N,N,O-三乙酰基-2-氨基苯酚置于溶剂黄146体系中,化学反应 3.0H,以87%的收率获得产物2-氨基苯酚-N,O-二乙酸酯
参考文献:Reexamination Of The Thermolytic Rearrangement Of 4-Halophenyl Azides To 2-Aminophenols And Other Products
标题:Reexamination Of The Thermolytic Rearrangement Of 4-Halophenyl Azides To 2-Aminophenols And Other Products
摘要:The Halogenation Of Derivatives Of 2-Aminophenol With N-Chloro-And N-Bromosuccinimides At Ambient Temperatures In Acetic Acid Was Studied. With The Necessary Compounds Available,A Reexamination Of The Thermolytic Rearrangement Of 2-Halophenyl Azides To 2-Aminophenols And Other Products Was Undertaken. It Is Certain That The Rearrangement Of 4-Halophenyl Azides To 2-Aminophenols occurs But The Products Identified In This Study Differ Significantly From Those Reported Previously By Suschitzky Et Al. (1963,1966).
DOI:10.1007/bf00814133