CAS: 25152-85-6; (Z)-Hex-3-En-1-Yl Benzoate

相似化合物

928-96-1 928-97-2 25152-85-6

上下游产品

CAS号928-96-1 叶醇 | CAS号94-36-0 过氧化苯甲酰 | CAS号93-97-0 苯甲酸酐 | CAS号98-88-4 苯甲酰氯 | CAS号1711-02-0 4-碘苯甲酰氯

4-Iodo-Benzoic Acid (Z)-Hex-3-Enyl Ester置于palladium On Activated Charcoal 氢气,三乙胺体系中,用 甲醇 用作溶剂,20.0 °C,101.33 Kpa 条件下,反应 4.0H,反应生成顺式-3-己烯醇苯甲酸酯
参考文献:Consequences Of Affinity In Heterogeneous Catalytic Reactions: Highly Chemoselective Hydrogenolysis Of Iodoarenes
标题:Consequences Of Affinity In Heterogeneous Catalytic Reactions: Highly Chemoselective Hydrogenolysis Of Iodoarenes
摘要:The Catalytic Hydrodeibdination Reaction Using Molecular Hydrogen And Pd/c Has Been Revisited. It Is Shown,For The First Time,That The Chemoselectivity Of This Reaction Is Controlled By The High Affinity Of The Iodinated Compound For The Catalyst. This Reaction Is Compatible With Most Easily Reducible Functional Groups (Nitro,Aldehyde,Olefin,Etc:). Using This Reaction,The First General Method For Tritium Labeling Of 3-(Triflubromethyl)-3-Phenyldiazirine Is Described.
Doi:10.1021/jo0012243

专利信息

专利号:US-9988349-B2
优先权日:2014-01-03
标 题:Direct stereospecific synthesis of unprotected aziridines from olefins
发明人：ESS DANIEL HALSELL; FALCK JOHN RUSSELL; JAT JAWAHAR LAL; KURTI LASZLO
权利人:ESS DANIEL HALSELL; FALCK JOHN RUSSELL; JAT JAWAHAR LAL; KURTI LASZLO
摘要:A method for the direct stereospecific conversion of structurally diverse mono-, di-, tri- and tetra-substituted olefins to N—H, N-alkyl, N-cycloalkyl, or N-aralkyl aziridines using a hydroxylamine amination agent with transition metal catalyst. The method is operationally simple (i.e., one-pot), scalable and fast at ambient temperature.

专利号:US-2016340305-A1
优先权日:2014-01-03
标题 :Direct stereospecific synthesis of unprotected aziridines from olefins

专利号:WO-2015103505-A2
优先权日:2014-01-03
标 题:Direct stereospecific synthesis of unprotected aziridines from olefins