CAS: 314-40-9; Bromacil

该化合物是一种合成除草剂,主要用于控制不同农业环境中的杂草,特别是柑橘和菠萝作物中的杂草,属于被称作替代尿素的化学品类别和抑制目标植物中的光合作用功能,其特点是水溶性相对较低,有助于其在环境中的持久性,对水生生物具有中度至高度毒性,需要谨慎管理,防止水源污染.Bromacil的化学结构包括一种溴原子,该原子可加强其除草活动.通常根据特定杂草物种的潜在环境影响,在使用前期或后期施用.鉴于其对环境的潜在影响,许多地区对Bromacil的使用实行管制,并建议用户遵守安全准则,以尽量减少对非目标物种和生态系统的风险.

结构式图片

相似化合物

22663-43-0 15018-59-4 80746-00-5

欧盟法规

REACH注册ECHA物质ECHA物质C&L通报REACH预注册

上下游产品

5-溴-6-甲基-3-(1-甲基乙基)-2,4-(1H,3H)-嘧啶二酮 Isocil 314-42-1
5-Brom-3-Cyclohexyl-1,6-Dimethyl-Uracil 7692-39-9
特草定 Terbacil 5902-51-2
环草定 Lenacil 01/08/2164

合成工艺路线路线简述

    Sodium;3-Butan-2-Yl-6-Methylpyrimidin-1-Ide-2,4-Dione置于氢溴酸,双氧水体系中,用 水 作为反应溶剂,以90 %的收率获得产物西玛嗪
    参考文献:Wo2024062479A1
    标题:Wo2024062479A1

    海关参考信息

    专利信息


    专利号:WO-2024012791-A1
    优先权日:2022-07-11
    标题 :Electrochemical synthesis of pyrazolines and pyrazoles
    发明人:BÄR ROBIN MAXIMILIAN; FORD MARK JAMES; KALDAS SHERIF JAMES; WALDVOGEL SIEGFRIED; HOFMANN SILJA; LINDEN MARTIN
    权利人:BAYER AG
    摘要:The present invention relates to an electrochemical process for the synthesis of pyrazolines and pyrazoles of formula (I). The process can be especially used for the synthesis of the herbicide safener mefenpyr-diethyl.

    专利号:WO-2024256370-A1
    优先权日:2023-06-13
    标 题 :Synthesis of glufosinate using an amidase-based process
    发明人:ZIMMERMANN GUNTHER; POTT MORITZ STEFAN
    权利人:BASF SE
    摘要:The present invention relates to a method of preparing glufosinate, comprising the steps of hydrolysing an N-carbamoyl glufosinate amide with an Amidase enzyme to form an N- carbamoyl amino acid compound followed by cleaving off the carbamoyl moiety of said N- carbamoyl amino acid compound.

    专利号:US-2025120400-A1
    优先权日:2021-12-10
    标题:Synthesis of glufosinate using a hydantoinase-based process
    发明人:DITRICH KLAUS; BREUER MICHAEL; POTT MORITZ STEFAN; ZIMMERMANN GUNTHER; SEEMAYER STEFAN
    权利人:BASF SE
    摘要:The present invention relates to a method of manufacturing glufosinate, comprising the steps of hydrolysing a hydantoin with a Hydantoinase enzyme to form a N-carbamoyl amino acid compound followed by cleaving off the carbamoyl moiety of said N-carbamoyl amino acid compound.

    专利号:US-11919928-B2
    优先权日:2016-03-16
    标题 :Method for producing dihydrotentoxin
    发明人:KUBO TAKASHI; MACHIDA MASAYUKI; FUJIOKA TOMONORI; YAMAGUCHI Shigenari; KAWAI KIYOSHI
    权利人:KUMIAI CHEMICAL INDUSTRY CO
    摘要:An object of the present invention is to identify an enzyme having activity of synthesizing dihydrotentoxin that is a tentoxin precursor and an enzyme having activity of synthesizing tentoxin using dihydrotentoxin as a substrate. The present invention concerns a tentoxin synthesis-related gene encoding a protein comprising the amino acid sequence of SEQ ID NO: 16 and having activity of nonribosomal peptide synthesis of dihydrotentoxin and a tentoxin synthesis-related gene encoding a protein comprising the amino acid sequence of SEQ ID NO: 18 and having activity of converting dihydrotentoxin to tentoxin.

