100-20-9 + 90-14-2 = 624-38-4 + 879-18-5 反应条件:1.1 Catalysts: 2241736-67-2 Solvents: Benzene-D6; 20 H,110 °C 标题:Functional Group Transposition: A Palladium-Catalyzed Metathesis Of Ar-X σ-Bonds And Acid Chloride Synthesis 作者:De La Higuera Macias,Maximiliano; Et Al 参考文献:Journal Of The American Chemical Society 日期:2018 卷标:140(32) 页码:10140-10144]
624-31-7 + 100-20-9 = 624-38-4 + 874-60-2 反应条件:1.1 Catalysts: 2241736-67-2 Solvents: Benzene-D6; 20 H,110 °C 标题:Functional Group Transposition: A Palladium-Catalyzed Metathesis Of Ar-X σ-Bonds And Acid Chloride Synthesis 作者:De La Higuera Macias,Maximiliano; Et Al 参考文献:Journal Of The American Chemical Society 日期:2018 卷标:140(32) 页码:10140-10144
专利号:US-4788354-A 优先权日:1984-10-16 标 题 :Method for the synthesis of iodobenzene 发明人:PAPARATTO GIUSEPPE; SAETTI MARCO 权利人:MONTEDIPE SPA 摘要:A method for the synthesis of iodobenzene by iodination, in the gaseous phase, of benzene with iodine, in the presence of a zeolitic catalyst, selected from the group comprising the zeolites of X type or of Y type, characterized in that said iodination is an oxidative one and that said zeolites are in a form different from the acid (H) form.
专利号:US-5239052-A 优先权日:1990-08-30 标 题 :Process for synthesis of aromatic sulfides 发明人:HAY ALLAN S; WANG ZHI Y 权利人:HAY ALLAN S; WANG ZHI Y 摘要:Aromatic sulfides including diarylsulfides and poly(arylene sulfides) are produced in a novel synthesis in high yield under moderate conditions by heating an aromatic disulfide in the presence of aromatic halide, in which the halide is chloride, bromide or iodide; the diaryl sulfides are useful precursors and starting materials for a range of compounds and the poly(arylene sulfides) are important high temperature engineering thermoplastics.
专利号:US-5177183-A 优先权日:1990-08-30 标 题:Process for synthesis of aromatic sulfides 发明人:HAY ALLAN S; WANG ZHI Y 权利人:HAY ALLAN S; WANG ZHI Y 摘要:Aromatic sulfides including diarylsulfides and poly(arylene sulfides) are produced in a novel synthesis in high yield under moderate conditions by heating an aromatic disulfide in the presence of aromatic halide, in which the halide is chloride, bromide or iodide; the diaryl sulfides are useful precursors and starting materials for a range of compounds and the poly(arylene sulfides) are important high temperature engineering thermoplastics.
专利号:US-5484883-A 优先权日:1990-06-25 标题 :Lithium/HMPA-promoted synthesis of poly(phenylenes) 发明人:TOUR JAMES M; STEPHENS ERIC B 权利人:UNIV SOUTH CAROLINA 摘要:Poly(phenylene) that is substantially free of insoluble material is prepared by the polymerization of a lithioarylhalide compound in the presence of a polar aprotic compound such as hexamethylphosphoramide, N,N,N',N'-tetramethylethylenediamine or hexamethylphosphorous triamide. The preferred reaction involves the polymerization of 1-bromo-4-lithiobenzene in the presence of hexamethylphosphoramide. The 1-bromo-4-1ithiobenzene may be synthesized by reacting 1,4-dibromobenzene with t-butyllithium. These same types of reactions can also be used to synthesis other benzenoid polymers.
专利号:US-10865163-B2 优先权日:2017-12-20 标题:Carbon dioxide as a directing group for C—H functionalization reactions involving Lewis basic amines, alcohols, thiols, and phosphines for the synthesis of compounds 发明人:YOUNG MICHAEL C; KAPOOR MOHIT 权利人:UNIV TOLEDO 摘要:Methods of synthesizing compounds using CO 2 as a directing group for C—H functionalization, and compounds made thereby, are described.
专利号:US-7722851-B2 优先权日:2001-12-10 标题 :Bulk synthesis of carbon nanotubes from metallic and ethynyl compounds 发明人:KELLER TEDDY M; QADRI SYED B 权利人:US NAVY 摘要:A process of making carbon nanotubes comprising the steps of: providing a precursor composition comprising at least one metallic compound and at least one organic compound; wherein the organic compound is selected from the group consisting of an ethynyl compound, a metal-ethynyl complex, and combinations thereof; wherein the precursor composition is a liquid or solid at room temperature; and heating the precursor composition under conditions effective to produce carbon nanotubes. A carbon nanotube composition comprising carbon nanotubes and a metal component selected from the group consisting of metal nanoparticles and elemental metal; wherein the carbon nanotube composition is rigid.
[参考文献]: Alfonso Pérez-Garrido, Et Al. Convenient Qsar Model For Predicting The Complexation Of Structurally Diverse Compounds With Beta-Cyclodextrins. Bioorg Med Chem. 2009 Jan 15;17(2):896-904. [参考文献]: J A Lipton-Duffin, Et Al. Synthesis Of Polyphenylene Molecular Wires By Surface-Confined Polymerization. Small. 2009 Mar;5(5):592-7. [参考文献]: Uta Funke, Et Al. Radiosynthesis And Radiotracer Properties Of A 7-(2-[18F]Fluoroethoxy)-6-Methoxypyrrolidinylquinazoline For Imaging Of Phosphodiesterase 10A With Pet. Pharmaceuticals (Basel). 2012 Feb 6;5(2):169-88.
合成参考文献
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