CAS: 7787-64-6; Bismuth(Iii) Iodide

该化合物是一种无机化合物,其特征是深褐色和黑晶状表面,由二氯和碘组成,分子公式反映二氯和碘的1:3比重,该化合物的半导体特性显著,并经常用于电子和光电子的应用.三硫化物具有层结构,有助于其独特的物理特性,包括其在可见频谱中吸收光体的能力.在环境条件下,它相对稳定,但可以分解取暖,释放碘蒸气.三硫化物在水中是溶解的,但可以溶解入有机溶剂,在各种化学反应和工艺中有用.在处理该化合物时,应当采取安全防范措施,因为碘在某些形式上是危险的.

结构式图片

相似化合物

41944-01-8

欧盟法规

ECHA物质C&L通报REACH预注册

上下游产品

bismuth(III) oxide aluminium(III) iodide bismuth iodinebismuth(III) oxide iodide bismuth bismuth(III) chloride bismuth(III) oxide

合成工艺路线路线简述

  • 合成目标产物 Bismuth(Iii) Iodide 主要起始原料 Bismuth And Iodine
  • (文献来源)合成步骤主要原料 Bismuth 和 Iodine
在 Oxonium体系中,用 Not Given 作为反应溶剂,以100%的收率获得产物碘化铋
参考文献:Montignie,E.,Bulletin De La Societe Chimique De France,1934,Vol. 1,P. 692-696
标题:Montignie,E.,Bulletin De La Societe Chimique De France,1934,Vol. 1,P. 692-696

专利信息


专利号:US-10189803-B2
优先权日:2008-02-22
标题 :Synthesis of therapeutic and diagnostic drugs centered on regioselective and stereoselective ring opening of aziridinium ions
发明人:CHONG HYUN-SOON
权利人:CHONG HYUN SOON; ILLINOIS INSTITUTE OF TECH
摘要:Stereoselective and regioselective synthesis of compounds via nucleophilic ring opening reactions of aziridinium ions for use in stereoselective and regioselective synthesis of therapeutic and diagnostic compounds.

专利号:US-7615169-B2
优先权日:2004-09-20
标题 :Method for synthesis of colloidal nanoparticles
发明人:STROUSE GEOFFREY FIELDING; GERBEC JEFFREY A; MAGANA DONNY
权利人:UNIV CALIFORNIA
摘要:A method for synthesis of high quality colloidal nanoparticles using comprises a high heating rate process. Irradiation of single mode, high power, microwave is a particularly well suited technique to realize high quality semiconductor nanoparticles. The use of microwave radiation effectively automates the synthesis, and more importantly, permits the use of a continuous flow microwave reactor for commercial preparation of the high quality colloidal nanoparticles.

专利号:US-7927516-B2
优先权日:2004-09-20
标题 :Method for synthesis of colloidal nanoparticles
发明人:STROUSE GEOFFREY F; GERBEC JEFFREY A; MAGANA DONNY
权利人:UNIV CALIFORNIA
摘要:A method for synthesis of high quality colloidal nanoparticles using comprises a high heating rate process. Irradiation of single mode, high power, microwave is a particularly well suited technique to realize high quality semiconductor nanoparticles. The use of microwave radiation effectively automates the synthesis, and more importantly, permits the use of a continuous flow microwave reactor for commercial preparation of the high quality colloidal nanoparticles.

专利号:US-8709304-B2
优先权日:2009-12-14
标题 :Hydrothermal synthesis of nanocubes of sillenite type compounds for photovoltaic applications and solar energy conversion of carbon dioxide to fuels
发明人:SUBRAMANIAN VAIDYANATHAN; MURUGESAN SANKARAN
权利人:SUBRAMANIAN VAIDYANATHAN; MURUGESAN SANKARAN; UNIV NEVADA
摘要:The present invention relates to formation of nanocubes of sillenite type compounds, such as bismuth titanate, i.e., Bi 12 TiO 20 , nanocubes, via a hydrothermal synthesis process, with the resulting compound(s) having multifunctional properties such as being useful in solar energy conversion, environmental remediation, and/or energy storage, for example. In one embodiment, a hydrothermal method is disclosed that transforms nanoparticles of TiO 2 to bismuth titanate, i.e., Bi 12 TiO 20 , nanocubes, optionally loaded with palladium nanoparticles. The method includes reacting titanium dioxide nanotubes with a bismuth salt in an acidic bath at a temperature sufficient and for a time sufficient to form bismuth titanate crystals, which are subsequently annealed to form bismuth titanate nanocubes. After annealing, the bismuth titanate nanocubes may be optionally loaded with nano-sized metal particles, e.g., nanosized palladium particles.

