CAS: 422556-08-9; Pyroxsulam

该化合物是一种该化合物是一种乙醇综合酶抑制剂,干扰易感染植物的分链氨基酸合成. Pyroxsulam 显示目标杂草具有很高的选择性,同时在按建议的比例施用时保持作物安全.它的系统活动确保了植物内部的有效迁移,对抗药性杂草群提供了有力的控制.注意到化合物的使用率低,环境状况良好,与综合杂草管理系统兼容性.

结构式图片

欧盟法规

ECHA物质ECHA物质欧盟农药活性物质C&L通报REACH预注册

上下游产品

CAS号13223-43-3 2-氨基-5,7-二甲氧基-1... | CAS号219715-41-0 2-methoxy-4-(tr...

合成工艺路线路线简述

    以 甲苯,乙腈 作为反应溶剂,以83%的收率获得产物甲氧磺草胺
    参考文献:Application Of The Tisler Triazolopyrimidine Cyclization To The Synthesis Of A Crop Protection Agent And An Intermediate
    标题:Application Of The Tisler Triazolopyrimidine Cyclization To The Synthesis Of A Crop Protection Agent And An Intermediate
    摘要:A New Synthetic Route To The Dow Agrosciences Early Stage Sulfonamide Herbicide 3-(2-Methoxy-4-Trifluoromethyl)-N-(5,7-Dimethoxy[1,2,4]Triazolo[1,5-A]Pyrimidin-2-yl)Pyridinesulfonamide (Pyroxsulam) Has Been Developed. The Synthesis Is Based On Formation Of The Triazole Ring As The Final Step,Utilizing The Tisler Triazolopyrimidine Cyclization. A Tisler Cyclization Route To 2-Amino-5,7-Dimethoxy-1,2,4-Trazolo[1,5-A]Pyrimidine Starting With 2-Chloro-4,6-Dimethoxypyrimidine Has Also Been Demonstrated.
    DOI:10.1021/op0601518

    海关参考信息

    专利信息


    专利号:WO-2024256370-A1
    优先权日:2023-06-13
    标 题 :Synthesis of glufosinate using an amidase-based process
    发明人:ZIMMERMANN GUNTHER; POTT MORITZ STEFAN
    权利人:BASF SE
    摘要:The present invention relates to a method of preparing glufosinate, comprising the steps of hydrolysing an N-carbamoyl glufosinate amide with an Amidase enzyme to form an N- carbamoyl amino acid compound followed by cleaving off the carbamoyl moiety of said N- carbamoyl amino acid compound.

    专利号:US-2025120400-A1
    优先权日:2021-12-10
    标题:Synthesis of glufosinate using a hydantoinase-based process
    发明人:DITRICH KLAUS; BREUER MICHAEL; POTT MORITZ STEFAN; ZIMMERMANN GUNTHER; SEEMAYER STEFAN
    权利人:BASF SE
    摘要:The present invention relates to a method of manufacturing glufosinate, comprising the steps of hydrolysing a hydantoin with a Hydantoinase enzyme to form a N-carbamoyl amino acid compound followed by cleaving off the carbamoyl moiety of said N-carbamoyl amino acid compound.

    专利号:WO-2021130756-A1
    优先权日:2019-12-25
    标题:Combinations of non-protein amino acids and acetolactate synthase enzyme inhibitors
    发明人:KLIPCAN LIRON; VAN-OSS PINHASI RUTH
    权利人:THE STATE OF ISRAEL MINISTRY OF AGRICULTURE & RURAL DEVELOPMENT AGRICULTURAL RES ORGANIZATION ARO VO
    摘要:The present invention provides compositions and methods for disrupting protein synthesis in plant cells.

    专利号:US-11919928-B2
    优先权日:2016-03-16
    标题 :Method for producing dihydrotentoxin
    发明人:KUBO TAKASHI; MACHIDA MASAYUKI; FUJIOKA TOMONORI; YAMAGUCHI Shigenari; KAWAI KIYOSHI
    权利人:KUMIAI CHEMICAL INDUSTRY CO
    摘要:An object of the present invention is to identify an enzyme having activity of synthesizing dihydrotentoxin that is a tentoxin precursor and an enzyme having activity of synthesizing tentoxin using dihydrotentoxin as a substrate. The present invention concerns a tentoxin synthesis-related gene encoding a protein comprising the amino acid sequence of SEQ ID NO: 16 and having activity of nonribosomal peptide synthesis of dihydrotentoxin and a tentoxin synthesis-related gene encoding a protein comprising the amino acid sequence of SEQ ID NO: 18 and having activity of converting dihydrotentoxin to tentoxin.

    专利号:US-2021386068-A1
    优先权日:2018-11-07
    标题 :Compositions comprising pyridine carboxylate herbicides and very long chain fatty acid (vlcfa) synthesis inhibitor herbicides
    发明人:KISTER JEREMY; SATCHIVI NORBERT M
    权利人:CORTEVA AGRISCIENCE LLC
    摘要:Disclosed herein are compositions comprising (a) a pyridine carboxylate herbicide or an agriculturally acceptable N-oxide, salt, or ester thereof and (b) a VLCFA synthesis inhibitor herbicide. Also disclosed herein are methods of controlling undesirable vegetation, comprising applying to vegetation or an area adjacent the vegetation or applying in soil or water to control the emergence or growth of vegetation (a) a pyridine carboxylate herbicide or an agriculturally acceptable N-oxide, salt, or ester thereof, and (b) a VLCFA synthesis inhibitor herbicide.

    专利号:US-2021352899-A1
    优先权日:2018-11-07
    标题 :Compositions comprising pyridine carboxylate herbicides and fatty acid and lipid synthesis inhibitor herbicides
    发明人:KISTER JEREMY; SATCHIVI NORBERT M
    权利人:CORTEVA AGRISCIENCE LLC
    摘要:Disclosed herein are compositions comprising (a) a pyridine carboxylate herbicide or an agriculturally acceptable N-oxide, salt, or ester thereof and (b) a fatty acid and lipid synthesis inhibitor (FA/LSI) herbicide, an agriculturally acceptable salt or ester thereof, or mixtures thereof. Also disclosed herein are methods of controlling undesirable vegetation, comprising applying to vegetation or an area adjacent the vegetation or applying in soil or water to control the emergence or growth of vegetation (a) a pyridine carboxylate herbicide or an agriculturally acceptable N-oxide, salt, or ester thereof and (b) a fatty acid and lipid synthesis inhibitor (FA/LSI) herbicide, an agriculturally acceptable salt or ester thereof, or mixtures thereof.
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    合成参考文献


    摘要:S60 | SWISSPEST19 | Swiss Pesticides and Metabolites from Kiefer et al 2019 | DOI:10.5281/zenodo.3544759
    摘要:S69 | LUXPEST | Pesticide Screening List for Luxembourg | DOI:10.5281/zenodo.3862688
    摘要:S78 | SLUPESTTPS | Pesticides and TPs from SLU, Sweden | DOI:10.5281/zenodo.4687924
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