFs) and covalent organic frameworks (COFs). According to this invention, micelles are used as nanoreactors for the synthesis and stabilisation of porous crystalline materials in aqueous dispersions. Disclosed are dispersions comprising such porous crystalline materials, the synthesis and use of such dispersions. Further disclosed are novel porous crystalline materials, the synthesis and use of such crystalline materials. Further disclosed are novel inks comprising the dispersions and non-solvent, the synthesis and use of such inks for direct printing, 2D printing and 3D printing.

    专利号:US-7880026-B2
    优先权日:2006-04-14
    标 题 :MOF synthesis method
    发明人:NI ZHENG; MASEL RICHARD I
    权利人:UNIV ILLINOIS
    摘要:A rapid, simple and versatile metal organic framework molecule (MOF) synthesis method particularly adapted to make non-linear MOFs includes heating MOF precursors, such as a metal or metal oxide and an organic ligand, in a microwave oven for a period sufficient to achieve crystallization. Microwave-assisted MOF synthesis yields high quality MOF crystals in a reaction time ranging from about 5 seconds to about 2.5 minutes, compared to hours and days required in conventional solvothermal and hydrothermal methods. In addition, microwave assisted methods provide MOF materials with uniform crystal size and well-defined shape. Further, microwave synthesis of MOFs allows the size and shape of MOF crystals to be tailored for use in a wide range applications by manipulating reaction conditions. Secondary growth processes may also be employed to grow larger crystals using seeds obtained from microwave-assisted synthesis methods.

    专利号:US-9951095-B2
    优先权日:2014-05-16
    标 题:Chromium metal organic frameworks and synthesis of metal organic frameworks
    发明人:ZHOU HONG-CAI; Liu tian-fu; LIAN XIZHEN; ZOU LANFANG; FENG DAWEI
    权利人:TEXAS A & M UNIV SYS
    摘要:The present invention relates to monocrystalline metal organic frameworks comprising chromium ions and carboxylate ligands and the use of the same, for example their use for storing a gas. The invention also relates to methods for preparing metal organic frameworks comprising chromium, titanium or iron ions and carboxylate ligands. The methods of the invention allow such metal organic frameworks to be prepared in monocrystalline or polycrystalline forms.

    专利号:US-8871926-B1
    优先权日:2010-09-28
    标题:Synthesis of porphyrin nanostructures
    发明人:FAN HONGYOU; BAI FENG
    权利人:FAN HONGYOU; BAI FENG; SANDIA CORP
    摘要:The present disclosure generally relates to self-assembly methods for generating porphyrin nanostructures. For example, in one embodiment a method is provided that includes preparing a porphyrin solution and a surfactant solution. The porphyrin solution is then mixed with the surfactant solution at a concentration sufficient for confinement of the porphyrin molecules by the surfactant molecules. In some embodiments, the concentration of the surfactant is at or above its critical micelle concentration (CMC), which allows the surfactant to template the growth of the nanostructure over time. The size and morphology of the nanostructures may be affected by the type of porphyrin molecules used, the type of surfactant used, the concentration of the porphyrin and surfactant the pH of the mixture of the solutions, and the order of adding the reagents to the mixture, to name a few variables.

    专利号:EP-4345058-A1
    优先权日:2022-08-16
    标 题:Method for recycling organophosphates
    发明人:WEIGAND JAN; SCHWEDTMANN KAI; SCHNEIDER TOBIAS; SCHULZ STEPHEN
    权利人:UNIV DRESDEN TECH
    摘要:The present invention relates to a process for the synthesis of nitrogen-containing phosphorus(V) precursors of the formula (I), wherein a phosphoric acid ester is reacted with an oxygen acceptor based on a sulfonic acid anhydride in the presence of a Lewis base LN which is capable of coordination via a nitrogen atom, wherein the Lewis base LN is a nitrogen-containing heteroaromatic compound which contains a six-membered heteroaromatic ring.The present invention also relates to a process for the synthesis of oxyphosphorus compounds, wherein the process is carried out for the synthesis of nitrogen-containing phosphorus(V) precursors of the formula (I) and the nitrogen-containing phosphorus(V) precursor of the formula (I) is reacted with a nucleophile.
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    主要参考文献

    1.) Rajasree, S.S., Li, X., Deria, P.; Physical Properties of Porphyrin-based crystalline metal-organic frameworks. Communications Chemistry 4, 47, 2021. https://doi.org/10.1038/s42004-021-00484-4 2.) Chen, J., Zhu, Y., Kaskel, S.; Porphyrin-Based Metal_Organic Frameworks for Biomedical Applications. Angew. Chemie. Int. Ed. 2021, 60, 5010-5035. https://doi.org/10.1002/anie.201909880 3.) Moradi, E., Rahimi, R., Farahani, Y.D., Safarifard, V.; Porphyrinic zirconium-based MOF with exposed pyrrole Lewis base site as a luminescent sensor for highly selective sensing of Cd2+ and Br- ions and THF small molecule. Journal of Solid State Chemistry 2020, 282, 121103. https://doi.org/10.1016/j.jssc.2019.121103 4.) Jia, Y., Li, F., Jia, T., Wang, Z.; Meso-tetra(4-carboxyphenyl)porphine-Enhanced DMA Methylation Sensing Interface on a Light-Addressable Potentiometric Sensor. ACS Omega 2019, 4, 7, 12567-12574. https://doi.org/10.1021/acsomega.9b00980 5.) Elzi, D.J., Bauta, W.E., Sanchez, J.R., Das, T., Mogare, S., Fatland, P.Z., Iza, M., Pertsemlidis, A., Rebel, V.T.; Identification of a novel mechanism for meso-tetra(4-carboxyphenyl) porphyrin (TCPP) uptake in cancer cells. The FASEB Journal. 2021;35:e21427. https://doi.org/10.1096/fj.202000197R 6.) Sanchez-Munoz, E., Garate-Morales, J.L, Sandoval-Lira, J., Hernandez-Perez, J.M., Aguilar-Sanchez, R.; Porphyrin Supramolecular Arrays Fromed by Weakly Intereacting Meso-Functional Groups on Au(111). Molecules 2019, 24(18), 3326; https://doi.org/10.3390/molecules24183326 7.) Cherian, S., Wamser, C.C.; Adsorption and Photoactivity of Tetra(4-carboxyphenyl)porphyrin (TCPP) on Nanoparticulate TiO2. J. Phys. Chem. B 2000, 104, 15, 3624–3629. https://doi.org/10.1021/jp994459v

    合成参考文献


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    参考文献:10.1007/s00216-021-03482-6
    摘要:Zhang X, Lin B, Shu Y, Wang J. “Switch-on” fluorescence sensing platform based on porphyrin metal-organic frameworks for rapid and specific detection of zinc ion. Analytical and Bioanalytical Chemistry. 2021 Jul 29;413(20):5161–8. doi: 10.1007/s00216-021-03482-6.
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