CAS: 87061-56-1; Triethoxy(1-Triethoxysilylethenyl)Silane

该化合物是有机硅化合物,其特征是双三氧环乙烷功能组,附于乙烯基骨上,结构允许其作为硅合金剂,加强有机材料和无机亚体(如玻璃或金属)之间的粘合;三氧环乙烷组可水解,使化合物在接触水分时形成硅烷联结,有利于产生耐久的涂层和密封剂.二(三氧环乙烷)乙烯通常无色,无色可染黄色液体,具有低挥发性和高热稳定性,在有机溶剂中可溶性,可用于各种用途,包括表面改造,复合材料,以及聚合剂制剂中的交叉联结剂.三氧环环基组在改进机械特性和耐受环境因素影响的能力使其在建筑,汽车和电子等行业中具有价值.在处理这种化合物时,应当注意安全防范,因为它可能会导致皮肤接触或皮肤.

英文名称Triethoxy(1-Triethoxysilylethenyl)Silane
中文名称双(三乙氧基硅基)乙烯
其它别名BIS(TRIETHOXYSILYL)ETHYLENE; Bis(triethoxysilyl)ethylene~80%transisomer
CAS编号87061-56-1
MFCD编号:MFCD28134212
EINECS号:689-758-7
分子式:C14H32O6Si2
分子量:352.57
产品CID: 1875174
产品分类化学试剂 → 硅烷试剂

相似结构搜索
InChIKey: BTLPDSCJUZOEJB-UHFFFAOYSA-N
InChI=1S/C14H32O6Si2/c1-7-15-21(16-8-2,17-9-3)13-14-22(18-10-4,19-11-5)20-12-6/h13-14H,7-12H2,1-6H3/b14-13+…
计算化学: 氢键受体数6.0氢键供体数0.0可旋转键数14.0

MSDS等安全信息

GHS象形图
GHS符号GHS07;
注释: Exclamation mark
危险类别严重眼刺激类别2
急性毒性类别4(经皮)
急性毒性类别3(经口)
水生慢性毒性类别3
警示词Warning(警告)
危险描述H319 |造成严重眼刺激.
H312 |皮肤接触有害.
H301 |吞咽会中毒.
H412 |对水生生物有害并具有长期持续影响.
防范说明P264-P280-P305+P351+P338-P337+P313P
危险品标志Xi
安全声明23-36/37/39-45
危险类别码20/21/22-36/37/38

欧盟法规

ECHA物质C&L通报

上下游产品

Triethoxysilane Triethoxyvinylsilane acetylene1,2-bis(triethoxysilyl)ethane

合成工艺路线路线简述

合成目标产物 Bis(Triethoxysilyl)Ethylene 主要起始原料 Ethanol And Silane, 1,2-Ethenediylbis[trichloro-
998-30-1 = 87061-56-1
反应条件:1.1 Catalysts: Bis[1,3-Bis(η2-Ethenyl)-1,1,3,3-Tetramethyldisiloxane][μ-[1,3-Bis(η2-Ethenyl)-1,...; 2 H,393 K
标题:Process For Preparation Of Silylethenes By Dehydrogenative Hydrosilylation Of Terminal Olefins With Hydrosilanes In Presence Of Vinylsiloxane-Containing Nickel Catalyst
参考文献:Poland]

998-30-1 = 87061-56-1 + 52885-14-0
反应条件:1.1 Catalysts: Bis(Acetylacetonato)Nickel,Tris(2,6-Dimethoxyphenyl)Phosphine
标题:Catalysis Of Hydrosilylation. Part Xxv. Effect Of Nickel(O) And Nickel(Ii) Complex Catalysts On Dehydrogenative Silylation,Hydrosilylation And Dimerization Of Vinyltriethoxysilane
作者:Marciniec,Bogdan; Et Al
参考文献:Journal Of Organometallic Chemistry 日期:1994 卷标:484(1-2) 页码:147-51]

5356-83-2 + 2550-04-1 = 87061-56-1 + 151176-38-4 + 15772-90-4
反应条件:1.1 Catalysts: Dichlorotris(Triphenylphosphine)Ruthenium Solvents: Benzene
标题:Metathesis Of Silicon-Containing Olefins. Part Xii. Metathetical Activity Of Allyl-Substituted Silanes In The Presence Of Ruthenium Catalyst
作者:Marciniec,Bogdan; Et Al
参考文献:Journal Of Molecular Catalysis 日期:1994 卷标:90(1-2) 页码:125-34]

