CAS: 88-53-9; 2-Amino-5-Chloro-4-Methylbenzenesulfonic Acid

该化合物是一种全氟辛烷磺酸芳烃化合物,主要用作染料,色素和特殊化学品的合成中间体,其分子结构包括氨基和磺酸功能组,增强了其在相系和其他电益替代反应中的回活动性;氯和甲基替代成分有助于其稳定性和影响衍生产品的电子特性;该化合物因其在生产光敏度和溶性提高的高性能色素方面的作用而受到重视;通常以精细粉或晶体固态供应,其纯度一致,以确保工业应用中的可靠性能;建议进行适当的处理和储存,因为其可能具有湿度和热度.

结构式图片

欧盟法规

REACH注册ECHA物质ECHA物质C&L通报REACH预注册

上下游产品

CAS号7664-93-9 硫酸 | CAS号7149-75-9 4-氯-3-甲基苯胺 | CAS号98-34-0 2-chlorotoluene... | CAS号88-56-2 乙基-CLT酸 | CAS号7149-75-9 4-氯-3-甲基苯胺 | CAS号88-62-0 2-氨基-4-甲基苯磺酸

合成工艺路线路线简述

  • 6973-13-3 = 88-53-9
    反应条件:1.1 Reagents: Carbon Monoxide Catalysts: 1,8-Diazabicyclo[5.4.0]Undec-7-Ene,Selenium Solvents: Water; 6 H,6 Mpa,160 °C
    标题:Selenium-Catalyzed Reduction To Prepare Clt Acid With Co/h2O By High Pressure Reduction In Aqueous Solution
    作者:Wang,Si-Yuan; Qin,Long; Zhang,Chuan-Yang; Wang,Bei-Bei; Liu,Xiao-Zhi
    参考文献:Ranliao Yu Ranse 日期:2015 卷标:52(1) 页码:42-44]

    6973-13-3 = 88-53-9
    反应条件:1.1 Reagents: Hydrogen Catalysts: Alumina,Palladium; 3 H,3 Mpa,100 °C
    标题:Influence Of Support Calcination Temperature On The Performance Of Pd/al2O3 Catalyst Used In Liquid-Phase Catalytic Hydrogenation Of 6-Chloro-3-Nitrotoluene-4-Sulfonic Acid
    作者:Xu,Le; Hua,Da-Yin; Zhou,Sheng-Hu; Yu,Hong-Bo
    参考文献:Huaxue Yanjiu Yu Yingyong 日期:2014 卷标:26(2) 页码:187-193]

    6973-13-3 = 88-53-9
    反应条件:1.1 Reagents: Carbon Monoxide,Selenium Catalysts: 1,8-Diazabicyclo[5.4.0]Undec-7-Ene Solvents: N,N-Dimethylaniline,Water; 10 H,180 °C
    标题:Selenium-Catalyzed Reduction To Prepare Clt Acid With Co/h2O By Atmospheric Pressure Reduction
    作者:Wang,Si-Yuan; Bai,Xue-Jing; Wang,Bei-Bei; Zhang,Chuan-Yang; Liu,Xiao-Zhi
    参考文献:Ranliao Yu Ranse 日期:2015 卷标:52(2) 页码:26-28]

    7149-75-9 = 88-53-9
    反应条件:1.1 Reagents: Sulfuric Acid Solvents: 1,2-Dichlorobenzene,Water; Rt; 10 Min1.2 Reagents: Ferrous Sulfate; 8 H,180 - 185 °C1.3 Reagents: Sodium Hydroxide Solvents: Water; Ph 8 - 9
    标题:Process For Preparation Of 6-Chloro-3-Aminotoluene-4-Sulfonic Acid From 2-Chlorotoluene
    参考文献:China]

    7149-75-9 = 88-53-9
    反应条件:1.1 Reagents: Sulfuric Acid Catalysts: Ferrous Ammonium Sulfate Solvents: Water
    标题:Synthesis Of Aminochlorotoluenesulfonic Acid Using O-Chlorotoluene
    参考文献:China
3-氯-4-甲基苯磺酸 反应生成 2-氨基-5-氯-4-甲基苯磺酸
参考文献:De145908
标题:De145908

