CAS: 606-45-1; Methyl 2-Methoxybenzoate

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CAS号67-56-1 甲醇 | CAS号579-75-9 邻甲氧基苯甲酸 | CAS号77-78-1 硫酸二甲酯 | CAS号69-72-7 水杨酸 | CAS号135-02-4 邻甲氧基苯甲醛 | CAS号75-91-2 叔丁基过氧化氢 | CAS号578-57-4 邻溴苯甲醚 | CAS号201230-82-2 carbon monoxide | CAS号21615-34-9 邻甲氧基苯甲酰氯 | CAS号100-66-3 苯甲醚 | CAS号40751-89-1 2-甲氧基-5-硝基苯甲酸 | CAS号34841-11-7 2-甲氧基-5-硝基苯甲酸甲酯 | CAS号35276-83-6 2-甲氧基苯甲酰乙腈 | CAS号41607-95-8 (2-甲氧基苯甲酰基)乙酸乙酯 | CAS号4630-82-4 环己甲酸甲酯 | CAS号51664-89-2 1-carbomethoxy-... | CAS号22945-63-7 2-(2-METHOXYBEN... | CAS号611-20-1 水杨腈 | CAS号6609-56-9 2-甲氧基氰苯 | CAS号579-75-9 邻甲氧基苯甲酸

2,6-二甲氧基苯甲酸甲酯置于bis(1,5-Cyclooctadiene)Nickel (0),1,1,3,3-四甲基二硅氧烷,三环己基膦体系中,用 甲苯 作为反应溶剂,化学反应 12.0H,以68%的收率获得产物2-甲氧基苯甲酸甲酯
参考文献:通过镍催化完全还原酯类
标题:通过镍催化完全还原酯类
摘要:我们报告了将未活化的芳基酯直接还原为其相应的甲苯基衍生物的一步程序.这是通过有机硅烷介导的酯氢化硅烷化反应和随后的 Ni/nhc 催化氢解来实现的.由此产生的条件为通常需要使用危险金属氢化物的这种转化的多步骤程序提供了一种直接有效的替代方法.展示了在合成含-Cd3 的产品,生物活性分子的衍生化以及在其他 Co 键存在下进行化学选择性还原中的应用.
DOI:10.1021/jacs.0C02405

专利信息

专利号:US-2010137421-A1
优先权日:2006-11-08
标题 :Small molecule therapeutics, synthesis of analogues and derivatives and methods of use
发明人：THEODORAKIS EMMANUEL; BATOVA AYSE
权利人:THEODORAKIS EMMANUEL; BATOVA AYSE
摘要:Provided herein are compounds that are inducers of apoptosis activators of caspases and pharmaceutically acceptable derivatives thereof. Also provided are methods of synthesis of the compounds and methods for treatment of diseases in which there is uncontrolled cell growth and spread of abnormal cells, such as cancers, by administering the compounds.

专利号:US-2019276389-A1
优先权日:2015-12-18
标题:Synthesis of aryl cyclohexane ester derivatives useful as sensates in consumer products
发明人：WOS JOHN AUGUST; YELM KENNETH EDWARD; BUNKE GREGORY MARK; FREDERICK HEATH ALAN; REILLY MICHAEL; HAUGHT JOHN CHRISTIAN; SREEKRISHNA KOTI TATACHAR; LIN YAKANG
权利人:PROCTER & GAMBLE
摘要:Personal care compositions, such as oral care and skin care compositions containing a flavor/perfume system comprising one or more coolants. The pleasant cool sensation provided by a coolant is enhanced in terms of quicker onset, greater intensity, impact or longer duration, which improves appeal and acceptability of the compositions to consumers.

专利号:CN-101456815-A
优先权日:2007-12-13
标题:Synthesis of Aromatic Carboxylates by Carbonylation of Iodo-Arenes

专利号:BR-112017006799-B1
优先权日:2014-10-17
标题 :METHOD OF TREATMENT OF AN UNDERGROUND FORMATION, PROCESS FOR THE SYNTHESIS OF A COMPOUND, AND, SYSTEM FOR CARRYING OUT THE METHOD

专利号:US-6602989-B1
优先权日:2000-05-17
标题:Synthesis, characterization, and application of pyridylazo bioconjugates as diagnostic and therapeutic agents
发明人：SADIK OMOWUNMI A; XU HONGWU
权利人:UNIV NEW YORK STATE RES FOUND
摘要:The detection of gallium in biological samples is required due to its role in the diagnosis of tumor and for possible treatment of malignancies. However, the use of purely instrumental techniques is unsuitable for detection of low levels of gallium in biological matrices. New protein conjugates have been synthesized based on 4-(2-pyridylazo) ligands. The conjugates detect gallium in biological matrices using a non antibody-based sandwich assay format. The recovery level is between 97-101.3 with a relative standard deviation of less than 5%. The assay results in a detection limit of 5×10 −8 M and a remarkable selectivity for gallium(III) relative to other metals investigated. The new method provides adequate accuracy for gallium applicable for animal physiology and clinical toxicology.

专利号:US-7132092-B2
优先权日:2002-02-08
标 题:Metallized mesoporous silicate and method of oxidation with the same
发明人：HAGIYA KOJI
权利人:SUMITOMO CHEMICAL CO
摘要:A metallized mesoporous silicate which is obtained by (i) reacting (a) either a metal peroxide obtained by the reaction of an aqueous hydrogen peroxide solution with at least one metal or metal compound selected from the group consisting of the following 1) to 4) 1) tungsten 2) molybdenum 3) vanadium 4) compounds comprising 4 a ) any of tungsten, molybdenum, and vanadium and 4 b ) at least one element selected from Groups 13 to 16 (excluding oxygen) or a solution of the metal peroxide with (b) a silicon compound in the presence of an alkylamine or a quaternary ammonium salt and separating the resultant silicate; and a process for producing the metallized mesoporous silicate. Also provided is a method of organic synthesis with the silicate.