CAS: 101-86-0; 2-Hexyl-3-Phenylacrylaldehyde

相似化合物

122-40-7 101-85-9 101-39-3

上下游产品

°Ctanal benzaldehyde (1,5-Dimethyl-hexyl)-[2-[1-phenyl-meth-(E)-ylidene]-°Ct-(E)-ylidene]-amine 1-Phenyl-2-hexyl-1,5-hexadien-3-ol (+/-)-2-benzyl-1-°Ctanol α-hexylcinnamyl alcohol

2-Benzylideneoctan-1-Ol置于manganese(Iv) Oxide体系中,用 二氯甲烷 用作溶剂,化学反应生成α-己基肉桂醛
参考文献:使用钯/铜/锂三元系统对偕二氟亚甲基进行去对称化,用于立体发散​​合成氟化氨基酸
标题:使用钯/铜/锂三元系统对偕二氟亚甲基进行去对称化,用于立体发散​​合成氟化氨基酸
摘要:开发了使用钯/铜/锂三元系统的偕二氟亚甲基的去对称化,用于手性氟化氨基酸的立体发散合成.该三元系统以立体发散的方式以非常好的收率提供了烯丙基和苄基取代的氟化 α-氨基酸,并具有优异的立体选择性(高达 >99 % Ee 和 >20 : 1 Dr)
Doi:10.1002/anie.202313838

专利信息

专利号:WO-2015120485-A1
优先权日:2014-02-10
标 题:Water, bubble collapse and syngas species in the synthesis of graphene and its derivatives
发明人：SHANKMAN RICHARD S
权利人:PEERLESS WORLDWIDE LLC
摘要:Hydrodynamic cavitation-inducing inertial, non-inertial, and combination reactors are employed in the hydrothermal synthesis of graphene and its derivatives, both in solution and vapor. Various hydrodynamic cavitation reactor embodiments are revealed. Water is used to both nucleate and 'self-heal' graphene sheet growth in solution and vapor. Various methods of combustion, hydrothermal and dehydration synthesis of graphene and its derivatives are revealed. Additionally, water and ice are used as a substrate, both alone and in combination with other substrates, to grow and recover useful graphene and its derivatives.

专利号:US-5786321-A
优先权日:1996-07-09
标题:Preparation of cis-isoambrettolidies and their use as a fragrance
发明人：MANE MAURICE; PONGE JEAN-LOUIS
权利人:MANE V FILS SA
摘要:A method for the production of omega -haloalkyl esters which are useful as intermediates in the synthesis of cis-oxacycloheptadec-11-en-2-one (Product I) and cis-oxacycloheptadec-12-en-2-one (Product II). Also disclosed is a process for the synthesis of Products I-II and a method for using Products I-II to impart an ambery or musky smell to a fragrance composition. Finally, fragrance compositions including Products I-II are disclosed as well as end products such as perfume extracts, toilet waters, cosmetic preparations, soaps, detergents and functional products, each of which also contains at least one of Products I-II.

专利号:US-8754259-B2
优先权日:2008-08-15
标 题 :Synthesis of cyclohexane derivatives useful as sensates in consumer products
发明人：YELM KENNETH EDWARD; BUNKE GREGORY MARK; HAUGHT JOHN CHRISTIAN
权利人:PROCTER & GAMBLE; PROCTER & GAMBLE
摘要:The present invention provides synthetic routes for preparing various isomers of cyclohexane-based coolants, such as menthyl esters and menthanecarboxamide derivatives, in particular those substituted at the amide nitrogen, for example with an aromatic ring or aryl moiety. Such structures have high cooling potency and long lasting sensory effect, which make them useful in a wide variety of consumer products. One synthetic route involves a copper catalyzed coupling of a primary menthanecarboxamide with an aryl halide, such reaction working best in the presence of potassium phosphate and water. Using this synthetic route, specific isomers can be prepared including the menthanecarboxamide isomer having the same configuration as l-menthol and new isomers such as a neoisomer having opposite stereochemistry at the carboxamide (C-1) position. The neoisomer unexpectedly has potent and long lasting cooling effect. Preparation schemes for neoisomers of other menthyl derivatives which are useful as coolants, including esters, ethers, carboxy esters and other N-substituted carboxamides are also provided.

专利号:US-8440608-B2
优先权日:2004-08-06
标题:Beta-substituted tetrandropyrana (on) s and method for the synthesis and the use thereof
发明人：MANE JEAN; CHANOT JEAN-JACQUES; SCHROEDER MARTIN
权利人:MANE JEAN; CHANOT JEAN-JACQUES; SCHROEDER MARTIN; MANE FILS V
摘要:The invention relates, in particular to a tetrahydropyran(on) compound which is substituted in position beta with respect to a cycle oxygen of formula (I), wherein a substituent R is a linear alkyl radical in C2:C10 including, (CH 3 ) 2 CH— or C 6 H 5 —(CH 2 ) m —, with m=0 or 1, or formula (II), wherein A is —CH 2 — or —CO—, in the form of an odorant and to a method for the synthesis thereof by reducing oxo-ester. The use of the inventive compound in composition such as perfumery compositions in the ordinary sense of the term i.e. topic, in particular cosmetic compositions and care products.

专利号:RU-2035448-C1
优先权日:1992-04-20
标题:2-acetonyl-5,5-dimethyl-1,2,3,4,5,6,7,8-octahydronaphthalene as a component of perfumery composition, method of its synthesis, 2,6-dimethyl-2,6,10-tridecatriene-12-one as an intermediate product in synthesis of 2-acetonyl-5,5-dimethyl-1,2,3,4,5,6,7,8-octahydronaphthalene

专利号:US-7501536-B2
优先权日:2005-01-19
标题 :Odorant compounds, synthesis method, and uses of said compounds
发明人：JAUNKY PIOTR; MANE JEAN; SCHROEDER MARTIN
权利人:MANE FILS V
摘要:A compound of general formula (I) with or without the double bond illustrated by the dotted line. In formula (I), X is a CHO, CH2OH, CH2OC(O)R or CH(OR)2 group, and R represents a linear or branched C1-C5 alkyl or alkenyl chain. The synthesis method for the compound, and especially the 6,8-dimethyl-non-7-enal (1) prepared by the hydroformylation of the 5,7-dimethyl-octa-1,6-diene is also disclosed, as well as compositions containing the compounds of formula (I). Due to the odorant properties thereof, the compounds are highly useful in perfumery, especially for cosmetic products and household products.