专利号:US-9561493-B2
优先权日:2010-05-11
标题 :Synthesis of pyrochlore nanostructures and uses thereof
发明人:SUBRAMANIAN VAIDYANATHAN; MURUGESAN SANKARAN
权利人:SUBRAMANIAN VAIDYANATHAN; MURUGESAN SANKARAN; UNIV NEVADA RENO
摘要:A template-free reverse micelle (RM) based method is used to synthesize pyrochlore nanostructures having photocatalytic activity. In one embodiment, the method includes separately mixing together a first acid stabilized aqueous solution including pyrochlore precursor A and a second acid stabilized aqueous solution including pyrochlore precursor B with an organic solution including a surfactant to form an oil-in-water emulsion. Next, equimolar solutions of the first and second acid stabilized oil-in-water emulsions are mixed together. Then, the mixture of the first and second acid stabilized oil-in-water emulsion is treated with a base to produce a precipitate including pyrochlore precursors A and B. After which, the precipitate is dried to remove volatiles. The precipitate is then calcined in the presence of oxygen to form a pyrochlore nanostructure, such as a bismuth titanate (Bi 2 Ti 2 O 7 ) pyrochlore nanorod. The method of synthesizing the pyrochlore nanorod is template-free.

专利号:US-8957260-B2
优先权日:2011-02-07
标题 :Process for the oxidation of mesitol
发明人:WEYRAUCH JAN PHILIPP; WEIS MARTINE; TELES JOAQUIM HENRIQUE; EBEL KLAUS; DEGLMANN PETER
权利人:WEIS MARTINE; TELES JOAQUIM HENRIQUE; EBEL KLAUS; DEGLMANN PETER; WEYRAUCH VIVIEN ELLINOR; WEYRAUCH GUNHILD; BASF SE
摘要:The invention relates to a process for the oxidation of mesitol with singlet oxygen, which is released from hydrogen peroxide, this release taking place in the presence of a bismuth compound as catalyst. In the process, 2,4,6-trimethylquinol is formed in high yield and selectivity as product, which can be used in further reactions for the synthesis of vitamins and in particular of vitamin A and vitamin E.
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主要参考文献

[参考文献]: F M Abdel-Gawad, Et Al. Ion-Pair Formation Of Bi(Iii)-Iodide With Some Nitrogenous Drugs And Its Application To Pharmaceutical Preparations. J Pharm Biomed Anal. 1998 Jan;16(5):793-9.
[参考文献]: Minhua Su, Et Al. Enhanced Adsorption And Photocatalytic Activity Of Bioi-Mwcnt Composites Towards Organic Pollutants In Aqueous Solution. J Hazard Mater. 2012 Aug 30:229-230:72-82.
[参考文献]: Nathan T Hahn, Et Al. Spray Pyrolysis Deposition And Photoelectrochemical Properties Of N-Type Bioi Nanoplatelet Thin Films. Acs Nano. 2012 Sep 25;6(9):7712-22.
[参考文献]: R R Jia, Et Al. Synthesis And Characterization Of Aspartic Acid Complexes Of Antimony And Bismuth Triiodide. Amino Acids. 2006 Jul;31(1):85-90.
[参考文献]: S Dolapchieva, Et Al. Bismuth Iodide Impregnation Of The Peripheral Nerve Fibres. Z Mikrosk Anat Forsch. 1985;99(5):804-12.

合成参考文献


参考文献:10.1007/bf02885430
摘要:Xiang Y, Zhang C, Zheng Y. Studies on the chemical constituents of the roots of Rhododendron molle G. Don. J Huazhong Univ Sci Technolog Med Sci. 2004;24(2):202–4. doi: 10.1007/bf02885430.
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