海关参考信息

专利信息


专利号:US-4719053-A
优先权日:1980-08-01
标题 :Beta-chloroethylsulfonylmethyl-benzoic halides as intermediates
发明人:SCHLAEFER LUDWIG; HAEHNLE REINHARD
权利人:HOECHST AG
摘要:New beta -chloroethylsuflonylmethyl-benzoic acid halides which can serve as fibre-reactive anchors for thesynthesis of novel organic, water-soluble compounds, preferably dyestuffs, having fibre-reactive and fibre-finishing properties, such as preferably dyestuff properties, and containing, as a fibre-reactive group, one or two beta -chloroethylsufonylmethylbenzoic acid amide groups. For the synthesis of these novel fibre-finishing compounds, said new beta -chloroethylsulfonylmethyl-benzoic acid halide compounds are reacted with an organic, water-soluble compound having fibre-finishing properties and continuing one or two amino groups. Also precursors of the fibre-finishing, fibre-reactive compounds, containing said beta -chloroethylsulfonylmethyl-benzxoic acid amid grouping, can be employed for their synthesis. The novel fibre-finishing compounds can be applied onto suitable fibre materials, such as especially cellulose fibre material and natural or synthetic polyamide fibre materials, and fixed on these fibre materials in a manner similar to application and fixation methods usual in the technique for fibre-reactive compounds. The fibre-finished material, such as dyed material, shows very good wet fastnesses.

专利号:US-4118384-A
优先权日:1976-02-21
标题 :Process for preparation of azo dyestuffs by coupling in presence of aromatic sulphonic acid-formaldehyde reaction product
发明人:MOLLS HANS-HEINZ; SCHIWY WILLY; HORNLE REINHOLD; NEBELING REINHARD
权利人:BAYER AG
摘要:Dyestuff dispersions and dyestuff solutions free from salt or at least having a low salt content are obtained in that the diazotization is carried out with addition of free dispersing agent acid to which, after the synthesis, either no basic agents are added or basic agents are added only up to a pH value of 3. The disclosed process gives dyestuff compositions of low salt content and results in readily dispersible dyestuffs when water insoluble dyestuffs are prepared and stable solutions when water soluble dyestuffs are prepared. The process is widely applicable and chemical constitution of the dyestuffs is conventional.

专利号:US-4035350-A
优先权日:1975-01-30
标 题:Process for the preparation of water-soluble azo dyestuffs by reacting an aromatic amine and a coupling component with alkali metal nitrite or alkyl nitrite in the absence of acid
发明人:LANDLER JOSEF; WORFEL ERHARD
权利人:HOECHST AG
摘要:A new and very advantageous Process had been found for the preparation of azo dyestuffs by diazotation and coupling in which the synthesis is carried out without the hitherto usual addition of an acid, with the proviso that at least one of the diazo and coupling components contains at least one acid group. Besides the saving of reaction material and subsequently of alkali for neutralization of the reaction medium and isolation of the dyestuff, highly concentrated solutions of the dyestuff and salt-free or practically salt-free dyestuffs can be obtained, and waste-water is no longer charged with big amounts of salts.

专利号:US-5389524-A
优先权日:1989-07-28
标 题:Method and a system for quantitatively monitoring a chemical component dissolved in a liquid medium
发明人:LARSEN BJORN E H; VINTHER ARNE; MOLLER POUL; THORSSON JORN R; SOEBERG HENRIK; SORENSEN JESPER L; LARSEN LYKKE B
权利人:KOEGE KEMISK VAERK
摘要:PCT No. PCT/DK90/00196 Sec. 371 Date Mar. 24, 1992 Sec. 102(e) Date Mar. 24, 1992 PCT Filed Jul. 30, 1990 PCT Pub. No. WO91/02254 PCT Pub. Date Feb. 21, 1991.A method and apparatus for quantitatively monitoring a chemical component dissolved in a liquid medium utilize the creation, in a measurement cell, of an interface zone between the liquid medium and an analytical reagent or reference solution. The concentration or amount of the chemical component are determined by the measurement of a value of a measurement parameter in the interface zone, and the derivation from that value of the concentration or amount of the component in comparison with a baseline or reference value measured for the reagent or reference solution alone. Matrix effects and ghosting errors are avoided. The method and apparatus can be used advantageously for on-line optimization and control of industrial, chemical and biological processes, such as chemical reactions in progress, coupling reactions for the synthesis of azo compounds, and the monitoring of in vivo or in vitro biological systems as well as for conventional analytical purposes.
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合成参考文献


摘要:MATSUI S ET AL; PROG WATER TECHNOL 7(2-4) 645 (1975)
摘要:Bräse, S.; Keck, D., Science of Synthesis, (2007) 31, 1832.
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