专利号:US-4629807-A 优先权日:1986-02-06 标 题 :Selective synthesis of aliphatic dicarboxylic acid esters using palladium-phosphine or palladium-arsine catalysts 发明人:KNIFTON JOHN F 权利人:TEXACO INC 摘要:A process for preparing aliphatic dicarboxylic acid esters from aliphatic, non-conjugated dienes via carbonylation in the presence of a homogeneous palladium-phosphine catalyst or a palladium-phosphine melt catalyst.
专利号:US-4270015-A 优先权日:1979-02-05 标题:Manufacture of ethylene from synthesis gas (D#75,673-C1) 发明人:KNIFTON JOHN F 权利人:TEXACO INC 摘要:This invention concerns a two-step process for the preparation of ethylene from mixture of carbon monoxide and hydrogen (commonly known as synthesis gas) by reaction of said carbon monoxide/hydrogen mixtures with a carboxylic acid in the presence of one or more ruthenium catalyst complexes to form an ethyl ester of said carboxylic acid coreactant, followed by pyrolysis of said ethyl ester intermediate to ethylene.
专利号:US-4451680-A 优先权日:1982-10-21 标题:Alcohols prepared from olefins and synthesis gas 发明人:KNIFTON JOHN F 权利人:TEXACO INC 摘要:This invention concerns a process of preparing predominantly linear alcohols which comprises the steps of contacting a mixture of terminal and/or internal olefins and synthesis gas with a catalyst system comprising a ruthenium-containing compound coupled with one or more bidentate or multidentate, phosphine-containing promoters, dispersed in a low melting quaternary phosphonium salt, and heating said resultant reaction mixture under a pressure of 100 psi or greater at a temperature of at least 50 DEG C. for a sufficient time to produce said alcohols.
专利号:US-4451679-A 优先权日:1982-10-21 标题 :Alcohols and aldehydes prepared from olefins and synthesis gas 发明人:KNIFTON JOHN F; LIN JIANG-JEN; GRIGSBY JR ROBERT A; BRADER JR WALTER H 权利人:TEXACO INC 摘要:This invention concerns a process of preparing alcohols and aldehydes which comprises the steps of contacting a mixture of terminal and/or internal olefins and synthesis gas with a catalyst system comprising a ruthenium-containing compound dispersed in a low melting quaternary phosphonium or ammonium base or salt and heating said resultant reaction mixture under a pressure of 100 psi or greater at a temperature of at least 50 DEG C. for a sufficient time to produce said alcohols and aldehydes.
专利号:US-4469895-A 优先权日:1982-10-21 标题 :Process for preparing alcohols from olefins and synthesis gas 发明人:KNIFTON JOHN F; GRIGSBY JR ROBERT A 权利人:TEXACO INC 摘要:This invention concerns an improved process of preparing predominantly linear alcohols which comprises the steps of contacting a mixture of terminal and/or internal olefins and synthesis gas with a catalyst system comprising a ruthenium-containing compound in conjunction with one or more tertiary amine promoters, dispersed in a low melting quaternary phosphonium salt and heating said resultant reaction mixture under a pressure of 100 psi or greater at a temperature of at least 50 DEG C. for a sufficient time to produce said alcohols.
专利号:US-9809519-B1 优先权日:2016-05-26 标 题 :Oxygenate synthesis and homologation 发明人:LOTZ MONICA D; KEUSENKOTHEN PAUL F; SALCICCIOLI MICHAEL 权利人:EXXONMOBIL CHEMICAL PATENTS INC 摘要:The invention relates to processes for oxygenate synthesis and homologation, to equipment and materials useful in such processes, and to the use of such oxygenate for producing olefin and polyolefin.