CAS: 579-66-8; 2,6-Diethylaniline

上下游产品

2,3-dimethylindole ethene aniline toluene-4-sulfonic acid-(2,6-diethyl-anilide) N,N'-bis-(2,6-diethyl-phenyl)-pentanediyldiamineN,N'-bis-(2,6-diethyl-phenyl)-pentanediyldiamine N,N'-bis-(2,6-diethyl-phenyl)-hexanediyldiamineN,N'-bis-(2,6-diethyl-phenyl)-hexanediyldiamine N-triethyl-aniline2,6,N-triethyl-aniline 2,6-diethylphenol

2,6-二乙基-乙酰苯胺置于schwartz'S Reagent,水体系中,用 四氢呋喃 作为反应溶剂,化学反应 0.08H,以87%的收率获得产物2,6-二乙基苯胺
参考文献:Chemoselective N-Deacetylation Under Mild Conditions
标题:Chemoselective N-Deacetylation Under Mild Conditions
摘要:描述了一种温和高效的化学选择性去乙酰化方法,该方法使用施瓦茨试剂在室温下迅速进行.温和和中性的条件使得在一些常见保护基团(即b°C,Fm°C,Cbz,Ts)存在的情况下能够进行正交去乙酰化.去保护条件不会引起手性氨基中心的任何表异构化.
DOI:10.1039/c3Ob41971A

专利信息

专利号:US-5262373-A
优先权日:1990-04-20
标题:Process for the synthesis of metal oxides of high specific surface area and high porosity, oxides obtained and catalysts containing the said oxides
发明人：DURAND BERNARD; DE MAREUIL DOMINIQUE; VRINAT MICHEL; THIERRY DES GOURIERES
权利人:ELF AQUITAINE
摘要:PCT No. PCT/FR91/00322 Sec. 371 Date Jan. 17, 1992 Sec. 102(e) Date Jan. 17, 1992 PCT Filed Apr. 18, 1991 PCT Pub. No. WO91/16265 PCT Pub. Date Oct. 31, 1991.A process is provided for the synthesis for metal oxides of high specific surface area and high porosity which are particularly useful as catalyst supports. The process comprises forming a mixture of a salt of at least one metal and a molten salt medium comprising at least one alkali metal salt having an oxidizing effect, maintaining this mixture at the reaction temperature for the time necessary to convert the salt to oxide and thereafter isolating the metal oxide formed.

专利号:US-5329022-A
优先权日:1991-01-16
标 题:Process for the synthesis of citraconimides
发明人：TALMA AUKE G; HOOFT HENDRIKA P M; VAN DE BOVENKAMP-BOUWMAN ANNA
权利人:AKZO AMERICA INC
摘要:The present invention relates to an improved synthesis method for the making of citraconimides wherein a citraconic anhydride is reacted with 0.5 to 2.0 equivalents of at least one amine salt. This process may be carried out in a solvent and generally leads to excellent yields of the citraconimides with high selectivity and easy purification. The present inventional so relates to a process for the production of citraconic anhydride from itaconic anhydride with an amine or phosphine catalyst and in a cosolvent.

专利号:US-6316590-B1
优先权日:1999-11-10
标 题 :Synthesis of stereospecific and atactic poly(lactic acid)s
发明人：COATES GEOFFREY W; CHENG MING; CHAMBERLAIN BRADLEY M
权利人:CORNELL RES FOUNDATION INC
摘要:Isotactic poly ((R)-lactic acid) or isotactic poly (S)-lactic acid are respectively prepared from (R,R)-lactide and (S,S)-lactide using a catalyst which has a zinc center or a magnesium center and two ligands where one of the ligands is a propagating group and the other of the ligands is not a propagating group. Heterotactic poly(lactic acid) is prepared from rac-lactide using a catalyst which has a zinc center and two ligands where one of the ligands is a propagating group and the other of the ligands is not a propagating group; heterotactic poly(lactic acid) is a novel composition. The catalyst with a magnesium center is a novel catalyst. Syndiotactic poly(lactic acid) is prepared from meso-lactide using a syndiotactic poly(lactic acid) effecting catalyst which has a zinc center and two ligands where one of the ligands is a propagating group and the other of the ligands is not a propagating group and the preferred catalyst contains as the ligand which is not a propagating group diiminate substituted with isopropyl substituted phenyl and the propagating group is isopropoxide. Atactic poly(lactic acid) of polydispersity ranging from 1.15 to 1.40 is prepared in less than 10 minutes by polymerizing rac-lactide in the presence of C 1 -C 4 alcohol and a catalyst with a magnesium center and two ligands where one of the ligands is a propagating group and the other of the ligands is not a propagating group.

