CAS: 49669-13-8; 2-Acetyl-6-Bromopyridine

上下游产品

2,6-Dibromopyridine N,N-dimethyl acetamide 6-bromopyridin-2-carbonitrile methylmagnesium bromide 2‐bromo‐6‐(2‐methyl‐1,3‐dioxolan‐2‐yl)pyridine (+/-)-1-[2-(6-bromopyridyl)]ethanol 6-bromo-5'-methyl-2,2'-bipyridine methyl(2-phenylpyridin-6-yl)-methanone

2,6-二溴吡啶,N,N-二甲基乙酰胺置于正丁基锂体系中,用 乙醚 作为反应溶剂,化学反应 17.5H,以74.62%的收率获得产物2-乙酰基-6-溴吡啶
参考文献:含吡唑和吡啶基的三齿配体的环金属化pt(II)和pd(II)配合物的合成和物理性质研究
标题:含吡唑和吡啶基的三齿配体的环金属化pt(II)和pd(II)配合物的合成和物理性质研究
摘要:摘要成功合成了含有一系列吡唑和吡啶基团作为供体的新型取代三齿配体,并成功合成了它们的环金属化配合物.配体和配合物已通过多种技术进行了全面表征,例如1H NMR,Uv-Vis,Ft-Ir,质谱和元素分析.同时,通过x射线晶体学测定了配体7和配合物11的单晶结构.对于配体7,由于离域作用,吡唑环中的c(6)-C(7)键长比正常的cc键短0.05A.与金属中心配位后,构型受到配位球的限制,因此配合物11的键长和键角与配体7的键长和键角不同.对于配合物9和10,发现在500至600 Nm之间有两个发射带.此外,对于配体7和8,有几个吸收带分别位于240至250 Nm和300至310 Nm(π(l)->π*(L)和n->π*(l)).比较配体上具有给电子和吸电子基团的配合物时,在紫外光谱中观测到红移,这是由于取代基的电子作用所致.对于络合物9和10,在375至425Nm处还发现一个吸收带,该吸收带归因
DOI:10.1016/j.Poly.2020.114799

专利信息

专利号:US-5539117-A
优先权日:1993-04-13
标题:2-acetyl-6-cyanopyridines and their use as intermediates in the synthesis of oligo-2,6-pyridines
发明人：SNOW ROBERT A; DELECKI DANIEL J; SHAH CHANDRA R; HOLLISTER K ROBERT
摘要:The present invention is directed to 2-acetyl-6-cyanopyridine compounds that are useful as intermediates in the synthesis of oligo-2,6-pyridines. The present invention is also directed to new, simpler, less expensive methods for synthesizing such oligopyridines using the novel 2-acetyl-6-cyanopyridine compounds as intermediates.

专利号:US-2003100119-A1
优先权日:1994-10-18
标题:Combinatorial synthesis and screening of supported organometallic compounds and catalysts
发明人：WEINBERG W HENRY; MCFARLAND ERIC; GOLDWASSER ISY; BOUSSIE THOMAS; TURNER HOWARD; BEEK JOHANNES A M VAN; MURPHY VINCE; POWERS TIM
权利人:SYMYX TECHNOLOGIES INC
摘要:The present invention relates, inter alia, to methodologies for the synthesis, screening and characterization of organometallic compounds and catalysts (e.g., homogeneous catalysts). The methods of the present invention provide for the combinatorial synthesis, screening and characterization of libraries of supported and unsupported organometallic compounds and catalysts (e.g., homogeneous catalysts). The methods of the present invention can be applied to the preparation and screening of large numbers of organometallic compounds which can be used not only as catalysts (e.g., homogeneous catalysts), but also as additives and therapeutic agents.

专利号:WO-9803521-A1
优先权日:1996-07-23
标题 :Combinatorial synthesis and analysis of organometallic compounds and catalysts
发明人：WEINBERG W HENRY; MCFARLAND ERIC; GOLDWASSER ISY; BOUSSIE THOMAS; TURNER HOWARD; VAN BEEK JOHANNES A M; MURPHY VINCE; POWERS TIMOTHY
权利人:SYMYX TECHNOLOGIES INC; WEINBERG W HENRY; MCFARLAND ERIC; GOLDWASSER ISY; BOUSSIE THOMAS; TURNER HOWARD; BEEK JOHANNES A M VAN; MURPHY VINCE; POWERS TIMOTHY
摘要:The present invention relates, inter alia, to methodologies for the synthesis, screening and characterization of organometallic compounds and catalysts (e.g., homogeneous catalysts). The methods of the present invention provide for the combinatorial synthesis, screening and characterization of libraries of supported and unsupported organometallic compounds and catalysts (e.g., homogeneous catalysts). The methods of the present invention can be applied to the preparation and screening of large numbers of organometallic compounds which can be used not only as catalysts (e.g., homogeneous catalysts), but also as additives and therapeutic agents.

专利号:US-6756195-B2
优先权日:1996-07-23
标题 :Polymerization method from the combinatorial synthesis and analysis of organometallic compounds and catalysts
发明人：WEINBERG W HENRY; MCFARLAND ERIC; GOLDWASSER ISY; BOUSSIE THOMAS; TURNER HOWARD; BEEK JOHANNES A M VAN; MURPHY VINCE; POWERS TIMOTHY
权利人:SYMYX TECHNOLOGIES INC
摘要:The present invention relates, inter alia, to methodologies for the synthesis, screening and characterization of organometallic compounds and catalysts (e.g., homogeneous catalysts). The methods of the present invention provide for the combinatorial synthesis, screening and characterization of libraries of supported and unsupported organometallic compounds and catalysts (e.g., homogeneous catalysts). The methods of the present invention can be applied to the preparation and screening of large numbers of organometallic compounds which can be used not only as catalysts (e.g., homogeneous catalysts), but also as additives and therapeutic agents.

专利号:US-6440745-B1
优先权日:1994-10-18
标 题 :Combinatorial synthesis and screening of organometallic compounds and catalysts
发明人：WEINBERG W HENRY; MCFARLAND ERIC W; GOLDWASSER ISY; BOUSSIE THOMAS; TURNER HOWARD; BEEK JOHANNES A M VAN; MURPHY VINCE; POWERS TIM
权利人:SYMYX TECHNOLOGIES INC
摘要:The present invention relates, inter alia, to methodologies for the synthesis, screening and characterization of organometallic compounds and catalysts (e.g., homogeneous catalysts). The methods of the present invention provide for the combinatorial synthesis, screening and characterization of libraries of supported and unsupported organometallic compounds and catalysts (e.g., homogeneous catalysts). The methods of the present invention can be applied to the preparation and screening of large numbers of organometallic compounds which can be used not only as catalysts (e.g., homogeneous catalysts), but also as additives and therapeutic agents.

专利号:EP-0985678-B1
优先权日:1996-07-23
标题:Combinatorial synthesis and analysis of organometallic compounds and catalysts
发明人：WEINBERG HENRY W; MCFARLAND ERIC; GOLDWASSER ISY; BOUSSIE THOMAS; TURNER HOWARD; BEEK JOHANNES A M VAN; MURPHY VINCE; POWERS TIMOTHY
权利人:SYMYX TECHNOLOGIES INC
摘要:Methodologies for the synthesis, screening and characterisation of organometallic compounds and catalysts (eg homogenous catalysts), including combinatorial synthesis, screening and characterisation of libraries of supported and unsupported organometallic compounds and catalysts (eg homogenous catalysts). The methods can be applied to the preparation and screening of large numbers of organometallic compounds which can be used not only as catalysts (eg homogeneous catalysts), but also as additives and therapeutic agents.