CAS: 23184-66-9; Butachlor

该化合物是一种选择性除草剂,主要用于控制各种作物,特别是大米中的年草和某些大叶杂草,属于氯乙酰胺类除草剂和功能,禁止植物中合成脂肪酸,从而有效干扰植物生长;甲草胺通常在出现前应用,即指在目标杂草和土壤中产生作物之前使用;该物质的特点是水溶性相对较低,导致其在土壤中的持久性,允许长期控制杂草;该物质对水生生物具有中度毒性,需要谨慎管理,以尽量减少环境影响;甲草胺还受到监管审查,由于潜在的健康和环境问题,在某些地区可能会限制或监测其使用;适当的处理和应用做法对于减轻使用该物质的风险至关重要.

结构式图片

欧盟法规

ECHA物质C&L通报REACH预注册

上下游产品

2-chloro-2',6'-diethylacetanilide 1-(chloromethoxy)butane di-n-butyloxymethane Alachlor2,6-diethylaniline

合成工艺路线路线简述

    2-氯-2,6-二乙基乙酰苯胺,氯甲基丁基醚置于peg-400 Sodium Hydroxide体系中,用 苯 用作溶剂,化学反应 2.0H,反应生成丁草胺
    参考文献:Preparation Of Alkoxymethyl And Alkoxyethoxymethyl Derivatives Of Acylanilines Using Polyethylene Glycols As Phase Transfer Catalysts
    标题:Preparation Of Alkoxymethyl And Alkoxyethoxymethyl Derivatives Of Acylanilines Using Polyethylene Glycols As Phase Transfer Catalysts
    摘要:
    Doi:10.1055/s-1982-30008

    海关参考信息

    专利信息


    专利号:WO-2024256370-A1
    优先权日:2023-06-13
    标 题 :Synthesis of glufosinate using an amidase-based process
    发明人:ZIMMERMANN GUNTHER; POTT MORITZ STEFAN
    权利人:BASF SE
    摘要:The present invention relates to a method of preparing glufosinate, comprising the steps of hydrolysing an N-carbamoyl glufosinate amide with an Amidase enzyme to form an N- carbamoyl amino acid compound followed by cleaving off the carbamoyl moiety of said N- carbamoyl amino acid compound.

    专利号:US-2025120400-A1
    优先权日:2021-12-10
    标题:Synthesis of glufosinate using a hydantoinase-based process
    发明人:DITRICH KLAUS; BREUER MICHAEL; POTT MORITZ STEFAN; ZIMMERMANN GUNTHER; SEEMAYER STEFAN
    权利人:BASF SE
    摘要:The present invention relates to a method of manufacturing glufosinate, comprising the steps of hydrolysing a hydantoin with a Hydantoinase enzyme to form a N-carbamoyl amino acid compound followed by cleaving off the carbamoyl moiety of said N-carbamoyl amino acid compound.

    专利号:US-4224050-A
    优先权日:1977-02-10
    标 题 :Chloroacetanilides having a selective herbicidal activity, ortho-alkenyl-substituted anilines, intermediates in the synthesis of said herbicidal chloroacetanilides, and methods for their preparation
    发明人:COLLE ROBERTO; GOZZO FRANCO; CAMAGGI GIOVANNI; SIDDI GIORGIO
    权利人:MONTEDISON SPA
    摘要:Chloroacetanilides are disclosed having the general formula: wherein R1=H, or alkyl with 1-5 carbon atoms, or X; X=alkenyl, and preferably in which the various R2, which may be equal to or different from each other, are H or an alkyl with 1-3 carbon atoms; A=alkylene, optionally substituted, of the formula: in which the various R2, which may be equal to or different from each other, have the meanings specified above; and Y=H; alkyl with 1-5 carbon atoms; alkenyl with 2-5 carbon atoms; alkinyl with 2-5 carbon atoms; phenyl; cycloalkyl with 3-8 carbon atoms; halogen; +TR wherein R=H; alkyl with 1-5 carbon atoms; alkenyl or alkinyl with 2-5 carbon atoms; cycloalkyl with 3-8 carbon atoms; phenyl; The chloroacetanilide derivatives are useful in combatting infestations of infesting monocotyledons and dicotyledons during pre-emergence, by spreading the chloroacetanilide derivative on the soil adjacent thereto in quantities ranging from 0.25 kg/ha upwards.

    专利号:US-11919928-B2
    优先权日:2016-03-16
    标题 :Method for producing dihydrotentoxin
    发明人:KUBO TAKASHI; MACHIDA MASAYUKI; FUJIOKA TOMONORI; YAMAGUCHI Shigenari; KAWAI KIYOSHI
    权利人:KUMIAI CHEMICAL INDUSTRY CO
    摘要:An object of the present invention is to identify an enzyme having activity of synthesizing dihydrotentoxin that is a tentoxin precursor and an enzyme having activity of synthesizing tentoxin using dihydrotentoxin as a substrate. The present invention concerns a tentoxin synthesis-related gene encoding a protein comprising the amino acid sequence of SEQ ID NO: 16 and having activity of nonribosomal peptide synthesis of dihydrotentoxin and a tentoxin synthesis-related gene encoding a protein comprising the amino acid sequence of SEQ ID NO: 18 and having activity of converting dihydrotentoxin to tentoxin.

