对氟甲苯置于chromium(Vi) Oxide,硫酸,硝酸,乙酸酐体系中,化学反应生成4-氟-2-硝基苯甲醛 参考文献:Bentov,M. Et Al.,Journal Of The Chemical Society,1962,P. 2825-2827 标题:Bentov,M. Et Al.,Journal Of The Chemical Society,1962,P. 2825-2827
专利号:US-11040939-B1 优先权日:2020-06-23 标 题 :N-transfer reagent and method for preparing the same and its application 发明人:CHOU HO-HSUAN; LU GUAN-HAN; HSUEH HSIAO-CHIN; HUANG TZU-CHIA 权利人:UNIV NAT CHENG KUNG 摘要:Provided are a novel N-transfer reagent and a method for preparing the same and its application. The N-transfer reagent is represented by the following Formula (I): n n n n n n n n n n The various novel N-transfer reagents of the present invention can be quickly prepared by employing different nitrobenzene precursors. The N-transfer reagents can directly convert a variety of amino compounds into diazo compounds under mild conditions. Particularly, the N-transfer reagents can facilitate the synthesis of the diazo compounds. The application of synthesizing diazo compounds of the present invention can greatly decrease the difficulty in operation, increase the safety during experiments, reduce the cost of production and the environmental pollution, and enhance the industrial value of diazo compounds.
摘要:U.S. Army Armament Research & Development Command, Chemical Systems Laboratory, NIOSH Exchange Chemicals., NX#03510 摘要:Das, A.; Sarmah, B. K., Science of Synthesis: Knowledge Updates, (2024) 1, 306.