998-30-1 = 87061-56-1 + 16068-37-4
反应条件:1.1 2 - 24 H,20 - 120 °C
标题:Triethoxysilane
作者:Corriu,Robert J. P.; Et Al
参考文献:E-Eros Encyclopedia Of Reagents For Organic Synthesis 日期:2014 卷标:1 页码:1-10]

= 87061-56-1 + 52111-25-8 + 195209-68-8 + 52111-26-9 + 65119-03-1
反应条件:1.1 Catalysts: Dichlorotris(Triphenylphosphine)Ruthenium Solvents: Benzene
标题:Metathesis Of Silicon-Containing Olefins. 14. Ruthenium-Catalyzed Cross-Metathesis Of Trisubstituted Vinylsilanes With Light Alkenes
作者:Foltynowicz,Zenon; Et Al
参考文献:Applied Organometallic Chemistry 日期:1997 卷标:11(8) 页码:667-671]

998-30-1 = 87061-56-1 + 195209-68-8 + 16068-37-4
反应条件:1.1 Catalysts: Nickel Solvents: Toluene; 120 °C
标题:Alkene Hydrosilylation With Supported And Unsupported Ni Nanoparticles: Strong Influence Of The Ni Environment On Activity And Selectivity
作者:Galeandro-Diamant,Thomas; Et Al
参考文献:Catalysis Science & Technology 日期:2019 卷标:9(7) 页码:1555-1558]

998-30-1 = 87061-56-1 + 52885-14-0 + 151198-82-2 + 137963-74-7 + 16068-37-4
反应条件:1.1 Catalysts: Bis(Acetylacetonato)Nickel
标题:Catalysis Of Hydrosilylation. Xxiii. Effect Of Substituents At Silicon On Unusual Hydrosilylation Of Vinylsilanes Catalyzed By Nickel Acetylacetonate
作者:Marciniec,Bogdan; Et Al
参考文献:Journal Of Organometallic Chemistry 日期:1993 卷标:454(1-2) 页码:45-50]

692-52-4 = 87061-56-1
反应条件:1.1 Solvents: Dichloromethane
标题:Alkoxylation Of 1,2-Bis(Methylchlorosilyl)Ethylenes And -Acetylenes
作者:Lakhtin,V. G.; Et Al
参考文献:Russian Journal Of General Chemistry (Translation Of Zhurnal Obshchei Khimii) 日期:2001 卷标:71(8) 页码:1252-1254]

998-30-1 = 87061-56-1
反应条件:1.1 Catalysts: Nickel,[μ-(η4:η4-2,4,6,8-Tetraethenyl-2,4,6,8-Tetramethylcyclotetrasiloxane)]Bi...; Rt; 3 H,120 °C
标题:Nickel(0) Phosphine Complexes,Process For Their Preparation And Activity As Dehydrogenative Hydrosilylation Catalysts For Olefins
参考文献:Poland]

998-30-1 = 87061-56-1
反应条件:1.1 Catalysts: Nickel,[μ-[1,3-Bis(η2-Ethenyl)-1,1,3,3-Tetraphenyldisiloxane]]Bis[1,3-Bis(η2-Et...; Rt; 2 H,120 °C
标题:Process For Preparation Of Nickel(0) Vinylsiloxane Complexes From Nickel Cyclooctadiene And Divinyldisiloxane Derivatives As Dehydrogenative Silylation Catalysts For Olefins
参考文献:Poland]

4667-99-6 + 79-01-6 = 87061-56-1
反应条件:1.1 Reagents: Butyllithium Solvents: Diethyl Ether; -78 °C; 1 H,-78 °C; 12 H,Rt1.2 Solvents: Diethyl Ether; Rt -> -78 °C; 12 H,-78 °C -> Rt
标题:Polymerization Behavior And Gel Properties Of Ethane,Ethylene And Acetylene-Bridged Polysilsesquioxanes
作者:Yamamoto,Kazuki; Et Al
参考文献:Journal Of Sol-Gel Science And Technology 日期:2014 卷标:71(1) 页码:24-30]

998-30-1 = 87061-56-1 + 52885-14-0
反应条件:1.1 Catalysts: Nickel,Bis(3-Propyl-2,4-Pentanedionato-Ko,Ko′)-; Rt -> Reflux; 24 H,Reflux
标题:Process For Preparation Of Bis(Silyl)Ethenes By Dehydrogenative Silylation Of Vinylsilanes With Hydrosilanes In Presence Of Nickel(Ii) Catalyst
参考文献:Poland]

