专利号:US-2021107859-A1 优先权日:2018-04-06 标题 :A process for the synthesis of carbon labeled organic compounds 发明人:AUDISIO DAVIDE; CANTAT THIBAULT; DESTRO GIANLUCA 权利人:COMMISSARIAT ENERGIE ATOMIQUE 摘要:A process for the synthesis of a carbon labeled organic compound containing a carbon labeled carboxyl group is described. A method of using carbon labeled organic compounds containing a carbon labeled carboxyl group according to the present disclosure; a process for manufacturing labeled pharmaceuticals and agrochemicals comprising synthesis of carbon labeled organic compounds containing a carbon labeled carboxyl group according to the present disclosure; and a process for producing tracers comprising synthesis of carbon labeled organic compounds containing a carbon labeled carboxyl group according to the present disclosure are also described.
专利号:US-10633315-B2 优先权日:2016-10-19 标 题:Synthesis of bicyclo[2.2.2]octanes 发明人:HU YUE RACHEL; HEMBRE ROBERT THOMAS; TUSTIN GERALD CHARLES; BURK CHRISTOPHER HARLAN 权利人:EASTMAN CHEM CO 摘要:Provided is a process for the preparation of certain 1,4-bicyclo[2.2.2]octane derivatives. The new synthetic procedure involves treating 1,4-dimethylene cyclohexane with an oxidizing agent in the presence of a transition metal catalyst comprising a palladium compound to afford certain oxo-substituted bicyclo[2.2.2]octane species. The process of the invention thus affords a novel and simplified means for the commercial production of a wide variety of bicyclo[2.2.2]octane derivatives.
专利号:WO-2024040556-A1 优先权日:2022-08-26 标题 :Organic hole injection material and use thereof 发明人:MENG HONG; LU KE; YAN ZHAOYI; HU ZHAO; HE YAOWU; MENG ZHIMIN; LI TINGTING; CAI YU 权利人:UNIV PEKING SHENZHEN GRADUATE SCHOOL 摘要:The present invention relates to an organic hole injection material with a general chemical formula as represented by (I). The hole injection material of the present invention structurally contains two units, i.e., an azafluorene alkene derivative and an electron-deficient group, as well as other aromatic groups, etc., and mainly has the following advantages: the synthesis of the material is relatively simple, which is beneficial for large-scale production and synthesis; the melting point and boiling point of the material are moderate or the material is well dissolved in solvents commonly used in the preparation of devices, such that the preparation of devices by using the material is relatively easy and a high-performance device can be obtained; and since the material contains a plurality of electron-deficient groups, the HOMO-LUMO energy level structure of the material is appropriate, which is more conducive to the injection of holes from an anode into an adjacent organic layer, i.e., a hole transport layer, such that the performance of a device is improved.
专利号:EP-3529230-B1 优先权日:2016-10-19 标 题 :Synthesis of bicyclo(2.2.2)octanes
专利号:US-8912342-B2 优先权日:2012-02-06 标题:Pyrazole synthesis by coupling of carboxylic acid derivatives and enamines 发明人:GLORIUS FRANK; SURI MAMTA 权利人:UNIV MUENSTER WILHELMS; Westfälische Wilhelms Universität Münster 摘要:A method of synthesizing Pyrazoles by means of the oxidative conversion of Enamines with suitable N-containing carboxylic acid derivatives in the presence of copper ions and 2-picolinic acid derivatives is provided.
专利号:WO-2024044937-A1 优先权日:2022-08-30 标题:Organic hole injection material and use thereof 发明人:MENG HONG; LU KE; CAI YU; YAN ZHAOYI; HU ZHAO; HE YAOWU; MENG ZHIMIN; LI TINGTING 权利人:UNIV PEKING SHENZHEN GRADUATE SCHOOL 摘要:The present invention relates to an organic hole injection material, which has a general chemical formula as below: The structure of the hole injection material of the present invention comprises two units of an azafluorene alkene derivative and a cyclic electron-deficient group, etc. Compared with a previous hole injection material, the material has the following advantages: the synthesis of the material is relatively simple, which is beneficial for large-scale production; the HOMO-LUMO energy level structure of the material is appropriate, which is conducive to the injection of carriers; an azafluorene alkene derivative and an electron-deficient group are used as a core of the material, which facilitates the transport of the carriers in an organic layer; and the material has a high LUMO/HOMO energy level, thereby facilitating the transport of holes from anode ITO to a hole transport layer.
[参考文献]: Youxiang Wang, Et Al. Preparation, Purification, And Characterization Of Binuclear Ruthenium(Ii) Complexes: Bridging Ligands Based On Diazafluorenes. Inorg Chem. 1998 May 4;37(9):2227-2234.
合成参考文献
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