CAS: 1185-81-5; Dibutyl-Bis(Dodecylsulfanyl)Stannane

该化合物是一种有机锡化合物,其独特结构包括两个丁基化合物和两个多德基锡化合物组,这些有机锡化合物与中锡原子相连,通常是室温粘稠液体,由于长的多德基链会提高非极溶剂的溶解性,因此其疏水特性为人所知.它经常用于各种用途,包括作为聚合物配方的稳定剂和有机合成的催化剂.锡在结构中的存在具有特定的再活性,使其在化学和材料科学的协调方面有用.然而,有机锡化合物由于在水生系统中的潜在毒性和生物累积性,受环境条例的约束.在处理该物质时,安全防范至关重要,因为它可能因吸入或皮肤接触而造成健康风险.

结构式图片

欧盟法规

《欧盟PIC法规》REACH注册ECHA物质ECHA物质OtherC&L通报REACH预注册

上下游产品

dibutyltin chloride 1-dodecylthioltetra-n-butyltin(IV)

合成工艺路线路线简述

    二正丁基氧化锡,十二硫醇 以 水 用作溶剂,化学反应生成二(十二烷硫基)二丁基锡
    参考文献:Compositions And Electrodes Comprising Organotin Ionophores
    标题:Compositions And Electrodes Comprising Organotin Ionophores
    摘要:本发明揭示了一种离子敏感组合物和离子选择性电极,其中离子载体是具有以下式子的有机锡化合物:R.Sub.X.Sup.1 Sn(Sr.Sup.2).Sub.4-X或r.Sub.Y.Sup.1 Sn(Sr.Sup.3--X--R.Sup.3 S).Sub.4-Y Snr.Sup.1,其中x为0或1至3的整数;Y为2或3;每个r.Sup.1独立地是取代或未取代的烷基或取代或未取代的芳基;每个r.Sup.2独立地是取代或未取代的烷基;每个r.Sup.3独立地是取代或未取代的亚烷基;而x是单一化学键或连接基.

    海关参考信息

    专利信息


    专利号:US-4054592-A
    优先权日:1974-02-04
    标题 :Urethanes containing two perfluoroalkylthio groups
    发明人:DEAR ROBERT ERNEST ARTHUR; FALK ROBERT ALLAN
    权利人:CIBA GEIGY CORP
    摘要:Perfluoroalkylthio glycols and esters thereof can be prepared by the free-radical catalyzed addition of a perfluoroalkylthiol to an acetylenic alcohol or ester thereof. The compounds obtained are useful intermediates for the synthesis of fluorochemicals with low free surface energies having oil and water repellent properties. In one embodiment, a perfluoroalkylthio glycol can be reacted with a diisocyanate to obtain a polyurethane containing perfluoroalkylthio groups, which polyurethanes are useful as coatings to provide oil and water repellence to textiles and as additives to plastics to provide mold-release and other desirable properties.

    专利号:US-4097642-A
    优先权日:1975-11-12
    标题:Fabric coated with RF-glycols containing two perfluoroalkylthio groups
    发明人:DEAR ROBERT ERNEST ARTHUR; FALK ROBERT ALLAN
    权利人:CIBA GEIGY CORP
    摘要:Perfluoroalkylthio glycols and esters thereof can be prepared by the free-radical catalyzed addition of a perfluoroalkylthiol to an acetylenic alcohol or ester thereof. The compounds obtained are useful intermediates for the synthesis of fluorochemicals with low free surface energies having oil and water repellent properties. In one embodiment, a perfluoroalkylthio glycol can be reacted with a diisocyanate to obtain a polyurethane containing perfluoroalkylthio groups, which polyurethanes are useful as coatings to provide oil and water repellance to textiles and as additives to plastics to provide mold-release and other desirable properties.

    专利号:US-10000608-B2
    优先权日:2013-03-15
    标题:Dynamic urea bonds for reversible and self-healing polymers
    发明人:CHENG JIANJUN; YING HANZE
    权利人:UNIV ILLINOIS
    摘要:The disclosure provides reversible polymers from polyurea by modifying the nitrogen atom with hindered substituents. The reversibility of hindered urea bond (HUB) can be controlled by changing the bulkiness of the substituents, and N-tert-butyl-N-ethylurea (TBEU), with its high binding constant and short lifetime, is applicable in the design of reversible polymer and self-healing materials at mild temperatures without external stimuli. HUB can be used in the design of smart materials with its adjustable reversibility, facile synthesis, and compatibility with many other polymer structures.

    专利号:US-5198521-A
    优先权日:1988-08-29
    标题 :Conductive polyurethane-urea/polyethylene oxide polymer
    发明人:EHRHART WENDELL A; HALOUT NOWAF; KO KENNETH K; SMITH DAVID A
    权利人:ARMSTRONG WORLD IND INC
    摘要:A water reaction synthesis with polyoxyethylene diol, diisocyanate and dibutyltin bis lauryl mercaptide produces a high molecular weight thermoplastic polyurethane-urea linear polymer with surface resistivity 1011-106 ohm/sq. Thermoplastic and/or elastomeric antistatic compositions containing other melt processable polymers and/or filler, and the polymer exhibit permanent protection. Antistatic protection can be increased when the polymer complexes with a metal salt such as lithium chloride, or lithium acetate. The composition is useful in the manufacture of antistatic floor coverings and textile texturing and drafting elements such as cots and aprons.
    武汉弘德悦欣医药科技有限公司
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    信用代码: 91420102MA4K4WB79G法定代表人:袁洪杰
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    成立日期:2019-07-31登记机关:武汉市江岸区市场监督管理局
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    地址: 武汉市江岸区车站路6号怡东大厦19层F室
    常规和库存产品*产品总量: 509

    平台资质认证✓营业执照✓
    二(十二烷硫基)二丁基锡
    DI-N-BUTYLBIS(DODECYLTHIO)TIN
    产品图片纯度:98
    250kg/drum
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    ✅ COA系统入驻 | 共享模式

    合成参考文献


    摘要:2024 Emergency Response Guidebook,
    摘要:National Toxicology Program, Institute of Environmental Health Sciences, National Institutes of Health (NTP). 1992. National Toxicology Program Chemical Repository Database. Research Triangle Park, North Carolina.
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