专利号:EP-0051792-A1
优先权日:1980-11-08
标 题 :Derivatives of hydroxamic-acid esters, process for their preparation and their use as herbicides
发明人：FUEHRER WOLFGANG DR; STETTER JOERG DR; EUE LUDWIG DR; SCHMIDT ROBERT RUDOLF DR
权利人:BAYER AG
摘要:Hydroxamic acid derivatives of the formula in which Y represents oxygen or sulfur, R¹ represents hydrogen, alkyl or alkoxy, R² represents hydrogen, alkyl, alkoxy or halogen, R³ represents hydrogen, alkyl, alkoxy or halogen, R < 4> represents hydrogen or alkyl, R <5> represents alkyl, alkenyl, alkynyl or alkoxyalkyl, R <6> represents hydrogen, alkyl, alkenyl, alkynyl or alkoxyalkyl or R <4> and R <5> together represent one Alkylene chain, or R 5 and R 6 together represent an alkylene chain, provided Y is oxygen and Z is halogen, a process for their preparation and their use as herbicides. N-phenylglycine derivatives of the formula in which Y, R¹, R², R³, R <4>, R <5> and R <6> have the meanings given above, several processes for their preparation and their use as intermediates for the synthesis of the substances of formula (I).

专利号:US-2010093880-A1
优先权日:2006-12-20
标 题:Recycling cleavage of polyurethanes
发明人：BERGFELD MANFRED; KIEFFER ANDREAS
权利人:BERGFELD MANFRED; KIEFFER ANDREAS
摘要:A process is described for splitting polyurethanes and polyurethaneureas, in which the polymer is first reacted with gaseous or liquid secondary aliphatic or cycloaliphatic amines, the secondary urea formed, after removal with hydrogen chloride, is split to the isocyanate, and the polyols or polyamines also formed in the reaction are worked up and purified. It is possible by the process according to the invention to work up polyurethanes, polyurethaneureas, etc., of any origin, and to break them down into the starting materials, specifically the isocyanates, polyols or polyamines, to form starting materials in very high quality, which can be reused for the synthesis of any polyurethanes or polyureas. The invention further provides for the preparation of secondary bis-ureas from polyurethanes or polyurethaneureas or/and ureas.

专利号:WO-2023248205-A1
优先权日:2022-06-23
标 题 :Novel ruthenium complexes, method of their synthesis, intermediate compounds used in this method, method of their synthesis and the use of novel ruthenium complexes in olefin metathesis reactions
发明人：GRELA KAROL; KAJETANOWICZ ANNA; SYTNICZUK ADRIAN; MILEWSKI MARIUSZ; PUROHIT VISHAL; STRUZIK FILIP
权利人:UNIV WARSZAWSKI
摘要:The subject of the invention is a novel ruthenium complex with the general formula Ru-1, in which all the variables have the meaning defined in the disclosure. The subject of the invention is also a synthesis method of the ruthenium complex, an intermediate which is a precursor of the ligand used in the synthesis reactions of the ruthenium complex CAAC-1 and application of this ruthenium complex as a (pre)catalyst in olefin metathesis reactions.