    专利号:WO-03086971-A1
    优先权日:2002-04-18
    标题:Method for synthesising superhard materials
    发明人:STARCHENKO IGOR MICHAILOVICH
    权利人:STARCHENKO IGOR MICHAILOVICH
    摘要:The invention relates to the production of superhard materials including the synthesis of diamonds and cubic boron nitride, polycrystalline and composite materials based thereon, to the production of powders and tools containing such materials and used, in particular for manufacturing abrasive and cutting tools. The aim of said invention is to develop a method for producing superhard materials which makes it possible to ensure the high output of said materials at low temperatures and a relatively low pressure without using catalysts. The inventive method is characterised in that the ultradispersed powder of a material having a cubic structure is used in the form of crystal-forming additives. In one of variants, a diamond ultradispersed powder is used as an ultradispersed powder of a material having a cubic structure. The inventive synthesis of superhard materials (diamond and/or c-BN) is carried out at extremely low temperatures (800-1000 °C low than for catalytic synthesis) and at relatively low pressures. The output of the superhard materials is increased to 96-100 %, said materials being devoid of impurities, thereby making it possible to produce the tools having required structure and characteristics. Said invention significantly reduces energy and costly materials consumption.

    专利号:US-2021386068-A1
    优先权日:2018-11-07
    标题 :Compositions comprising pyridine carboxylate herbicides and very long chain fatty acid (vlcfa) synthesis inhibitor herbicides
    发明人:KISTER JEREMY; SATCHIVI NORBERT M
    权利人:CORTEVA AGRISCIENCE LLC
    摘要:Disclosed herein are compositions comprising (a) a pyridine carboxylate herbicide or an agriculturally acceptable N-oxide, salt, or ester thereof and (b) a VLCFA synthesis inhibitor herbicide. Also disclosed herein are methods of controlling undesirable vegetation, comprising applying to vegetation or an area adjacent the vegetation or applying in soil or water to control the emergence or growth of vegetation (a) a pyridine carboxylate herbicide or an agriculturally acceptable N-oxide, salt, or ester thereof, and (b) a VLCFA synthesis inhibitor herbicide.
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    主要参考文献


    1: Angthararuk D, Sutthivaiyakit P, Blaise C, Gagné F, Sutthivaiyakit S. Photo-catalysis of bromacil under simulated solar light using Au/TiO₂: evaluation of main degradation products and toxicity implications. Environ Sci Pollut Res Int. 2015 Jan;22(2):1468-79. doi: 10.1007/s11356-014-3425-3. Epub 2014 Aug 28. doi: 10.1186/s40064-015-1148-7. eCollection 2015.
    3: Williams RM, Kulick AR, Yedlapalli S, Battistella L, Hajiran CJ, Sooter LJ. In vitro selection of a single-stranded DNA molecular recognition element specific for bromacil. J Nucleic Acids. 2014;2014:102968. doi: 10.1155/2014/102968. Epub 2014 Oct 23.
    4: Chen Z, Zou Y, Wang J, Li M, Wen Y. Phytotoxicity of chiral herbicide bromacil: Enantioselectivity of photosynthesis in Arabidopsis thaliana. Sci Total Environ. 2016 Apr 1;548-549:139-147. doi: 10.1016/j.scitotenv.2016.01.046. Epub 2016 Jan 20. doi: 10.1002/etc.22. doi: 10.1016/j.chemosphere.2008.02.015. Epub 2008 Mar 28. doi: 10.1016/j.jhazmat.2010.05.035. Epub 2010 May 13. doi: 10.1002/rcm.5183.

    合成参考文献


    摘要:Fundamental and Applied Toxicology., 7(299), 1986
    摘要:Lam RHF et al; pp. 15-44 in Water Contamination and Health. Wang RGM ed. New York, NY: Marcel Dekker (1994)
    摘要:Spencer, E. Y. Guide to the Chemicals Used in Crop Protection. 7th ed. Publication 1093. Research Institute, Agriculture Canada, Ottawa, Canada: Information Canada, 1982., p. 51
    摘要:Lewis, R.J. Sr. (ed) Sax's Dangerous Properties of Industrial Materials. 11th Edition. Wiley-Interscience, Wiley & Sons, Inc. Hoboken, NJ. 2004., p. 544
    摘要:Hansch, C., Leo, A., D. Hoekman. Exploring QSAR - Hydrophobic, Electronic, and Steric Constants. Washington, DC: American Chemical Society., 1995., p. 61
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