CAS: 4693-47-4; 2,2'-(Diazene-1,2-Diyl)Bis(5-Hydroxy-2-Methylpentanenitrile)

该化合物是白色到浅黄色的固体,在有机溶剂中可溶解.其热稳定性允许其在取暖时分解,产生自由基质,引发聚合反应,使其在生产各种聚合物和共聚物过程中具有价值.此外,丙ententanol 组的存在为进一步的功能化提供了潜力,提高了其在合成应用中的效用.在处理该化合物时,安全考虑十分重要,因为它可能带来与激进生成的特性和潜在毒性有关的风险.应当遵循适当的储存和处理规程来减轻任何危害.

结构式图片

相似化合物

2638-94-0 1029945-77-4

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CAS号1071-73-4 5-羟基-2-戊酮 (单体和二... | CAS号143-33-9 氰化钠

合成工艺路线路线简述

    5-羟基-2-戊酮,氰化钠置于盐酸,溴,硫酸肼体系中,化学反应生成 4,4'-偶氮双(4-氰基戊醇)
    参考文献:非交联嵌段共聚物自由基聚合的双官能引发剂
    标题:非交联嵌段共聚物自由基聚合的双官能引发剂
    摘要:已经设计了具有独立产生自由基的官能团的新型双功能引发剂.合成的引发剂既包含重氮基(nndi),又包含通过酯或醚键连接的2,2,6,6-四甲基哌啶基-1-氧基(tempo)部分.预期这些化合物将可用于生产多种嵌段共聚物,用于聚合物支持的有机合成和材料科学中.
    DOI:10.1016/s0040-4039(98)00070-7

    海关参考信息

    专利信息


    专利号:US-6512081-B1
    优先权日:1997-07-21
    标题:Synthesis of dithioester chain transfer agents and use of bis(thioacyl) disulfides or dithioesters as chain transfer agents
    发明人:RIZZARDO ENZIO; THANG SAN HOA; MOAD GRAEME
    权利人:E I DUPONT NEMOURS AND COMPANY; COMMW SCIENT IND RES ORG
    摘要:This invention relates to the synthesis of dithiocarboxylic acid esters by reaction of bis(thioacyl) disulphides, thioacetals or vinylidane bis(thioether) with free-radicals (optionally in the presence of monomers). The invention also relates to processes for the synthesis of polymers utilising these dithioesters as polymerisation regulators (chain transfer agents) or to the use of bis(thioacyl) disulphides to generate dithioester chain transfer agents in situ.

    专利号:US-2019055337-A1
    优先权日:2016-02-02
    标题 :Low-cost synthesis of macromonomers
    发明人:MAYS JIMMY W; KANG NAM-GOO; WANG WEIYU; WANG HUIQUN
    权利人:UNIV TENNESSEE RES FOUND
    摘要:Methods of preparing macromonomers, e.g., single- or double-tailed macromonomers, using radical polymerization of a first monomer in solution or in an emulsion are described. Methods of using the macromonomers in the preparation of multigraft copolymers are also described. For instance, the macromonomer prepared by radical polymerization can be used in an emulsion copolymerization with a second monomer to form a random multigraft copolymer. The random multigraft co-polymers can be superelastomers.

    专利号:EP-1699833-B1
    优先权日:2003-12-31
    标题:Oligomers containing n-acetyl glucosamine
    发明人:KULKARNI MOHAN GOPALKRISHNA; KHANDARE JAYANT JAGANNATH
    权利人:COUNCIL SCIENT IND RES
    摘要:Functional polyvalent oligomer for applications in medicine and biotechnology are disclosed. These oligomers have the formula (1) wherein R is H, CH3, C2H5, RI, is H, NH2, OH, COOH, X is N-Acetyl Glucosamine, mannose, galactose and sialic acid, fructose, ribulose, erythrolose, xylulose, psicose, sorbose, tagatose, glucopyranose, fructofuranose, deoxyribose, galactosamine, sucrose, lactose, isomaltose, maltose, cellobiose, cellulose and amylose, Y is H, COOH, OH or NH2., and n is from 3 to 50. The present invention also relates to synthesis of such oligomeric ligands. The method of synthesis of the present invention for oligomerization can be - applied to other ligands such as sialic acid, mannose and galactose and can -be used for the prevention of infections,

    专利号:US-6977285-B2
    优先权日:2004-03-30
    标题:Oligomers containing N-acetyl glucosamine (NAG)
    发明人:KULKARNI MOHAN GOPALKRISHNA; KHANDARE JAYANT JAGANNATH
    权利人:COUNCIL SCIENT IND RES
    摘要:Functional polyvalent oligomer for applications in medicine and biotechnology are disclosed. These oligomers have the formula (1) n nwherein R is H, CH 3 , C 2 H 5 , R1, is H, NH2, OH, COOH, X is N-Acetyl Glucosamine, mannose, galactose and sialic acid, fructose, ribulose, erythrolose, xylulose, psicose, sorbose, tagatose, glucopyranose, fructofuranose, deoxyribose, galactosamine, sucrose, lactose, isomaltose, maltose, cellobiose, cellulose and amylose, Y is H, COOH, OH or NH2, and n is from 3 to 50. The present invention also relates to synthesis of such oligomeric ligands. The method of synthesis of the present invention for oligomerization can be—applied to other ligands such as sialic acid, mannose and galactose and can -be used for the prevention of infections.

    专利号:WO-2017136565-A1
    优先权日:2016-02-02
    标 题 :Low-cost synthesis of macromonomers

    专利号:WO-9905099-A1
    优先权日:1997-07-21
    标题:Synthesis of dithioester chain transfer agents and use of bis(thioacyl) disulfides or dithioesters as chain transfer agents
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    合成参考文献


    参考文献:10.1007/978-94-007-2891-2_15
    摘要:Yang Y, Xie X, Cui W. Functionalization of Carbon Nanotubes with Ionic Liquids. 2012. In: Green Solvents II. : Springer Netherlands; 2012.
    参考文献:10.1007/s10965-022-03271-4
    摘要:Dong H, Wang Y, Fan M, Zhao J, Zhang Z, Zhang J. Synthesis and properties of multi-block thermoplastic polyurethanes constructed with polystyrene and poly(butylene adipate) sequences. Journal of Polymer Research. 2022 Sep 06;29(10):413. doi: 10.1007/s10965-022-03271-4.
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