CAS: 97511-04-1; 3-Bromodibenzo[b,D]Thiophene

该化合物其结构特征为:由二苯硫苯核心和三点的溴替代物构成,该化合物具有包括硫磺和芳香碳环的引信环系统,有助于其独特的化学特性;该化合物一般在室内温度下是固体,可能因其纯度和特定形式而表现出多种颜色;溴原子的存在,会使其具有卤素特性,影响其再活动,溶性以及有机合成和材料科学的潜在应用. 3-Bromodibenzothophene 由于其同化系统,还可能表现出有趣的电子特性,使其有可能被用于有机电子,例如有机半导体或光电装置.此外,其含硫成分可能会产生特定的化学再生反应,允许合成化学的进一步功能化或衍生.与许多有机化合物一样,在处理该物质时,在安全防范方面应当遵守,因为它可能构成健康风险或环境危害.

英文名称3-Bromodibenzo[b,D]Thiophene
中文名称3-溴二苯并噻吩
IUPAC名称3-bromodibenzo[b,d]thiophene
其它别名3-溴二苯并噻吩3-Bromo Dibenzothiophenecas: 97511-04-1; 3-Bromodibenzothiophene
CAS编号97511-04-1
MFCD编号:MFCD11052997
EINECS号:815-535-2
分子式:C12H7BrS
分子量:263.15
产品CID: 2021826
产品分类有机原料→分子砌块→芳杂环类化合物→苯并噻吩类化合物

相似结构搜索
InChIKey: FDPBPKDNWCZVQR-UHFFFAOYSA-N
InChI=1S/C12H7BrS/c13-8-5-6-10-9-3-1-2-4-11(9)14-12(10)7-8/h1-7H…
计算化学: 氢键受体数1.0氢键供体数0.0可旋转键数0.0

MSDS等安全信息

GHS象形图
GHS符号GHS07 & GHS09;
注释: Exclamation mark & Environment
危险类别急性毒性类别4(经口)
水生慢性毒性类别1
警示词Warning(警告)
危险描述H302 |吞咽有害.
H410 |对水生生物毒性极大并具有长期持续影响.
防范说明P261-P264-P270-P271-P280-P302+P352-P304+P340-P305+P351+P338-P330-P362+P364-P403+P233-P405-P501

欧盟法规

C&L通报

上下游产品

N-(3-bromo-dibenzothiophen-2-yl)-acetamideN-(3-bromo-dibenzothiophen-2-yl)-acetamide 2-acetylamino-dibenzothiophene 3-nitrodibenzothiophenesulfoxide 3-aminodibenzothiophene 3-methyl-dibenzothiophene 3-bromo-dibenzo[b,d]thiophene 5,5-dioxide 3-hydroxydibenzothiophene 3-(2-Formyl-4-methoxyphenyl)dibenzo[b,d]thiophene

合成工艺路线路线简述

合成目标产物 3-Bromodibenzo[b,D]Thiophene 主要起始原料 Dibenzo[b,D]Thiophen-3-Amine
1832665-29-8 + 37181-39-8 = 97511-04-1
反应条件:1.1 Reagents: Cesium Carbonate,S8 Solvents: Dimethyl Sulfoxide; 2 H,100 °C
标题:Transition-Metal-Free Diarylannulated Sulfide And Selenide Construction Via Radical/anion-Mediated Sulfur-Iodine And Selenium-Iodine Exchange
作者:Wang,Ming; Fan,Qiaoling; Jiang,Xuefeng
参考文献:Organic Letters 日期:2016 卷标:18(21) 页码:5756-5759]

1593914-06-7 = 97511-04-1
反应条件:1.1 Reagents: Methanesulfonic Acid,Mixt. With Phosphorus Oxide (P2O5) Solvents: 1,2-Dichloroethane; Rt -> 80 °C; 6 H,80 °C1.2 Reagents: Triethylamine Solvents: Water; Ph 7 - 8,Cooled
标题:Preparation Method Of 3-Substituted Dibenzothiophene And Its Application In Organic Light Emitting Device
参考文献:China]