    专利号:US-2021386068-A1
    优先权日:2018-11-07
    标题 :Compositions comprising pyridine carboxylate herbicides and very long chain fatty acid (vlcfa) synthesis inhibitor herbicides
    发明人:KISTER JEREMY; SATCHIVI NORBERT M
    权利人:CORTEVA AGRISCIENCE LLC
    摘要:Disclosed herein are compositions comprising (a) a pyridine carboxylate herbicide or an agriculturally acceptable N-oxide, salt, or ester thereof and (b) a VLCFA synthesis inhibitor herbicide. Also disclosed herein are methods of controlling undesirable vegetation, comprising applying to vegetation or an area adjacent the vegetation or applying in soil or water to control the emergence or growth of vegetation (a) a pyridine carboxylate herbicide or an agriculturally acceptable N-oxide, salt, or ester thereof, and (b) a VLCFA synthesis inhibitor herbicide.

    专利号:US-2021352899-A1
    优先权日:2018-11-07
    标题 :Compositions comprising pyridine carboxylate herbicides and fatty acid and lipid synthesis inhibitor herbicides
    发明人:KISTER JEREMY; SATCHIVI NORBERT M
    权利人:CORTEVA AGRISCIENCE LLC
    摘要:Disclosed herein are compositions comprising (a) a pyridine carboxylate herbicide or an agriculturally acceptable N-oxide, salt, or ester thereof and (b) a fatty acid and lipid synthesis inhibitor (FA/LSI) herbicide, an agriculturally acceptable salt or ester thereof, or mixtures thereof. Also disclosed herein are methods of controlling undesirable vegetation, comprising applying to vegetation or an area adjacent the vegetation or applying in soil or water to control the emergence or growth of vegetation (a) a pyridine carboxylate herbicide or an agriculturally acceptable N-oxide, salt, or ester thereof and (b) a fatty acid and lipid synthesis inhibitor (FA/LSI) herbicide, an agriculturally acceptable salt or ester thereof, or mixtures thereof.
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    ✅ COA系统入驻 | 共享模式

    主要参考文献


    1: Mukherjee I, Das SK, Kumar A. Atmospheric CO(2) Level and Temperature Affect Degradation of Pretilachlor and Butachlor in Indian Soil. Bull Environ Contam Toxicol. 2018 Apr 18. doi: 10.1007/s00128-018-2340-6. [Epub ahead of print] doi: 10.1007/s13205-018-1165-7. Epub 2018 Mar 7.
    3: Mei W, Li Q, Fang H, Geng H, Chen X. [Determination of six amide herbicide residues in soil by QuEChERS-gas chromatography-mass spectrometry]. Se Pu. 2017 Dec 8;35(12):1317-1321. doi: 10.3724/SP.J.1123.2017.09003. Chinese. doi: 10.1016/j.foodchem.2017.11.029. Epub 2017 Nov 10. doi: 10.1007/s00128-017-2245-9. Epub 2017 Dec 13. doi: 10.1007/s10646-017-1854-8. Epub 2017 Sep 21. doi: 10.1016/j.bios.2017.05.028. Epub 2017 May 12. doi: 10.1007/s00128-017-2105-7. Epub 2017 May 15. doi: 10.1007/s00128-017-2070-1. Epub 2017 Mar 31. doi: 10.1007/s10565-017-9388-7. Epub 2017 Mar 14. doi: 10.1007/s10142-017-0547-y. Epub 2017 Feb 11. doi: 10.1002/jssc.201601092. Epub 2017 Feb 7. doi: 10.1016/j.chemosphere.2016.12.021. Epub 2016 Dec 5. doi: 10.1016/j.chemosphere.2016.12.025. Epub 2016 Dec 7. doi: 10.1007/s11356-016-8205-9. Epub 2016 Dec 10. doi: 10.1016/j.envres.2016.08.006. Epub 2016 Aug 12. doi: 10.1016/j.watres.2016.08.042. Epub 2016 Aug 22. doi: 10.1002/jssc.201600735. Epub 2016 Sep 16. doi: 10.1016/j.etp.2016.07.004. Epub 2016 Jul 29. doi: 10.1016/j.jphotobiol.2016.07.005. Epub 2016 Jul 9.

    合成参考文献


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    摘要:Nippon Noyaku Gakkaishi. Journal of the Pesticide Science Society of Japan., 25(75), 2000
    摘要:Pesticide Manual., 9(106), 1991
    摘要:SRI Consulting. 2003 Directory of Chemical Producers. SRI International, Menlo Park, CA. 2003, p. 261
    摘要:Suwanketnikom R, Toopornsiri M; Kasetsart J, Nat Sci 26: 81- 9 (1992)
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