CAS: 349-58-6; 3,5-Bis(Trifluoromethyl)Phenol

上下游产品

CAS号328-70-1 1,3-双(三氟甲基)-5-溴苯 | CAS号30071-93-3 3,5-双(三氟甲基)苯乙酮 | CAS号4210-04-2 3,5-bis(trifluo... | CAS号112981-69-8 3,5-双(三氟甲基)苯基溴化镁 | CAS号667458-78-8 benzyl 3,5-bis(... | CAS号618-83-7 5-羟基间苯二甲酸 | CAS号685892-24-4 3,5-bis(trifluo... | CAS号130783-02-7 3,5－双(三氟甲基)苯硫酚 | CAS号402-31-3 间二三氟甲苯 | CAS号328-74-5 3,5-二(三氟甲基)苯胺 | CAS号349-60-0 3,5-双三氟甲基苯甲醚 | CAS号180134-15-0 2-甲氧基-4,6-二(三氟甲基)苯甲酸

间二三氟甲苯置于正丁基锂,Air,1,3-二溴-5,5-二甲基海因,硫酸体系中,用 乙醚 用作溶剂,化学反应 24.75H,反应生成3,5-二三氟甲基苯酚
参考文献:1-Bromo-3,5-双(三氟甲基)苯:一种多用途的有机金属合成原料
标题:1-Bromo-3,5-双(三氟甲基)苯:一种多用途的有机金属合成原料
摘要:可以通过在强酸性介质中用n,N'-二溴-5,5-二甲基乙内酰脲处理1,3-双(氟甲基)苯来选择性地制备1-Bromo-3,5-双(三氟甲基)苯(1).通过3,5-双(三氟甲基)苯基镁,-锂和-铜中间体完成了许多合成上有用的反应.
Doi:10.1002/cber.19961290219

专利信息

专利号:US-2004110228-A1
优先权日:2002-04-01
标 题:Combinatorial organic synthesis of unique biologically active compounds
发明人：MCALPINE SHELLI R; TAYLOR RACHEL E; BOLLA MEGAN L; SEGALL ANCA M
摘要:The invention provides a method for making a combinatorial library of cyclic compounds, such as Holliday junction-trapping compounds, comprising the steps of (a) obtaining a plurality of trimers according to the generic structure X 1- X 2- X 3 , wherein X 1 , X 2 and X 3 can be independently any naturally or nonnaturally occurring amino acids or peptidomimetics thereof; (b) optionally coupling a spacer S to the trimer at either end; (c) cyclizing two trimers or trimer-spacer conjugates in a head-to-tail orientation; thereby obtaining a combinatorial library of compounds, wherein the library does not include an unmodifed or naturally occurring Holliday Junction-trapping compounds. The invention additionally provides methods macrocyclic compounds that are synergimycin derivatives.

专利号:US-6828466-B2
优先权日:2002-07-19
标题:Process for the synthesis of phenols from arenes
发明人：MALECZKA JR ROBERT E; SMITH III MILTON R; HOLMES DANIEL; SHI FENG
权利人:UNIV MICHIGAN STATE
摘要:A process to synthesize substituted phenols such as those of the general formula RR'R''Ar(OH) wherein R, R', and R'' are each independently hydrogen or any group which does not interfere in the process for synthesizing the substituted phenol including, but not limited to, halo, alkyl, alkoxy, carboxylic ester, amine, amide; and Ar is any variety of aryl or hetroaryl by means of oxidation of substituted arylboronic esters is described. In particular, a metal-catalyzed C-H activation/borylation reaction is described, which when followed by direct oxidation in a single or separate reaction vessel affords phenols without the need for any intermediate manipulations. More particularly, a process wherein Ir-catalyzed borylation of arenes using pinacolborane (HBPin) followed by oxidation of the intermediate arylboronic ester by OXONE is described.

专利号:US-11932789-B2
优先权日:2019-11-11
标题 :Luminescent compound
发明人：DOBEREINER GRAHAM; SABBERS WILLIAM; WEERASIRI WEERASIRI ARACHCHIGE KUSHAN CHANDANA
权利人:Temple University—Of the Commonwealth System of Higher Education; UNIV TEMPLE
摘要:Provided herein are luminescent compounds, compositions including the same, and use and synthesis thereof.

专利号:US-2004030197-A1
优先权日:2002-07-19
标 题 :Process for the synthesis of phenols from arenes

专利号:CN-113461926-B
优先权日:2021-07-30
标题:Chemical synthesis method of poly beta-hydroxy fatty acid ester