2007912-59-4 = 97511-04-1
反应条件:1.1 Reagents: Trifluoromethanesulfonic Acid; 24 H,Rt1.2 Reagents: Pyridine Solvents: Water; Rt; 30 Min,Reflux
标题:Preparation Of Aromatic Heterocyclic Compounds For Organic Electric Device And Electronic Apparatus
参考文献:Korea]

132-65-0 = 97511-04-1
反应条件:1.1 Reagents: Bromine Catalysts: Iodine Solvents: Chloroform; Cooled; 2 H,Cooled; 2 H,Rt1.2 Reagents: Sodium Bisulfite
标题:Blue-Light Conjugated Polymer Luminescent Material Based On Bisthioxoindole Carbazole Unit And Preparation Method And Application Thereof
参考文献:China]

2242833-25-4 = 97511-04-1
反应条件:1.1 Catalysts: Palladium Chloride Solvents: Dimethyl Sulfoxide; 8 H,140 °C
标题:Synthesis Of Substituted Dibenzothiophene Compound
参考文献:China]

25288-76-0 = 97511-04-1
反应条件:1.1 Reagents: Sodium Nitrite,Sulfuric Acid Solvents: Acetic Acid,Water; 2 °C; 100 Min,5 - 8 °C; 8 °C -> -5 °C1.2 Reagents: Diethyl Ether; 25 Min,-5 °C
标题:Compound Having Phenylacetylene Structure,Liquid Crystal Composition,Polymer,Optically Anisotropic Product,Optical Or Liquid Crystal Element,Dibenzothiophene Compound,Intermediate,And Process For Producing The Same
参考文献:United States]

= 97511-04-1 [标题:Reaction Conditions
标题:Photocatalytic Defluorocarboxylation Using Formate Salts As Both A Reductant And A Carbon Dioxide Source
作者:Min,Shi-Yun; Song,He-Xin; Yan,Si-Shun; Yuan,Rong; Ye,Jian-Heng; Et Al
参考文献:Green Chemistry 日期:2023 卷标:25(16) 页码:6194-6199]

= 97511-04-1 [标题:Reaction Conditions
标题:Preparation Of Spiro Compound For Organic Electric Element And Electronic Device
参考文献:Korea]

1832665-29-8 + 37181-39-8 = 97511-04-1
反应条件:1.1 Reagents: Cesium Carbonate,S8 Solvents: Dimethyl Sulfoxide; 2 H,100 °C; 100 °C -> Rt1.2 Reagents: Water
标题:Diaryl Episulfide And Diaryl Episelenide,And Their Synthesis Method From Periodate Salt,And Application As Photoelectric Materials
参考文献:China]

2242833-25-4 = 97511-04-1
反应条件:1.1 Catalysts: Palladium Chloride Solvents: Dimethyl Sulfoxide; 12 H,140 °C
标题:Cyclization Of 2-Biphenylthiols To Dibenzothiophenes Under Pdcl2/dmso Catalysis
作者:Zhang,Tao; Deng,Guigang; Li,Hanjie; Liu,Bingxin; Tan,Qitao; Et Al
参考文献:Organic Letters 日期:2018 卷标:20(17) 页码:5439-5443]

1489811-65-5 = 97511-04-1
反应条件:1.1 Reagents: Sodium Nitrite,Hydrochloric Acid Solvents: Water; Rt -> 0 °C; < 5 °C; 30 Min,< 5 °C1.2 Reagents: Tetrafluoroboric Acid Solvents: Water; < 5 °C1.3 Reagents: Copper Oxide (Cu2O) Solvents: Water; 30 Min,Rt
标题:Preparation Of 3-Bromodibenzothiophene
参考文献:China]

14874-70-5 + 2094054-64-3 = 97511-04-1
反应条件:1.1 Catalysts: Tris(2,2′-Bipyridine)Ruthenium(2+) Bis(Hexafluorophosphate),[1,1,1-Trifluoro-N-[(Trifluoromethyl)Sulfonyl]Methanesulfonamidato-Kn](Triphenyl... Solvents: Acetonitrile; 16 H,Rt
标题:Dual Gold And Photoredox Catalyzed C-H Activation Of Arenes For Aryl-Aryl Cross Couplings
作者:Gauchot,V.; Sutherland,D. R.; Lee,A.-L.
参考文献:Chemical Science 日期:2017 卷标:8(4) 页码:2885-2889]