998-30-1 = 87061-56-1 + 52885-14-0
反应条件:1.1 Catalysts: Triphenylphosphine,Bis(Acetylacetonato)Nickel
标题:Catalysis Of Hydrosilylation. Part Xxv. Effect Of Nickel(O) And Nickel(Ii) Complex Catalysts On Dehydrogenative Silylation,Hydrosilylation And Dimerization Of Vinyltriethoxysilane
作者:Marciniec,Bogdan; Et Al
参考文献:Journal Of Organometallic Chemistry 日期:1994 卷标:484(1-2) 页码:147-51]

998-30-1 = 87061-56-1 + 52885-14-0 + 16068-37-4
反应条件:1.1 Catalysts: Bis(Acetylacetonato)Nickel
标题:Catalysis Of Hydrosilylation. Part Xxv. Effect Of Nickel(O) And Nickel(Ii) Complex Catalysts On Dehydrogenative Silylation,Hydrosilylation And Dimerization Of Vinyltriethoxysilane
作者:Marciniec,Bogdan; Et Al
参考文献:Journal Of Organometallic Chemistry 日期:1994 卷标:484(1-2) 页码:147-51

乙烯基三乙氧基硅烷置于ruhcl(Co)(Pcy3)2 Immobilized In 1-Butyl-3-Methylimidazolium Bis(Trifluoromethylsulfonyl)Imide体系中,用十二烷作为反应溶剂,化学反应 5.0H,以92%的收率获得产物(E)-1,2-Bis(Triethoxysilyl)Ethene
参考文献:通过在离子液体中进行的钌催化的乙烯基硅烷均质偶合,高效合成e-1,2-双(甲硅烷基)乙烯
标题:通过在离子液体中进行的钌催化的乙烯基硅烷均质偶合,高效合成e-1,2-双(甲硅烷基)乙烯
摘要:一系列钌络合物(rucl 3 x3H2O,[c 5 H 5 Ru(ch 3 Cn)3] + [pf 6]-,[rucl 2(pph 3)3],[ruhcl(co)(pph)3)3],固定在[bmim] [tf 2 N]中的[ruhcl(co)(pcy 3)2])在乙烯基硅烷(h 2 C Chsi(oet)3,H 2 C Chsi(o I Pr)3,H 2C Chsi(osime 3)3,H 2 C Chsime(osime 3)2和h 2 C Chsiph(osime 3)2)在双相系统中进行.对于[ruhcl(co)(pcy 3)2],观测到最高的催化活性和均偶联产物的选择性.固定在多种离子液体([bmim] [pf 6],[bmim] [bf 4],[bmim] [tf 2 N],[bmim] [tfo]中的络合物[ruhcl(co)(pcy 3)2]],[bmim]
DOI:10.1016/j.Apcata.2012.08.038

海关参考信息

2901210000-乙烯
💡 提示：海关信息按照顺序优先匹配，如需确认的海关信息，请参考相关资料。
详情请参考：📖 海关编码查询和海关进出口税则

专利信息

专利号:US-2010003204-A1
优先权日:2008-07-02
标题 :Nanoparticle hybrid sunscreens
发明人：LOY DOUGLAS ANSON; SHEA KENNETH J; BODAY DYLAN J; WERTZ JASON T
权利人:ENERGY MATERIALS CORP
摘要:The invention discloses and claims a new class of chemical compositions with ideal sunscreen properties. The chemical composition comprises spherical particles between 200 nm and 10 microns in diameter prepared by an emulsion polymerization of tetraalkoxysilanes or organotrialkoxysilanes or organobridged trialkoxysilanes with a dye monomer bearing two or more alkoxysilyl groups attached to the bridging chromophore. The resulting spheres absorb ultraviolet light. The dye can be any organic chromophore capable of receiving multiple trialkoxysilyl groups resulting in multipoint covalent attachment that precludes leaching of the dye from the spheres. The formic acid-toluene-monomer emulsion polymerization allows for large-scale (>100 gram) synthesis of monodisperse particles under acidic, non-aqueous conditions without surfactants. The particles less than 1 micron in diameter are smooth as talc to the touch and will provide a smooth formulation for sunscreen creams or lotions.

专利号:AU-2020226216-A1
优先权日:2019-02-21
标题:Direct nanoemulsion process for the synthesis of spheroidal organosiloxane sub-micron/nanoparticles

专利号:CA-3127541-A1
优先权日:2019-02-21
标题 :Direct nanoemulsion process for the synthesis of spheroidal organosiloxane sub-micron/nanoparticles

专利号:US-2021378981-A1
优先权日:2019-02-21
标题 :Direct nanoemulsion process for the synthesis of spheroidal organosiloxane sub-micron/nanoparticles

专利号:EP-3927379-A1
优先权日:2019-02-21
标题 :Direct nanoemulsion process for the synthesis of spheroidal organosiloxane sub-micron/nanoparticles