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CAS号24771-25-3 N-氰亚胺基碳酸二甲酯 | CAS号124-42-5 乙脒盐酸盐 | CAS号82097-50-5 醚苯磺隆 | CAS号144550-06-1 甲基碘磺隆甲酯 | CAS号64902-72-3 氯磺隆 | CAS号74223-64-6 甲磺隆 | CAS号4223-09-0 sulfuryl diis°C... | CAS号64903-72-6 thiophene-2-sul...合成工艺路线路线简述
- 合成目标产物 2-Amino-4-Methoxy-6-Methyl-1,3,5-Triazine 主要起始原料 Dimethyl Cyanocarbonimidate And Acetamidine Hydrochloride
- (文献来源)合成步骤主要原料 Dimethyl Cyanocarbonimidate 和 Acetamidine Hydrochloride
醚苯磺隆 以 二甲基亚砜 用作溶剂,化学反应 72.0H,以45%的收率获得2-氨基-4-甲氧基-6-甲基-1,3,5-三嗪
参考文献:Kinetics And Hydrolysis Mechanism Of Triasulfuron
标题:Kinetics And Hydrolysis Mechanism Of Triasulfuron
摘要:The Hydrolysis Of The Sulfonylurea Herbicide Triasulfuron [(2-(2-Chloroethoxy)-N-[[4-Methoxy-6-Methyl-1,3,5-Triazin-2-yl) Amino] Carbonyl]Benzenesulfonamide] Was Studied In Aqueous Buffers Of Ph Values 2,3,4,5,6,7,And 9. The Reaction Was Of First-Order And Ph-Dependent. Triasulfuron Was More Persistent In Neutral Or Weakly Basic Than In Acidic Solution. Five Metabolites Have Been Isolated And Identified. At All Ph Values Studied,The Primary Pathway Of Degradation Was The Cleavage Of The Sulfonylurea Bridge. However,Minor Degradation Pathways Have Also Been Observed Like O-Demethylation And Opening Of The Triazine Ring. The Product Distribution Was Ph-Dependent.
Doi:10.1021/jf970299D
专利信息
专利号:WO-2004020401-A1
优先权日:2002-09-02
标题 :Synthesis of sulfonamide derivatives
发明人:KALLIKAT JOHN; MANDAL ASHIS BARAN; GANESH SAMBASIVAM
权利人:SYNGENE INTERNAT PRIVATE LTD; KALLIKAT JOHN; MANDAL ASHIS BARAN; GANESH SAMBASIVAM
摘要:The novel method of synthesis of sulphonamide derivatives (I), comprising reaction of alkyl-4-halophenylsulfonate with an amine. Formula (I) wherein X is halogen and R1 and R2 are independently selected from group comprising (i) C1 to C15 alkyl, straight or branched, (ii) C3 to C15 cycloalkyl, substituted or unsubstituted, (iii) C2 to C15 alkenyl, straight or branched, (iv) C2 to C15 alkynyl, straight or branched, (v) phenyl or benzyl, substituted or unsubstituted, (vi) heterocycloalkyl, substituted or unsubstituted, (vii) hydrogen, (viii) form with the nitrogen to which they are attached a 3-7 membered heterocyclic moiety such as pyrolidine, piperidine, piperazine, imidazole, pyrazole, (ix) the alkyl in i) may be attached to a moiety selected from cycloalkyl or heterocycloalkyl, substituted or unsubstituted
专利号:RU-2096408-C1
优先权日:1993-03-11
标题 :Method of synthesis of substituted amino-1,3,5-triazines
专利号:CN-104387334-A
优先权日:2014-10-27
标题:A kind of synthesis technique of 2-amino-4-methoxy-6-methyl-s-triazine
专利号:CN-103508968-A
优先权日:2013-09-12
标题:Green Synthesis Process of Tribesulfuron-methyl for Broadleaf Weed Removal in Wheat Fields
专利号:CN-110283133-B
优先权日:2019-05-31
标 题 :Synthesis process of metsulfuron-methyl-D3