CAS: 92-06-8; M-Terphenyl

• 英文名称M-Terphenyl
• 中文名称间三联苯
• IUPAC名称1,1':3',1''-terphenyl
• 其它别名m-Diphenylbenzene; m-Terphenyl
• CAS编号92-06-8
• MFCD编号:MFCD00003059
• EINECS号:202-122-1
• 分子式:C18H14
• 分子量:230.31
• 产品CID: 2455224
• 产品分类有机原料→分子砌块→芳环类化合物→苯类化合物

• 相似结构搜索
• 产品信息参考
• InChIKey: YJTKZCDBKVTVBY-UHFFFAOYSA-N
• InChI=1S/C18H14/c1-3-8-15(9-4-1)17-12-7-13-18(14-17)16-10-5-2-6-11-16/h1-14H…
• 计算化学: 氢键受体数0.0氢键供体数0.0可旋转键数2.0

物理性质

• 熔点84-88°C
• 沸点379  °C(文献)
• 闪点191 °C
• 密度1,2 g/cm3
• PSA:0.0
• LogP:5.0206
• 折射率1.5681 (估算)
• 蒸汽压0.01 mm Hg at 200 °F (NIOSH, 2016)
• 溶解性Water solubility = 1.51 mg/l at 25 °C
• 外观形态黄色固体
• 储存条件Store at room temperature
• 产品应用该化合物用于电子设备,润滑油,密封剂和其他装置,也是一种全球环境污染物.
• 性质描述熔点84-88°C,沸点379°C,密度1,2g/cm3,闪点191°C

MSDS等安全信息

• GHS象形图
• GHS符号GHS07 & GHS09;
  注释: Exclamation mark & Environment
• 危险类别特定目标器官毒性 - 单次接触 类别3
  皮肤腐蚀/刺激 类别2
  严重眼刺激 类别2
  水生急性毒性 类别1
  水生慢性毒性 类别1
• 警示词Warning(警告)
• 危险描述H335 |可能引起呼吸道刺激.
  H315 |造成皮肤刺激.
  H319 |造成严重眼刺激.
  H400 |对水生生物毒性极大.
  H410 |对水生生物毒性极大并具有长期持续影响.
• 防范说明P260-P261-P264-P270-P271-P273-P280-P302+P352-P304+P340-P362+P364-P391-P405-P501
• 危险等级9
• UN编号3077.0
• 危险品标志Xi:Irritant;
• 包装等级Ⅲ
• 安全声明S26-S36-S61-S60
• 危险类别码R36/37/38
• WGK Germany2

欧盟法规

上下游产品

合成工艺路线路线简述

• 合成目标产物 1,3-Diphenylbenzene 主要起始原料 1,3-Diiodobenzene And Phenylboronic Acid
• 98-80-6 + 108-36-1 = 92-06-8
  反应条件:1.1 Reagents: Tripotassium Phosphate,Oxygen Catalysts: (Sp-4-3)-[2,6-Bis[(Di-1-Piperidinylphosphino-Kp)Amino]Phenyl-Kc]Chloropalladium Solvents: Toluene; 10 Min,100 °C
  标题:Aminophosphine Palladium Pincer Complexes For Suzuki And Heck Reactions
  作者:Bolliger,Jeanne L.; Frech,Christian M.
  参考文献:Chimia 日期:2009 卷标:63(1-2) 页码:23-28]
  
  5122-95-2 + 37181-39-8 + 135654-48-7 = 92-06-8
  反应条件:1.1 Reagents: Sodium Bicarbonate Catalysts: Bis(Tri-Tert-Butylphosphine)Palladium Solvents: Dimethylformamide; 6 H,60 °C
  标题:Pd-Catalyzed Suzuki-Miyaura Cross-Coupling Of [ph2Sr][otf] With Arylboronic Acids
  作者:Wang,Xiao-Yan; Song,Hai-Xia; Wang,Shi-Meng; Yang,Jing; Qin,Hua-Li; Et Al
  参考文献:Tetrahedron 日期:2016 卷标:72(47) 页码:7606-7612]
  
