CAS: 7152-03-6; Cyclopropyl(4-Methoxyphenyl)Methanone

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CAS号4023-34-1 环丙甲酰氯 | CAS号100-66-3 苯甲醚 | CAS号40877-19-8 γ-氯-4-甲氧基苯丁酮 | CAS号3874-54-2 4-氯-4'-氟苯丁酮 | CAS号23719-80-4 环丙基溴化镁 | CAS号874-90-8 4-甲氧基苯甲腈 | CAS号2973-86-6 苯硫酚锂 | CAS号111448-45-4 cyclopropyl[bis... | CAS号6552-45-0 alpha-cycloprop... | CAS号62586-99-6 Benzenemethanol... | CAS号100-09-4 对甲氧基苯甲酸 | CAS号4160-51-4 4'-甲氧基苯丁酮 | CAS号12771-68-5 嘧啶醇 | CAS号36116-18-4 环丙基(4-羟基苯基)甲酮 | CAS号22217-80-7 5-(4-甲氧基苯基)-3,4... | CAS号6552-45-0 alpha-cycloprop... | CAS号829-17-4 1-(1-cyclopropy... | CAS号62586-86-1 1-cyclopropyl-1...

4,4'-二甲氧基二苯甲酮置于碘苯二乙酸,碘体系中,用 四氢呋喃,二氯甲烷 作为反应溶剂,化学反应 0.25H,反应生成 环丙基-4-甲氧基苯酮
参考文献:环取代对1,1-二芳基烷氧基自由基的o-叶肉重排的影响.产品和时间分辨动力学研究
标题:环取代对1,1-二芳基烷氧基自由基的o-叶肉重排的影响.产品和时间分辨动力学研究
摘要:已经进行了环取代对1,1-二芳基烷氧基自由基反应性影响的产物和时间分辨动力学研究.所述基团经历o-新叶酸移位,以给出异构的1-芳基-1-芳氧基烷基,从其形成相应的芳族酮.重排速率常数受环取代的影响,在吸电子取代基的存在下增加,而在供电子取代基的存在下降低.根据产物和动力学研究的结果,获得了以下迁移能力:4-三氟甲基苯基>苯基≅4-甲基苯基> 4-甲氧基苯基.σ +之间的出色hammett型相关性获得了取代基常数以及可见吸收带最大值和重排速率常数.实验结果表明,重排受起始的1,1-二芳基烷氧基自由基的电子效应支配,而重排的以碳为中心的自由基的稳定性起次要作用,与类似反应物的过渡态一致,强烈支持了1,1-二芳基烷氧基基团的o-新叶重排通过协调机制进行的假说.
DOI:10.1021/jo0502448

专利信息

专利号:US-7253324-B1
优先权日:2007-01-23
标 题:Process for the synthesis of biologically active oxygenated compounds by dealkylation of the corresponding alkylethers
发明人：MAJEED MUHAMMED; THOMAS SAMUEL MANOHARAN; NAGABHUSHANAM KALYANAM; BALAKRISHNAN SIVAPRAKASH KURUM; PRAKASH SUBBALAKSHMI
权利人:SAMI LABS LTD
摘要:Alkoxy aromatic compounds are conveniently dealkylated to the corresponding phenolic compounds by treatment with aluminum chloride/N,N-dimethyl aniline complex. Aromatic poly O-demethylation is a unique feature of this invention. This process is applicable to the manufacture of polyphenols such as Resveratrol, Oxyresveratrol, Gnetol.

专利号:US-3869456-A
优先权日:1972-03-13
标 题 :Synthesis of 5-pyrimidinecarbinols
发明人：TAYLOR HAROLD M; DAVENPORT JAMES D; HACKLER RONALD E
权利人:LILLY CO ELI
摘要:There is disclosed an improved method of synthesizing 5pyrimidinecarbinols by the addition of an alkyllithium to a mixture of 5-halopyrimidine and a ketone at a low temperature. The product compounds are useful as plant fungicides and as plant growth regulators.

专利号:WO-2008091379-A1
优先权日:2007-01-23
标题 :A process for the synthesis of biologically active oxygenated compounds by dealkylation of the corresponding alkyllethers