CAS: 645-92-1; 4,6-Diamino-1,3,5-Triazin-2-Ol

该化合物是一种有机化合物,被归类为三聚氰胺的衍生物,化学配方C3H6N6O.这是一种白色晶状固体,在水中可溶解,并展示出一系列有趣的化学特性.Ammeline由于存在多种氨基和非尼诺组,因此有能力形成氢结,这有助于其在各个领域,包括材料科学和医药等领域的回作用和潜在应用.该化合物主要因其在合成其他含氮化合物中的作用及其作为树脂和涂层生产前体的潜在用途而受到研究.此外,Ammeline可以进行各种化学反应,例如硝化和氧化,使其成为有机合成的多功能建筑块.安全数据表明,与许多氮富含化合物一样,应谨慎处理氢结结结,因为接触时可能会对健康造成危害.

结构式图片

欧盟法规

ECHA物质C&L通报REACH预注册

上下游产品

Melam 2,4,6-triethoxy-[1,3,5]triazine guanidine; formate BIGUANIDEammelide cyanuric acid H-[1,3,5]triazin-2-one4,6-dihydrazino-1H-[1,3,5]triazin-2-one ammonia

合成工艺路线路线简述

    Alkaline Earth Salt Of/the/ Methylsulfuric Acid置于乙醇,氨体系中,化学反应生成 4,6-二氨基-2-羟基-1,3,5-三嗪
    参考文献:Weddige,Journal Fur Praktische Chemie (Leipzig 1954),1886,Vol. <2> 33,P. 81
    标题:Weddige,Journal Fur Praktische Chemie (Leipzig 1954),1886,Vol. <2> 33,P. 81

    专利信息


    专利号:US-5202438-A
    优先权日:1991-04-04
    标 题 :Process for the synthesis of melamine cyanurate
    发明人:PAUL JEAN-MICHEL
    权利人:ATOCHEM ELF SA
    摘要:For the synthesis of melamine cyanurate, by the reaction of cyanuric acid and melamine in an aqueous medium, the reaction is conducted in the presence of a strong mineral acid at a pH not above 1.

    专利号:US-12391655-B1
    优先权日:2022-10-07
    标 题:Melamine process with a two-stage purification of melamine offgas
    发明人:GAMBA SIMONE
    权利人:CASALE SA
    摘要:A process for the synthesis of melamine including the purification of the offgas released by the synthesis of melamine by means of a first purification stage followed by a second purification stage (7); in the first purification stage (6) the offgas (3) is contacted with urea melt from the second stage (7) and with a recirculated urea melt (8, 9) containing ammonia and melamine precursors (5); in the second purification stage (7) the offgas from the first stage is contacted with fresh urea melt (15); said recirculated urea melt is withdrawn from bottom of the first stage and cooled in a shell and tube heat exchanger (11) to a temperature of not less than 165° C. preferably in the range 165° C. to 245° C. prior to reintroduction in said first stage.

    专利号:WO-2024240658-A1
    优先权日:2023-05-25
    标 题:Melamine process with urea melt-based washing of melamine offgas
    发明人:DI CARLO GABRIELE; CIPOLLA MAURIZIO; GAMBA SIMONE
    权利人:CASALE SA
    摘要:A process for the synthesis of melamine from urea wherein offgas from the melamine synthesis reaction is washed in a scrubber with urea melt, the urea melt removed from the scrubber is sent to a urea melt pump and partly recirculated to the scrubber, said urea melt pump includes a dual seal pressurized with water.

    专利号:WO-2024083571-A1
    优先权日:2022-10-21
    标题 :Melamine process with purification of melamine offgas
    发明人:GAMBA SIMONE
    权利人:CASALE SA
    摘要:A process for the synthesis of melamine including the purification of the offgas released by the synthesis of melamine by means of a single purification stage (6); in the purification stage (6), the offgas (3) is washed with fresh urea melt and with a recirculated urea melt (8) containing ammonia and melamine precursors (5); said recirculated urea melt is withdrawn from bottom of the single purification stage (6) and cooled in a shell and tube heat exchanger (11), optionally after mixing with the fresh urea melt (15), to a temperature of at least 165 °C, preferably in the range 165 °C to 245 °C, prior to reintroduction in the purification stage.

    专利号:US-4725684-A
    优先权日:1987-04-02
    标 题:Synthesis of urea cyanurate
    发明人:MASON ROBERT W; PARKER THOMAS C
    权利人:OLIN CORP
    摘要:A process for producing urea cyanurate which comprises reacting an aqueous solution of urea with cyanuric acid at a temperature below the melting point of urea provides reaction conditions which minimize urea decomposition and are energy efficient. The urea cyanurate product can be used directly in the manufacture of cyanuric acid in a process which minimizes the build up of scale on the reactor walls. The cyanuric acid product has reduced concentrations of by-products such as ammelide and ammeline.

    专利号:US-8894886-B1
    优先权日:2010-03-05
    标 题 :Reductive-expansion synthesis of graphene
    发明人:LUHRS CLAUDIA CATALINA; PHILLIPS JONATHAN
    权利人:LUHRS CLAUDIA CATALINA; PHILLIPS JONATHAN; STC UNM
    摘要:Exemplary embodiments provide materials and methods for forming graphene-based exfoliated products with low oxygen contents by a reductive-expansion reaction from a physical mixture containing graphite-based precursor(s) and a chemical agent. Exemplary embodiments also provide materials and methods for forming graphene-based exfoliated products with controllable amounts of nitrogen and/or other impurities incorporated in the material structure as a result of a reductive-expansion reaction from a physical mixture containing graphite-based precursor(s) and a chemical agent.
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    主要参考文献

    参考标题:Studies Of Cyanamide Derivatives. Part 110. A Facile Synthesis Of 2,4,6-Triureido-1,3,5-Triazine And 2-Amino-4,6-Diureido-1,3,5-Triazine
    作者:Kokoro Iio,Eiichi Ichikawai |发布日期:1984.7
    摘要:2,4,6-Triureido-1,3,5-Triazine And 2-Amino-4,6-Diureido-1,3,5-Triazine Were Readily Synthesized In High Yields, 94 And 85% Respectively, By The Alcoholysis Of 2,4,6-Tris(Cyanoamino)-1,3,5-Triazine And 2-Amino-4,6-Bis(Cyanoamino)-1,3,5-Triazine In The Presence Of Hydrogen Chloride.

    合成参考文献


    参考文献:10.1093/toxsci/kfr176
    摘要:Simpkins JW, Swenberg JA, Weiss N, Brusick D, Eldridge JC, Stevens JT, Handa RJ, Hovey RC, Plant TM, Pastoor TP, Breckenridge CB. Atrazine and breast cancer: a framework assessment of the toxicological and epidemiological evidence. Toxicol Sci. 2011 Oct;123(2):441–59.
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