  98-80-6 + 591-18-4 = 92-06-8
  反应条件:1.1 Reagents: Potassium Carbonate Catalysts: Palladium (Nanoparticle Complexes With A Tris(Polyethylene Glycolyl Triazolyl)Benzene),Poly(Oxy-1,2-Ethanediyl),α,α′,α′′-[1,3,5-Benzenetriyltris(1H-1,2,3-Triazole-4,1... (Palladium Complexes) Solvents: Acetone,Water; 3 H,60 °C; 60 °C -> Rt
  标题:Water-Soluble Palladium Nanoparticles: Click Synthesis And Applications As A Recyclable Catalyst In Suzuki Cross-Couplings In Aqueous Media
  作者:Mejias,Nereida; Pleixats,Roser; Shafir,Alexandr; Medio-Simon,Mercedes; Asensio,Gregorio
  参考文献:European Journal Of Organic Chemistry 日期:2010 卷标:(26) 页码:5090-5099]
  
  98-80-6 + 591-18-4 = 92-06-8
  反应条件:1.1 Reagents: Sodium Carbonate Catalysts: Palladium Diacetate Solvents: Dimethylformamide,Water; 18 H,60 °C
  标题:Preparation Of Polyphenyls
  参考文献:China]
  
  65844-89-5 = 92-06-8
  反应条件:1.1 Catalysts: Dichlorobis(Triphenylphosphine)Palladium Solvents: Dimethylformamide1.2 Solvents: Water1.3 Solvents: Diethyl Ether
  标题:Synthesis Of Mono-,Di-,And Triphenylarenes By Sequential Photostimulated Srn1 And Pd(0)-Catalyzed Cross Coupling Reactions On Aryl Halides
  作者:Corsico,Eduardo F.; Rossi,Roberto A.
  参考文献:Synlett 日期:2000 卷标:(2) 页码:230-232]
  
  108-36-1 = 92-06-8
  反应条件:1.1 Reagents: Potassium Carbonate,Sodium Iodide Catalysts: 2376473-55-9 Solvents: Dimethylformamide; 6 H,120 °C
  标题:Synthesis,Characterization And Theoretical Investigation On Thiazoline-Derived Palladium-Complexes-Catalyzed Denitrogenative Cross-Coupling Of Aryl Halides With Arylhydrazines
  作者:Sudharsan,Murugesan; Thirumoorthy,Krishnan; Nethaji,Munirathinam; Suresh,Devarajan
  参考文献:Chemistryselect 日期:2019 卷标:4(32) 页码:9253-9261]
  
  = 92-06-8
  反应条件:1.1 Catalysts: Grubbs Second Generation Catalyst Solvents: Dichloromethane; 2 H,Rt1.2 Catalysts: P-Toluenesulfonic Acid; 1 H,Rt
  标题:Ring-Closing Olefin Metathesis For The Synthesis Of Benzene Derivatives
  作者:Yoshida,Kazuhiro; Kawagoe,Fumihiro; Iwadate,Noriyuki; Takahashi,Hidetoshi; Imamoto,Tsuneo
  参考文献:Chemistry - An Asian Journal 日期:2006 卷标:1(4) 页码:611-613]
  
  98-80-6 + 108-36-1 = 92-06-8
  反应条件:1.1 Reagents: Cesium Carbonate Catalysts: 2135789-70-5 Solvents: Dimethylformamide; 12 H,80 °C
  标题:A Straightforward Synthesis Of 4,5-Dihalofunctionalized Imidazol-2-Ylidene/imidazolyl-Metal Complexes From Trihaloimidazolium Salts/imidazoles: Structure And Catalytic Studies
  作者:Avinash,Iruthayaraj; Gupta,Vivek; Karthik,Vedhagiri; Anantharaman,Ganapathi
  参考文献:Journal Of Organometallic Chemistry 日期:2017 卷标:851 页码:104-114]
  