1832665-29-8 + 37181-39-8 = 97511-04-1
反应条件:1.1 Reagents: Tripotassium Phosphate,Potassium Thioacetate Catalysts: 1,10-Phenanthroline,Copper(Ii) Triflate Solvents: Dimethyl Sulfoxide; 6 H,80 °C
标题:Cu(Ii)-Catalyzed Sulfide Construction: Both Aryl Groups Utilization Of Intermolecular And Intramolecular Diaryliodonium Salt
作者:Wang,Ming; Wei,Jianpeng; Fan,Qiaoling; Jiang,Xuefeng
参考文献:Chemical Communications (Cambridge 日期:2017 卷标:53(20) 页码:2918-2921]

1832665-29-8 + 16722-51-3 = 97511-04-1
反应条件:1.1 Reagents: Tripotassium Phosphate,Potassium Thioacetate Catalysts: 1,10-Phenanthroline,Copper(Ii) Triflate Solvents: Dimethyl Sulfoxide; 6 H,80 °C
标题:A Process For Preparing Diaryl Thioethers
参考文献:China]

116668-69-0 = 97511-04-1 [标题:Reaction Conditions
标题:Product Class 6: Dibenzothiophenes
作者:Andrews,M. D.
参考文献:Science Of Synthesis 日期:2001 卷标:10 页码:211-263]

25288-76-0 = 97511-04-1
反应条件:1.1 Reagents: Nitrosylsulfuric Acid,Copper Bromide (Cubr),Hydrogen Bromide
标题:Synthesis Of Monoamino And Monohydroxydibenzothiophenes
作者:Kudo,Hirotaka; Castle,Raymond N.; Lee,Milton L.
参考文献:Journal Of Heterocyclic Chemistry 日期:1985 卷标:22(1) 页码:215-18]

= 97511-04-1 [标题:Reaction Conditions
标题:Preparation Of Fused-Heterocyclic Compounds,And Organic Electric Elements Using Them And Electronic Devices Thereof
参考文献:Korea]

= 97511-04-1 [标题:Reaction Conditions
标题:Preparation Of Tertiary Amines
参考文献:China

二苯并噻吩置于盐酸,四氯化碳,硫酸,水,硝酸,氯,Tin(Ll) Chloride,Sodium Nitrite体系中,用水,溶剂黄146 作为反应溶剂,化学反应 10.67H,反应生成 3-溴二苯并噻吩
参考文献:一种三芳胺衍生物及其有机电致发光器件
标题:一种三芳胺衍生物及其有机电致发光器件
摘要:本发明公开了一种三芳胺衍生物及其有机电致发光器件,涉及有机光电材料技术领域.本发明的三芳胺衍生物的共轭体系较大,因此具有较高的空穴迁移率,表现出较好的空穴传输性能,另外本发明的三芳胺衍生物还具有较好的热稳定性和溶解性,有利于材料成膜.本发明的有机电致发光器件包括阴极,阳极以及一个或多个有机物层,有机物层位于阴极和阳极之间,有机物层中的至少一层含有本发明的三芳胺衍生物,本发明的有机电致发光器件,具有较低的驱动电压,较高的发光效率和发光亮度,并且具有较长的使用寿命.

专利信息

专利号:EP-0444889-A1
优先权日:1990-02-26
标题:Novel synthesis of carbapenem intermediates
发明人：RANO THOMAS A; GREENLEE MARK L; DININNO FRANK P
权利人:MERCK & CO INC
摘要:Carbapenems having the formula: are prepared by a novel reaction of a readily accessible carbapenem intermediate and an organostannane. The reaction, which is mediated by a palladium compound and, optionally, a phosphine ligand, proceeds at remarkably mild temperatures in reproducibly good yields.

专利号:CA-2036960-A1
优先权日:1990-02-26
标题 :Novel synthesis of carbapenem intermediates