  98-80-6 + 591-18-4 = 92-06-8
  反应条件:1.1 Reagents: Sodium Carbonate Catalysts: Palladium Diacetate Solvents: Dimethylformamide,Water; 12 H,60 °C
  标题:Synthesis Of Biaryls And Polyaryls By Ligand-Free Suzuki Reaction In Aqueous Phase
  作者:Liu,Leifang; Zhang,Yuhong; Xin,Bingwei
  参考文献:Journal Of Organic Chemistry 日期:2006 卷标:71(10) 页码:3994-3997]
  
  20104-40-9 = 92-06-8
  反应条件:1.1 Reagents: Lithium Solvents: Tetrahydrofuran; 24 H,Rt
  标题:Electrostatic And Electrophilic Catalysis In The Reductive Cleavage Of Alkyl Aryl Ethers. The Influence Of Ion Pairing On The Regioselectivity
  作者:Casado,Francisco; Pisano,Luisa; Farriol,Maria; Gallardo,Iluminada; Marquet,Jordi; Et Al
  参考文献:Journal Of Organic Chemistry 日期:2000 卷标:65(2) 页码:322-331]
  
  98-80-6 = 92-06-8
  反应条件:1.1 Reagents: Potassium Hydroxide Catalysts: Palladium Diacetate,2′-(Dicyclohexylphosphino)-N,N-Dimethyl[1,1′-Biphenyl]-2-Amine Solvents: Toluene; 7 - 8 H,90 °C
  标题:Buchwald Ligand-Assisted Suzuki Cross-Coupling Of Polychlorobenzenes
  作者:Vasil'Ev,Andrei A.; Burukin,Alexander S.; Zhdankina,Galina M.; Zlotin,Sergei G.
  参考文献:Mendeleev Communications 日期:2021 卷标:31(3) 页码:400-402]
  
  108-37-2 + 98-80-6 = 92-06-8
  反应条件:1.1 Reagents: Tripotassium Phosphate Catalysts: Palladium Chloride,N2,N2,N6,N6-Tetrakis[(Diphenylphosphino)Methyl]-2,6-Pyridinediamine Solvents: Dimethylacetamide; 1 H,100 °C1.2 Solvents: O-Xylene; 2 H,90 °C
  标题:N,N,N',N'-Tetra(Diphenylphosphinomethyl)Pyridine-2,6-Diamine/palladium Catalyzed Suzuki-Miyaura Coupling Of Aryl And Heteroaryl Halides
  作者:Guo,Fei-Chen; Zhou,Rong; Jiang,Zhi-Jie; Wang,Wei; Fu,Hai-Yan; Et Al
  参考文献:Catalysis Communications 日期:2015 卷标:66 页码:87-90]
  
  98-80-6 + 108-36-1 = 92-06-8
  反应条件:1.1 Reagents: Tripotassium Phosphate Catalysts: Benzene,Diethenyl-,Polymer With 1-(1,1-Dimethylethyl)-4-Ethenylbenzene,Pyridine,4-Ethenyl-,Polymer With 1-(1,1-Dimethylethyl)-4-Ethenylbenzene Solvents: Ethanol,Tetrahydrofuran,Water; 5 H,70 °C1.2 Solvents: Water
  标题:Continuous-Flow Suzuki-Miyaura Coupling In Water And Organic Solvents Promoted By Blends Of Stabilized Convoluted Polymeric Palladium Catalysts And Polymeric Auxiliary Materials
  作者:Zhang,Zhenzhong; Ohno,Aya; Takaya,Hikaru; Yamada,Yoichi M. A.
  参考文献:Chemistry - A European Journal 日期:2023 卷标:29(34)]
  
  20442-79-9 = 92-06-8
  反应条件:1.1 Reagents: Potassium Carbonate Catalysts: Palladium Solvents: Ethanol; 60 Min
  标题:The Impact Of The Physical State And The Reaction Phase In The Direct Mechanocatalytic Suzuki-Miyaura Coupling Reaction
  作者:Yoo,Kwangho; Fabig,Sven; Graetz,Sven; Borchardt,Lars
  参考文献:Faraday Discussions 日期:2023 卷标:241 页码:206-216]
  
  98-80-6 + 108-36-1 = 92-06-8
  反应条件:1.1 Reagents: Potassium Carbonate Catalysts: 2230116-04-6 (Post-Treated With Pd(Oac)2) Solvents: Ethanol; 0.5 H,80 °C
  标题:Palladium Nanoparticle-Immobilized Porous Polyurethane Material For Quick And Efficient Heterogeneous Catalysis Of Suzuki-Miyaura Cross-Coupling Reaction At Room Temperature
  作者:Dey,Sandeep Kumar; Dietrich,Dennis; Wegner,Susann; Gil-Hernandez,Beatriz; Harmalkar,Sarvesh Shyam; Et Al
  参考文献:Chemistryselect 日期:2018 卷标:3(5) 页码:1365-1370]
  
  5122-95-2 = 92-06-8
  反应条件:1.1 Reagents: Cesium Carbonate Catalysts: Palladium Solvents: Ethanol,Water; 3 H,60 °C
  标题:Phosphine-Built-In Porous Organic Cage For Stabilization And Boosting The Catalytic Performance Of Palladium Nanoparticles In Cross-Coupling Of Aryl Halides
  作者:Wang,Zhaozhan; Reddy,C. Bal; Zhou,Xin; Ibrahim,Jessica Juweriah; Yang,Yong
  参考文献:Acs Applied Materials & Interfaces 日期:2020 卷标:12(47) 页码:53141-53149]
  
  = 92-06-8
  反应条件:1.1 Catalysts: (Sp-4-3)-[2,6-Bis[(Diphenylphosphino-Kp)Amino]Phenyl-Kc]Chloronickel Solvents: Tetrahydrofuran; 18 H,40 °C; 40 °C -> Rt1.2 Solvents: Water; Rt
  标题:Arylation Of Non-Activated C-Cl Bond With Grignard Reagents Catalyzed By Pincer [pcp]-Nickel Complexes
  作者:Sun,Yunqiang; Li,Xiaoyan; Sun,Hongjian
  参考文献:Inorganica Chimica Acta 日期:2014 卷标:415 页码:95-97]
  
  98-80-6 + 108-36-1 = 92-06-8
  反应条件:1.1 Reagents: Sodium Carbonate Catalysts: Tetraamminedichloropalladium(2+) Solvents: Dimethylacetamide,Water; 15 Min,100 °C
  标题:Pd-Loaded Nay Zeolite As A Highly Active Catalyst For Ligandless Suzuki-Miyaura Reactions Of Aryl Halides At Low Pd Loadings Under Aerobic Conditions
  作者:Durgun,Gulay; Aksin,Ozge; Artok,Levent
  参考文献:Journal Of Molecular Catalysis A: Chemical 日期:2007 卷标:278(1-2) 页码:189-199]
  
  = 92-06-8
  反应条件:1.1 Reagents: 1,8-Diazabicyclo[5.4.0]Undec-7-Ene Solvents: Ethyl Acetate; Rt
  标题:Assembly Of Unsymmetrical 1,3,5-Triarylbenzenes Via Tandem Reaction Of β-Arylethenesulfonyl Fluorides And α-Cyano-β-Methylenones
  作者:Zhang,Fang; An,Yi; Liu,Jichang; Du,Guangfen; Cai,Zhihua; Et Al
  参考文献:New Journal Of Chemistry 日期:2022 卷标:46(25) 页码:12367-12371

海关参考信息

• 2902200000-苯
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• 详情请参考：📖 海关编码查询和海关进出口税则

其他信息查阅

• ➥ 象形图和危险代码
• ➥ 防范代码详解
• ➥ 危险代码说明
• ➥ Globally Harmonized System
• ➥ REACH监管